PMID- 27328881
OWN - NLM
STAT- MEDLINE
DCOM- 20161213
LR  - 20181202
IS  - 1873-3778 (Electronic)
IS  - 0021-9673 (Linking)
VI  - 1456
DP  - 2016 Jul 22
TI  - Zirconium(IV) functionalized magnetic nanocomposites for extraction of 
      organophosphorus pesticides from environmental water samples.
PG  - 49-57
LID - S0021-9673(16)30749-X [pii]
LID - 10.1016/j.chroma.2016.06.005 [doi]
AB  - The widespread use of organophosphate pesticides (OPPs) in agriculture leads to 
      residue accumulation in the environment which is dangerous to human health and 
      disrupts the ecological balance. In this work, one nanocomposite immobilized 
      zirconium (Zr, IV) was prepared and used as the affinity probes to quickly and 
      selectively extract organophosphorus pesticides (OPPs) from water samples. The 
      Fe3O4-ethylenediamine tetraacetic acid (EDTA)@Zr(IV) nanocomposites (NPs) were 
      prepared by simply mixing Zr(IV) ions with Fe3O4-EDTA NPs synthesized by one-pot 
      chemical co-precipitation method. The immobilized Zr(IV) ions were further 
      utilized to capture OPPs based on their high affinity for the phosphate moiety in 
      OPPs. Coupled with GC-MS, four OPPs were used as models to demonstrate the 
      feasibility of this approach. Under the optimum conditions, the limits of 
      detection for target OPPs were in the range of 0.10-10.30ngmL(-1) with relative 
      standard deviations (RSDs) of 0.61-4.40% (n=3), respectively. The linear ranges 
      were over three orders of magnitudes (correlation coefficients, R(2)>0.9995). The 
      Fe3O4-EDTA@Zr(IV) NPs were successfully applied to extract OPPs samples with 
      recoveries of 86.95-112.60% and RSDs of 1.20-10.42% (n=3) from two spiked real 
      water. By the proposed method, the matrix interference could be effectively 
      eliminated. We hope our finding can provide a promising alternative for the fast 
      extraction of OPPs from complex real samples.
CI  - Copyright (c) 2016 Elsevier B.V. All rights reserved.
FAU - Jiang, Li
AU  - Jiang L
AD  - Key Laboratory of Oil Gas & Fine Chemicals, Ministry of Education and Xinjiang 
      Uyghur Autonomous Region, College of Chemistry and Chemical Engineering, Xinjiang 
      University, Urumqi 830046, China.
FAU - Huang, Tengjun
AU  - Huang T
AD  - Key Laboratory of Oil Gas & Fine Chemicals, Ministry of Education and Xinjiang 
      Uyghur Autonomous Region, College of Chemistry and Chemical Engineering, Xinjiang 
      University, Urumqi 830046, China.
FAU - Feng, Shun
AU  - Feng S
AD  - Key Laboratory of Oil Gas & Fine Chemicals, Ministry of Education and Xinjiang 
      Uyghur Autonomous Region, College of Chemistry and Chemical Engineering, Xinjiang 
      University, Urumqi 830046, China. Electronic address: fengshunxd@hotmail.com.
FAU - Wang, Jide
AU  - Wang J
AD  - Key Laboratory of Oil Gas & Fine Chemicals, Ministry of Education and Xinjiang 
      Uyghur Autonomous Region, College of Chemistry and Chemical Engineering, Xinjiang 
      University, Urumqi 830046, China. Electronic address: awangjd@126.com.
LA  - eng
PT  - Journal Article
DEP - 20160603
PL  - Netherlands
TA  - J Chromatogr A
JT  - Journal of chromatography. A
JID - 9318488
RN  - 0 (Magnetite Nanoparticles)
RN  - 0 (Organophosphates)
RN  - 0 (Pesticides)
RN  - 0 (Water Pollutants, Chemical)
RN  - 9G34HU7RV0 (Edetic Acid)
RN  - C6V6S92N3C (Zirconium)
SB  - IM
MH  - Agricultural Irrigation
MH  - Edetic Acid/*chemistry
MH  - Gas Chromatography-Mass Spectrometry/methods
MH  - Humans
MH  - Lakes/chemistry
MH  - Magnetite Nanoparticles/*chemistry
MH  - Nanocomposites/chemistry
MH  - Organophosphates/*isolation & purification
MH  - Pesticides/*isolation & purification
MH  - Solid Phase Extraction/methods
MH  - Water Pollutants, Chemical/*isolation & purification
MH  - Zirconium/*chemistry
OTO - NOTNLM
OT  - Extraction
OT  - Gas chromatography-mass spectrometry
OT  - Magnetic nanocomposites
OT  - Organophosphorus pesticides
OT  - Zirconium
EDAT- 2016/06/23 06:00
MHDA- 2016/12/15 06:00
CRDT- 2016/06/23 06:00
PHST- 2016/04/13 00:00 [received]
PHST- 2016/05/30 00:00 [revised]
PHST- 2016/06/02 00:00 [accepted]
PHST- 2016/06/23 06:00 [entrez]
PHST- 2016/06/23 06:00 [pubmed]
PHST- 2016/12/15 06:00 [medline]
AID - S0021-9673(16)30749-X [pii]
AID - 10.1016/j.chroma.2016.06.005 [doi]
PST - ppublish
SO  - J Chromatogr A. 2016 Jul 22;1456:49-57. doi: 10.1016/j.chroma.2016.06.005. Epub 
      2016 Jun 3.