PMID- 27367178 OWN - NLM STAT- MEDLINE DCOM- 20170316 LR - 20181202 IS - 1879-1298 (Electronic) IS - 0045-6535 (Linking) VI - 160 DP - 2016 Oct TI - Investigation of spatial distributions and sources of persistent organic pollutants (POPs) in a heavily polluted industrial region using tree components. PG - 114-25 LID - S0045-6535(16)30834-7 [pii] LID - 10.1016/j.chemosphere.2016.06.076 [doi] AB - Spatial distributions of persistent organic pollutants (POPs) were investigated in Iskenderun industrial region in Turkey. POP concentrations were measured in different tree components (i.e., pine needle, branch, bark, and stem) collected at several industrial and background sites (n = 27). Also, air, litter, and soil samples were analyzed to determine the relationship of atmospheric pollutants with tree components, litter, and soil. Spatial variation of measured concentrations and factor analysis showed that the iron-steel plants are the most important POP sources in Iskenderun area. Correlations of ambient air levels to those measured in soil, litter, and tree components were significant showing that POPs are exchanged between atmosphere and these compartments. Results have suggested that tree components, litter and soil could be used to determine the spatial distributions and sources of atmospheric POPs in a region. POP quantities (mg/ha) accumulated in different tree components, litter, and soil were also predicted. Generally, the highest quantities were accumulated by stem and needles. In terms of overall inventory, including trees, litter and soil, the highest accumulated quantities were found in soil followed by trees and litter, indicating that in addition to soil, vegetation is a notable reservoir accumulating POPs. Ambient air POP concentrations were also estimated using a bark/air partitioning model. The estimated/measured ratios were close to 1.0 for several compounds and the results showed that the atmospheric POP concentrations could be estimated from the bark measurements within factors of 0.23-3.07, 1.02-6.67, 0.63-7.44, 1.07-3.37 for polycyclic aromatic hydrocarbons, polychlorinated biphenyls, polychlorinated naphthalenes, and polybrominated diphenyl ethers, respectively. CI - Copyright (c) 2016 Elsevier Ltd. All rights reserved. FAU - Odabasi, Mustafa AU - Odabasi M AD - Department of Environmental Engineering, Faculty of Engineering, Dokuz Eylul University, Tinaztepe Campus, 35160, Buca, Izmir, Turkey. Electronic address: mustafa.odabasi@deu.edu.tr. FAU - Dumanoglu, Yetkin AU - Dumanoglu Y AD - Department of Environmental Engineering, Faculty of Engineering, Dokuz Eylul University, Tinaztepe Campus, 35160, Buca, Izmir, Turkey. FAU - Ozgunerge Falay, Ezgi AU - Ozgunerge Falay E AD - Department of Environmental Engineering, Faculty of Engineering, Dokuz Eylul University, Tinaztepe Campus, 35160, Buca, Izmir, Turkey. FAU - Tuna, Gizem AU - Tuna G AD - Department of Environmental Engineering, Faculty of Engineering, Dokuz Eylul University, Tinaztepe Campus, 35160, Buca, Izmir, Turkey. FAU - Altiok, Hasan AU - Altiok H AD - Department of Environmental Engineering, Faculty of Engineering, Dokuz Eylul University, Tinaztepe Campus, 35160, Buca, Izmir, Turkey. FAU - Kara, Melik AU - Kara M AD - Department of Environmental Engineering, Faculty of Engineering, Dokuz Eylul University, Tinaztepe Campus, 35160, Buca, Izmir, Turkey. FAU - Bayram, Abdurrahman AU - Bayram A AD - Department of Environmental Engineering, Faculty of Engineering, Dokuz Eylul University, Tinaztepe Campus, 35160, Buca, Izmir, Turkey. FAU - Tolunay, Doganay AU - Tolunay D AD - Department of Forestry Engineering, Faculty of Forestry, Istanbul University, 34470, Sariyer, Istanbul, Turkey. FAU - Elbir, Tolga AU - Elbir T AD - Department of Environmental Engineering, Faculty of Engineering, Dokuz Eylul University, Tinaztepe Campus, 35160, Buca, Izmir, Turkey. LA - eng PT - Journal Article DEP - 20160629 PL - England TA - Chemosphere JT - Chemosphere JID - 0320657 RN - 0 (Air Pollutants) RN - 0 (Halogenated Diphenyl Ethers) RN - 0 (Industrial Waste) RN - 0 (Polycyclic Aromatic Hydrocarbons) RN - 0 (Soil) RN - 0 (Soil Pollutants) RN - 12597-69-2 (Steel) RN - DFC2HB4I0K (Polychlorinated Biphenyls) SB - IM MH - Air Pollutants/*analysis MH - Atmosphere/analysis MH - Environmental Monitoring/*methods MH - Environmental Pollution/analysis MH - Geography MH - Halogenated Diphenyl Ethers/*analysis MH - Industrial Waste MH - Industry MH - Pinus MH - Polychlorinated Biphenyls/*analysis MH - Polycyclic Aromatic Hydrocarbons/analysis MH - Principal Component Analysis MH - Soil/chemistry MH - Soil Pollutants/*analysis MH - Steel/analysis MH - Trees MH - Turkey OTO - NOTNLM OT - Iskenderun OT - POPs OT - Pine needles OT - Spatial variation OT - Tree bark EDAT- 2016/07/02 06:00 MHDA- 2017/03/17 06:00 CRDT- 2016/07/02 06:00 PHST- 2016/02/12 00:00 [received] PHST- 2016/06/19 00:00 [revised] PHST- 2016/06/20 00:00 [accepted] PHST- 2016/07/02 06:00 [entrez] PHST- 2016/07/02 06:00 [pubmed] PHST- 2017/03/17 06:00 [medline] AID - S0045-6535(16)30834-7 [pii] AID - 10.1016/j.chemosphere.2016.06.076 [doi] PST - ppublish SO - Chemosphere. 2016 Oct;160:114-25. doi: 10.1016/j.chemosphere.2016.06.076. Epub 2016 Jun 29.