PMID- 27314927 OWN - NLM STAT- PubMed-not-MEDLINE DCOM- 20180718 LR - 20180718 IS - 1944-8252 (Electronic) IS - 1944-8244 (Linking) VI - 8 IP - 27 DP - 2016 Jul 13 TI - Improving the Transparency of Ultra-Drawn Melt-Crystallized Polyethylenes: Toward High-Modulus/High-Strength Window Application. PG - 17549-54 LID - 10.1021/acsami.6b04704 [doi] AB - Highly transparent, ultradrawn high-density polyethylene (HDPE) films were successfully prepared using compression molding and solid-state drawing techniques. The low optical transmittance (<50%) of the pure drawn HDPE films can be drastically improved (>90%) by incorporating a small amount (>1 wt %/wt) of specific additives to HDPE materials prior to drawing. It is shown that additives with relatively high refractive index result in an increased optical transmittance in the visible light wavelength which illustrates that the improvement in optical characteristics probably originates from refractive index matching between the crystalline and noncrystalline regions in the drawn films. Moreover, the optically transparent drawn HDPE films containing additives maintain their physical and mechanical properties, especially their high modulus and high strength, which make these films potentially useful in a variety of applications, such as high-impact windows. FAU - Shen, Lihua AU - Shen L AD - Laboratory of Functional Organic Materials and Devices, Eindhoven University of Technology , P.O. Box 513, Eindhoven 5600 MB, The Netherlands. FAU - Nickmans, Koen AU - Nickmans K AD - Laboratory of Functional Organic Materials and Devices, Eindhoven University of Technology , P.O. Box 513, Eindhoven 5600 MB, The Netherlands. FAU - Severn, John AU - Severn J AD - Laboratory of Functional Organic Materials and Devices, Eindhoven University of Technology , P.O. Box 513, Eindhoven 5600 MB, The Netherlands. AD - DSM Ahead B.V. , NL-6160 MD Geleen, The Netherlands. FAU - Bastiaansen, Cees W M AU - Bastiaansen CW AD - Laboratory of Functional Organic Materials and Devices, Eindhoven University of Technology , P.O. Box 513, Eindhoven 5600 MB, The Netherlands. AD - School of Engineering and Materials Science, Queen Mary, University of London , London E1 4NS, U.K. LA - eng PT - Journal Article DEP - 20160701 PL - United States TA - ACS Appl Mater Interfaces JT - ACS applied materials & interfaces JID - 101504991 OTO - NOTNLM OT - high-density polyethylenes OT - modulus OT - solid state drawing OT - strength OT - transparency EDAT- 2016/06/18 06:00 MHDA- 2016/06/18 06:01 CRDT- 2016/06/18 06:00 PHST- 2016/06/18 06:00 [entrez] PHST- 2016/06/18 06:00 [pubmed] PHST- 2016/06/18 06:01 [medline] AID - 10.1021/acsami.6b04704 [doi] PST - ppublish SO - ACS Appl Mater Interfaces. 2016 Jul 13;8(27):17549-54. doi: 10.1021/acsami.6b04704. Epub 2016 Jul 1.