PMID- 27211669
OWN - NLM
STAT- MEDLINE
DCOM- 20170210
LR  - 20181202
IS  - 1873-7072 (Electronic)
IS  - 0308-8146 (Linking)
VI  - 210
DP  - 2016 Nov 1
TI  - Detection of three herbicide, and one metabolite, residues in brown rice and rice 
      straw using various versions of the QuEChERS method and liquid 
      chromatography-tandem mass spectrometry.
PG  - 442-50
LID - S0308-8146(16)30681-1 [pii]
LID - 10.1016/j.foodchem.2016.05.005 [doi]
AB  - A single-run analytical method was developed to analyze the three herbicides 
      azimsulfuron, bensulfuron-methyl, and mesotrione and its metabolite 
      (4-methylsulfonyl-2-nitrobenzoic acid (MNBA)) in brown rice and rice straw using 
      liquid chromatography-tandem mass spectrometry (LC/MS/MS). Samples extracted 
      using various versions of Quick, Easy, Cheap, Effective, Rugged, and Safe 
      "QuEChERS" (original unbuffered, acetate (AOAC), and citrate (EN) buffered) 
      methods gave poor recoveries of all the tested analytes in both matrices. The 
      extraction efficiency was improved when primary-secondary amine (PSA) sorbent was 
      removed from the purification step, with the best recovery being achieved for 
      EN-QuEChERS, which was subsequently used throughout the study. Overall, a 
      determination coefficients (R(2))⩾0.995 was achieved at matrix-matched 
      calibration curves at various concentration ranges. The recovery rates at three 
      fortification levels (limit of quantification (LOQ), 1/2 maximum residue limit 
      (1/2MRL), and MRL) ranged from 78 to 114.5, with relative standard deviations 
      (RSDs)<18% for all the tested analytes in both matrices. The LOQs for all 
      herbicides were lower than the MRL set by the Ministry of Food and Drug Safety 
      (MFDS), Republic of Korea. Field trials with the recommended, or double the 
      recommended dose, revealed that the herbicides can safely be applied to rice, as 
      no residues were detected in the harvested samples at 110days.
CI  - Copyright (c) 2016 Elsevier Ltd. All rights reserved.
FAU - Lee, Young-Jun
AU  - Lee YJ
AD  - Biotechnology Research Institute, College of Agriculture and Life Sciences, 
      Chonnam National University, 77 Yongbong-ro, Buk-gu, Gwangju 500-757, Republic of 
      Korea.
FAU - Rahman, Md Musfiqur
AU  - Rahman MM
AD  - Biotechnology Research Institute, College of Agriculture and Life Sciences, 
      Chonnam National University, 77 Yongbong-ro, Buk-gu, Gwangju 500-757, Republic of 
      Korea.
FAU - Abd El-Aty, A M
AU  - Abd El-Aty AM
AD  - Department of Veterinary Pharmacology and Toxicology, College of Veterinary 
      Medicine, Konkuk University, Seoul, Repulic of Korea; Department of Pharmacology, 
      Faculty of Veterinary Medicine, Cairo University, 12211 Giza, Egypt. Electronic 
      address: abdelaty44@hotmail.com.
FAU - Choi, Jeong-Heui
AU  - Choi JH
AD  - Biotechnology Research Institute, College of Agriculture and Life Sciences, 
      Chonnam National University, 77 Yongbong-ro, Buk-gu, Gwangju 500-757, Republic of 
      Korea.
FAU - Chung, Hyung Suk
AU  - Chung HS
AD  - Biotechnology Research Institute, College of Agriculture and Life Sciences, 
      Chonnam National University, 77 Yongbong-ro, Buk-gu, Gwangju 500-757, Republic of 
      Korea.
FAU - Kim, Sung-Woo
AU  - Kim SW
AD  - Biotechnology Research Institute, College of Agriculture and Life Sciences, 
      Chonnam National University, 77 Yongbong-ro, Buk-gu, Gwangju 500-757, Republic of 
      Korea.
FAU - Abdel-Aty, Azza M
AU  - Abdel-Aty AM
AD  - Water Pollution Research Department, National Research Centre, 33 El Bohouth St., 
      Dokki, 12622 Giza, Egypt.
FAU - Shin, Ho-Chul
AU  - Shin HC
AD  - Department of Veterinary Pharmacology and Toxicology, College of Veterinary 
      Medicine, Konkuk University, Seoul, Repulic of Korea.
FAU - Shim, Jae-Han
AU  - Shim JH
AD  - Biotechnology Research Institute, College of Agriculture and Life Sciences, 
      Chonnam National University, 77 Yongbong-ro, Buk-gu, Gwangju 500-757, Republic of 
      Korea. Electronic address: jhshim@chonnam.ac.kr.
LA  - eng
PT  - Journal Article
DEP - 20160502
PL  - England
TA  - Food Chem
JT  - Food chemistry
JID - 7702639
RN  - 0 (Herbicides)
RN  - 0 (Pesticide Residues)
SB  - IM
MH  - Chromatography, Liquid/*methods
MH  - Herbicides/analysis
MH  - Oryza/*chemistry
MH  - Pesticide Residues/analysis/*chemistry
MH  - Tandem Mass Spectrometry/*methods
OTO - NOTNLM
OT  - Herbicides
OT  - LC/MS/MS
OT  - QuEChERS
OT  - Residues
OT  - Rice
OT  - Rice straw
EDAT- 2016/05/24 06:00
MHDA- 2017/02/12 06:00
CRDT- 2016/05/24 06:00
PHST- 2016/02/16 00:00 [received]
PHST- 2016/04/18 00:00 [revised]
PHST- 2016/05/01 00:00 [accepted]
PHST- 2016/05/24 06:00 [entrez]
PHST- 2016/05/24 06:00 [pubmed]
PHST- 2017/02/12 06:00 [medline]
AID - S0308-8146(16)30681-1 [pii]
AID - 10.1016/j.foodchem.2016.05.005 [doi]
PST - ppublish
SO  - Food Chem. 2016 Nov 1;210:442-50. doi: 10.1016/j.foodchem.2016.05.005. Epub 2016 
      May 2.