PMID- 27254815
OWN - NLM
STAT- PubMed-not-MEDLINE
DCOM- 20180117
LR  - 20180117
IS  - 1477-9234 (Electronic)
IS  - 1477-9226 (Linking)
VI  - 45
IP  - 25
DP  - 2016 Jun 21
TI  - Hydrosilane-B(C6F5)3 adducts as activators in zirconocene catalyzed ethylene 
      polymerization.
PG  - 10146-50
LID - 10.1039/c6dt01946c [doi]
AB  - Hydrosilane-B(C6F5)3 adducts were found to activate zirconocene dihalides and 
      generate ternary catalytic systems possessing moderate to high activity in 
      ethylene polymerization to high density polyethylene (HDPE). The activation 
      efficacy of the adducts increased with increasing hydride donor ability and 
      decreased with steric crowding of the particular hydrosilane used. NMR 
      investigation of the HSiEt3/B(C6F5)3/Cp*2ZrF2 system (Cp* = eta(5)-C5Me5) revealed 
      the formation of a stable intermediate [Cp*2ZrF(FSiEt3-kappaF)](+)[HB(C6F5)3](-), 
      whereas a crucial role of the [HB(C6F5)3](-) anion as a hydride donor for 
      generation of an active cationic zirconium hydride center was elucidated.
FAU - Varga, Vojtech
AU  - Varga V
AD  - J. Heyrovsky Institute of Physical Chemistry, Academy of Sciences of the Czech 
      Republic, v.v.i., Dolejskova 3, 182 23 Prague 8, Czech Republic. 
      jiri.pinkas@jh-inst.cas.cz.
FAU - Lamac, Martin
AU  - Lamac M
AD  - J. Heyrovsky Institute of Physical Chemistry, Academy of Sciences of the Czech 
      Republic, v.v.i., Dolejskova 3, 182 23 Prague 8, Czech Republic. 
      jiri.pinkas@jh-inst.cas.cz.
FAU - Horacek, Michal
AU  - Horacek M
AD  - J. Heyrovsky Institute of Physical Chemistry, Academy of Sciences of the Czech 
      Republic, v.v.i., Dolejskova 3, 182 23 Prague 8, Czech Republic. 
      jiri.pinkas@jh-inst.cas.cz.
FAU - Gyepes, Robert
AU  - Gyepes R
AD  - J. Heyrovsky Institute of Physical Chemistry, Academy of Sciences of the Czech 
      Republic, v.v.i., Dolejskova 3, 182 23 Prague 8, Czech Republic. 
      jiri.pinkas@jh-inst.cas.cz.
FAU - Pinkas, Jiri
AU  - Pinkas J
AD  - J. Heyrovsky Institute of Physical Chemistry, Academy of Sciences of the Czech 
      Republic, v.v.i., Dolejskova 3, 182 23 Prague 8, Czech Republic. 
      jiri.pinkas@jh-inst.cas.cz.
LA  - eng
PT  - Journal Article
PL  - England
TA  - Dalton Trans
JT  - Dalton transactions (Cambridge, England : 2003)
JID - 101176026
EDAT- 2016/06/03 06:00
MHDA- 2016/06/03 06:01
CRDT- 2016/06/03 06:00
PHST- 2016/06/03 06:00 [entrez]
PHST- 2016/06/03 06:00 [pubmed]
PHST- 2016/06/03 06:01 [medline]
AID - 10.1039/c6dt01946c [doi]
PST - ppublish
SO  - Dalton Trans. 2016 Jun 21;45(25):10146-50. doi: 10.1039/c6dt01946c.