PMID- 27225670 OWN - NLM STAT- PubMed-not-MEDLINE DCOM- 20170905 LR - 20170906 IS - 1613-6829 (Electronic) IS - 1613-6810 (Linking) VI - 12 IP - 26 DP - 2016 Jul TI - Black Phosphorus Nanosheets: Synthesis, Characterization and Applications. PG - 3480-502 LID - 10.1002/smll.201600032 [doi] AB - Black phosphorus (BP) is an emerging two-dimensional (2D) material with a natural bandgap, which has unique anisotropy and extraordinary physical properties. Due to its puckered structure, BP exhibits strong in-plane anisotropy unlike other layered materials. The bandgap tunability of BP enables a wide range of ultrafast electronics and high frequency optoelectronic applications ranging from telecommunications to thermal imaging covering the nearly entire electromagnetic spectrum, whereas no other 2D material has this functionality. Here, recent advances in the synthesis, fabrication, anisotropic physical properties, and BP-based devices including field effect transistors (FETs) and photodetectors, are discussed. Recent passivation approaches to address the degradation of BP, which is one of the main challenges to bring this material into real world applications, are also introduced. Finally, a comment is made on the recent developments in other emerging applications, future outlook and challenges ahead in BP research. CI - (c) 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. FAU - Eswaraiah, Varrla AU - Eswaraiah V AD - School of Materials Science and Engineering, Nanyang Technological University, Singapore, 639798. FAU - Zeng, Qingsheng AU - Zeng Q AD - School of Materials Science and Engineering, Nanyang Technological University, Singapore, 639798. FAU - Long, Yi AU - Long Y AD - School of Materials Science and Engineering, Nanyang Technological University, Singapore, 639798. FAU - Liu, Zheng AU - Liu Z AD - School of Materials Science and Engineering, Nanyang Technological University, Singapore, 639798. AD - Center for Programmable Materials, School of Materials Science and Engineering, Nanyang Technological University, Singapore. AD - NOVITAS, Nanoelectronics Center of Excellence, School of Electrical and Electronic Engineering, Nanyang Technological University, Singapore, 639798. AD - CINTRA CNRS/NTU/THALES, UMI 3288, Research Techno Plaza, 50 Nanyang Drive, Border X Block, Level 6, Singapore, 637553. LA - eng PT - Journal Article DEP - 20160525 PL - Germany TA - Small JT - Small (Weinheim an der Bergstrasse, Germany) JID - 101235338 OTO - NOTNLM OT - anisotropy OT - bandgaps OT - black phosphorus OT - electronics OT - optoelectronics EDAT- 2016/05/27 06:00 MHDA- 2016/05/27 06:01 CRDT- 2016/05/27 06:00 PHST- 2016/01/05 00:00 [received] PHST- 2016/03/23 00:00 [revised] PHST- 2016/05/27 06:00 [entrez] PHST- 2016/05/27 06:00 [pubmed] PHST- 2016/05/27 06:01 [medline] AID - 10.1002/smll.201600032 [doi] PST - ppublish SO - Small. 2016 Jul;12(26):3480-502. doi: 10.1002/smll.201600032. Epub 2016 May 25.