PMID- 27216949
OWN - NLM
STAT- PubMed-not-MEDLINE
DCOM- 20180116
LR  - 20180116
IS  - 1520-510X (Electronic)
IS  - 0020-1669 (Linking)
VI  - 55
IP  - 11
DP  - 2016 Jun 6
TI  - Lanthanide Germanate Cluster Organic Frameworks Based on Ln8Ge12 Clusters: From 
      One-Dimensional Chains to Two-Dimensional Layers and Three-Dimensional 
      Frameworks.
PG  - 5671-83
LID - 10.1021/acs.inorgchem.6b00754 [doi]
AB  - Under hydrothermal conditions, six series of novel lanthanide (Ln) 
      organogermanates (LnGs) [Ln8Ge12(mu3-O)24E12(H2O)16].14H2O (Ln(3+) = Pr(3+), 1; 
      Nd(3+), 2; Sm(3+), 3; Eu(3+), 4; Gd(3+), 5; one-dimensional (1-D) LnG cluster 
      organic chain (LnGCOC)), 
      [Nd8Ge12(mu3-O)24E12(H2O)10](mu2-H2O)2[Nd8Ge12(mu3-O)24E12(H2O)16].18H2O (6, 
      two-dimensional (2-D) planar LnG cluster organic layer (LnGCOL)), 
      [Ln2GeE(HO)2O(H2O)(CH3COO)2(CO3)]2[Ln8Ge12E12(mu3-O)24(H2O)10].6H2O (Ln(3+) = 
      Pr(3+), 7; Nd(3+), 8; 2-D wave-shaped LnGCOL), 
      [TbGeE(HO)2O(H2O)(pca)]2[Tb8Ge12E12(mu3-O)24(H2O)8].10H2O (9, three-dimensional 
      (3-D) LnG cluster organic framework (LnGCOF)), 
      ([Nd(pza)2(H2O)2]2[Nd8Ge12E12(mu3-O)24(H2O)12])([Nd(pza)2]2[Nd8Ge12E12(Hpza)2(mu3-O)24(H2O)10]).4OH.14H2O 
      (10, 3-D LnGCOF), [Nd8Ge12E12(mu3-O)24(H2O)10][Nd(pca)(pda)(H2O)]2.12H2O (11, 
      3-D LnGCOF) and [Nd8Ge12E12(mu3-O)24(H2O)10][Nd(pza)(pda)(H2O)]2.12H2O (12, 3-D 
      LnGCOF) (Hpca = 2-picolinic acid, H2pda = 2,6-pyridinedicarboxylic acid, Hpza = 
      2-pyrazinecarboxylic acid) were prepared by introducing the second auxiliary 
      ligands into the organogermanate-lanthanide-oxide reaction system. The obtainment 
      of these LnGs realized the utilization of the second auxiliary ligands inducing 
      the assembly from 1-D LnGCOCs to 2-D LnGCOLs and 3-D LnGCOFs based on LnG cluster 
      (LnGC) Ln8Ge12E12(mu3-O)24(H2O)16(Ln8Ge12) units and Ln-organic complexes or 
      organic ligand connectors. It should be noted that the well-organized structural 
      constructions of 1-12 can be visualized as the gradual replacement of active 
      water sites located at equatorial and polar positions on the hypothetical 
      [Ln8Ge12(mu3-O)24E12(H2O)18] LnGC core with oxygen or nitrogen atoms from organic 
      ligands. The solid-state luminescent properties of 2, 3, 4, 6, and 8-12 have been 
      investigated at room temperature.
FAU - Li, Lei-Lei
AU  - Li LL
AD  - MOE Key Laboratory of Cluster Science, School of Chemistry, Beijing Institute of 
      Technology , Beijing 100081, China.
FAU - Cao, Gao-Juan
AU  - Cao GJ
AD  - Department of Applied Chemistry, School of Life Science Fujian Agriculture and 
      Forestry University , Fuzhou, Fujian 350002, China.
FAU - Zhao, Jun-Wei
AU  - Zhao JW
AD  - Henan Key Laboratory of Polyoxometalate Chemistry, College of Chemistry and 
      Chemical Engineering, Henan University , Kaifeng, Henan 475004, China.
FAU - He, Huan
AU  - He H
AD  - MOE Key Laboratory of Cluster Science, School of Chemistry, Beijing Institute of 
      Technology , Beijing 100081, China.
FAU - Yang, Bai-Feng
AU  - Yang BF
AD  - MOE Key Laboratory of Cluster Science, School of Chemistry, Beijing Institute of 
      Technology , Beijing 100081, China.
FAU - Yang, Guo-Yu
AU  - Yang GY
AD  - MOE Key Laboratory of Cluster Science, School of Chemistry, Beijing Institute of 
      Technology , Beijing 100081, China.
AD  - Department of Chemistry and Key Laboratory for Preparation and Application of 
      Ordered Structural Materials of Guangdong Province Shantou University, Shantou, 
      Guangdong 515063, China.
LA  - eng
PT  - Journal Article
DEP - 20160524
PL  - United States
TA  - Inorg Chem
JT  - Inorganic chemistry
JID - 0366543
EIN - Inorg Chem. 2020 Mar 2;59(5):3340. PMID: 32037794
EDAT- 2016/05/25 06:00
MHDA- 2016/05/25 06:01
CRDT- 2016/05/25 06:00
PHST- 2016/05/25 06:00 [entrez]
PHST- 2016/05/25 06:00 [pubmed]
PHST- 2016/05/25 06:01 [medline]
AID - 10.1021/acs.inorgchem.6b00754 [doi]
PST - ppublish
SO  - Inorg Chem. 2016 Jun 6;55(11):5671-83. doi: 10.1021/acs.inorgchem.6b00754. Epub 
      2016 May 24.