PMID- 27312610 OWN - NLM STAT- MEDLINE DCOM- 20180123 LR - 20180123 IS - 1879-1344 (Electronic) IS - 0144-8617 (Linking) VI - 150 DP - 2016 Oct 5 TI - Preparation of cellulose composites with in situ generated copper nanoparticles using leaf extract and their properties. PG - 32-9 LID - S0144-8617(16)30498-2 [pii] LID - 10.1016/j.carbpol.2016.04.121 [doi] AB - In the present work, copper nanoparticles (CuNPs) were in situ generated in cellulose matrix using Ocimum sanctum leaf extract as a reducing agent and aq. CuSO4 solution by diffusion process. Some CuNPs were also formed outside the film in the solution which were separated and viewed by Transmission electron microscope and Scanning electron microscope (SEM). The composite films showed good antibacterial activity against Escherichia coli bacteria when the CuNPs were generated using higher concentrated aq. CuSO4 solutions. The cellulose, matrix and the composite films were characterized by Fourier transform infrared spectroscopic, X-ray diffraction, thermogravimetric analysis and SEM techniques. The tensile strength of the composite films was lower than that of the matrix but still higher than the conventional polymers like polyethylene and polypropylene used for packaging applications. These biodegradable composite films can be considered for packaging and medical applications. CI - Copyright (c) 2016 Elsevier Ltd. All rights reserved. FAU - Sadanand, V AU - Sadanand V AD - Department of Chemistry, Osmania University, Hyderabad 500007, India. FAU - Rajini, N AU - Rajini N AD - Department of Mechanical Engineering, Kalasalingam University, Anand Nagar, Krishnan Kovil 626126, India. FAU - Varada Rajulu, A AU - Varada Rajulu A AD - Centre for Composite Materials, International Research Centre, Kalasalingam University, Anand Nagar, Krishnan Kvoil 626126, India. Electronic address: avaradarajulu@gmail.com. FAU - Satyanarayana, B AU - Satyanarayana B AD - Department of Chemistry, Osmania University, Hyderabad 500007, India. LA - eng PT - Journal Article PT - Research Support, Non-U.S. Gov't DEP - 20160502 PL - England TA - Carbohydr Polym JT - Carbohydrate polymers JID - 8307156 RN - 0 (Anti-Bacterial Agents) RN - 789U1901C5 (Copper) RN - 9004-34-6 (Cellulose) SB - IM MH - Anti-Bacterial Agents/*chemistry/*pharmacology MH - Cellulose/*chemistry/*pharmacology MH - Copper/*chemistry MH - Escherichia coli/drug effects MH - Metal Nanoparticles/*chemistry MH - Ocimum sanctum/chemistry MH - Plant Leaves/*chemistry MH - Tensile Strength OTO - NOTNLM OT - Antibacterial activity OT - Biodegradable nanocomposites OT - Copper nanoparticles OT - In situ generation OT - Tensile properties OT - Thermal stability EDAT- 2016/06/18 06:00 MHDA- 2018/01/24 06:00 CRDT- 2016/06/18 06:00 PHST- 2016/02/14 00:00 [received] PHST- 2016/04/27 00:00 [revised] PHST- 2016/04/28 00:00 [accepted] PHST- 2016/06/18 06:00 [entrez] PHST- 2016/06/18 06:00 [pubmed] PHST- 2018/01/24 06:00 [medline] AID - S0144-8617(16)30498-2 [pii] AID - 10.1016/j.carbpol.2016.04.121 [doi] PST - ppublish SO - Carbohydr Polym. 2016 Oct 5;150:32-9. doi: 10.1016/j.carbpol.2016.04.121. Epub 2016 May 2.