PMID- 27173454 OWN - NLM STAT- MEDLINE DCOM- 20180321 LR - 20180515 IS - 1879-1026 (Electronic) IS - 0048-9697 (Linking) VI - 568 DP - 2016 Oct 15 TI - Polychlorinated dibenzo-p-dioxins, dibenzofurans and dioxin-like PCBs in commercialized food products from Colombia. PG - 1185-1191 LID - S0048-9697(16)30808-7 [pii] LID - 10.1016/j.scitotenv.2016.04.113 [doi] AB - Polychlorinated dibenzo-p-dioxins (PCDDs), polychlorinated dibenzofurans (PCDFs) and dioxin-like polychlorinated biphenyls (dl-PCBs) are commonly known as dioxins and are the most toxic members of persistent organic pollutants (POPs) because present a variety of health effects especially as promoting agent of growing and transformation of cancer cells. They are bio-accumulate in humans primarily via the diet, specifically by ingestion of foods that have high lipid content which are generally associated with foods of animal origin such as oils and fats and with fishery and dairy products. In Colombia the Ministry of Health and Social Protection which is the entity responsible for surveillance food conditions, has established maximum levels for dioxins and dl-PCBs in oils from animal and vegetable origins. Oils of vegetable and animal origin represent an appreciable intake in the country thus the presence of dioxins and dl-PCBs in these materials is a matter of concern because they can bioaccumulate in fat. In this contribution the levels of PCDD/Fs and dl-PCBs in olive, soybean, fish oil, butter and shrimp consumed in Colombia were determined using HRGC-HRMS and were compared with the maximum levels permitted in oil samples according to both the Colombian and European regulations. WHO-TEQ concentrations for PCDD/Fs and dioxin like PCBs ranged from 0.24 to 1.710pgWHO-TEQ PCDD/Fg(-1) of fat and from 0.050 to 3.000pgWHO-TEQ PCBg(-1) of fat, respectively. As expected, fish oils and shrimp present the highest WHO-TEQ PCDD/Fs and dl-PCBs values followed by butter and soybean oil sample, while the olive oil shows the lowest levels. In general, the vegetable oils show levels below the limits established by both the Colombian and European regulations. The levels from soybean oil found in this study were slightly higher than the threshold established both by the Commission Regulation European Union (EU) and the Colombian legislation, while fish oils showed concentrations above the European regulations. Furthermore, shrimp exhibited values below the maximum concentration levels established by the EU and Colombian regulation. CI - Copyright (c) 2016. Published by Elsevier B.V. FAU - Pemberthy, D AU - Pemberthy D AD - Environmental Catalysis Research Group, Chemical Engineering Department, Engineering School, Universidad de Antioquia, Calle 70 No. 52-2, Medellin, Colombia; Spanish Council for Scientific Research (CSIC), Institute of Environmental Assessments and Water Research, C/ Jordi Girona 18-26, 08034 Barcelona, Spain. FAU - Quintero, A AU - Quintero A AD - Environmental Catalysis Research Group, Chemical Engineering Department, Engineering School, Universidad de Antioquia, Calle 70 No. 52-2, Medellin, Colombia. FAU - Martrat, M G AU - Martrat MG AD - Spanish Council for Scientific Research (CSIC), Institute of Environmental Assessments and Water Research, C/ Jordi Girona 18-26, 08034 Barcelona, Spain. FAU - Parera, J AU - Parera J AD - Spanish Council for Scientific Research (CSIC), Institute of Environmental Assessments and Water Research, C/ Jordi Girona 18-26, 08034 Barcelona, Spain. FAU - Abalos, M AU - Abalos M AD - Spanish Council for Scientific Research (CSIC), Institute of Environmental Assessments and Water Research, C/ Jordi Girona 18-26, 08034 Barcelona, Spain. FAU - Abad, E AU - Abad E AD - Spanish Council for Scientific Research (CSIC), Institute of Environmental Assessments and Water Research, C/ Jordi Girona 18-26, 08034 Barcelona, Spain. FAU - Villa, A L AU - Villa AL AD - Environmental Catalysis Research Group, Chemical Engineering Department, Engineering School, Universidad de Antioquia, Calle 70 No. 52-2, Medellin, Colombia. Electronic address: aida.villa@udea.edu.co. LA - eng PT - Journal Article DEP - 20160509 PL - Netherlands TA - Sci Total Environ JT - The Science of the total environment JID - 0330500 RN - 0 (Benzofurans) RN - 0 (Dioxins) RN - 0 (Environmental Pollutants) RN - 0 (Fish Oils) RN - 0 (Plant Oils) RN - 0 (Polychlorinated Dibenzodioxins) RN - 8029-34-3 (Butter) SB - IM MH - Animals MH - Benzofurans/*analysis MH - Butter/analysis MH - Colombia MH - Crustacea/chemistry MH - Dioxins/*analysis MH - Environmental Pollutants/*analysis MH - Fish Oils/analysis MH - Food Contamination/*analysis MH - Plant Oils/analysis MH - Polychlorinated Dibenzodioxins/*analysis OTO - NOTNLM OT - Dioxin-like polychlorinated biphenyls (dl-PCBs) OT - HRGC-HRMS OT - Oil OT - Polychlorinated dibenzo-p-dioxins (PCDD) OT - Polychlorinated dibenzofurans (PCDF) OT - Shrimp EDAT- 2016/05/14 06:00 MHDA- 2018/03/22 06:00 CRDT- 2016/05/14 06:00 PHST- 2015/11/17 00:00 [received] PHST- 2016/04/15 00:00 [revised] PHST- 2016/04/16 00:00 [accepted] PHST- 2016/05/14 06:00 [entrez] PHST- 2016/05/14 06:00 [pubmed] PHST- 2018/03/22 06:00 [medline] AID - S0048-9697(16)30808-7 [pii] AID - 10.1016/j.scitotenv.2016.04.113 [doi] PST - ppublish SO - Sci Total Environ. 2016 Oct 15;568:1185-1191. doi: 10.1016/j.scitotenv.2016.04.113. Epub 2016 May 9.