PMID- 27398216
OWN - NLM
STAT- PubMed-not-MEDLINE
LR  - 20201001
IS  - 2050-7526 (Print)
IS  - 2050-7534 (Electronic)
IS  - 2050-7526 (Linking)
VI  - 4
IP  - 17
DP  - 2016 May 7
TI  - Solubilised bright blue-emitting iridium complexes for solution processed OLEDs.
PG  - 3726-3737
AB  - Combining a sterically bulky, electron-deficient 
      2-(2,4-difluorophenyl)-4-(2,4,6-trimethylphenyl)pyridine (dFMesppy) 
      cyclometalating C(wedge)N ligand with an electron rich, highly rigidified 
      1,1'-(alpha,alpha'-o-xylylene)-2,2'-biimidazole (o-xylbiim) N(wedge)N ligand gives an iridium 
      complex, [Ir(dFMesppy)(2)(o-xylbiim)](PF(6)), that achieves extraordinarily 
      bright blue emission (Phi(PL) = 90%; lambda(max) = 459 nm in MeCN) for a cationic 
      iridium complex. This complex is compared with two reference complexes bearing 
      4,4'-di-tert-butyl-2,2'-bipyridine, and solution-processed organic light emitting 
      diodes (OLEDs) have been fabricated from these materials.
FAU - Henwood, Adam F
AU  - Henwood AF
AD  - Organic Semiconductor Centre , EaStCHEM School of Chemistry , University of St 
      Andrews , St Andrews , Fife KY16 9ST , UK . Email: 
      eli.zysman-colman@st-andrews.ac.uk ; http://www.zysman-colman.com ; ; Tel: +44 
      (0)1334 463826.
FAU - Bansal, Ashu K
AU  - Bansal AK
AD  - Organic Semiconductor Centre , SUPA , School of Physics and Astronomy , 
      University of St Andrews , Fife , KY16 9SS , UK.
FAU - Cordes, David B
AU  - Cordes DB
AD  - Organic Semiconductor Centre , EaStCHEM School of Chemistry , University of St 
      Andrews , St Andrews , Fife KY16 9ST , UK . Email: 
      eli.zysman-colman@st-andrews.ac.uk ; http://www.zysman-colman.com ; ; Tel: +44 
      (0)1334 463826.
FAU - Slawin, Alexandra M Z
AU  - Slawin AM
AD  - Organic Semiconductor Centre , EaStCHEM School of Chemistry , University of St 
      Andrews , St Andrews , Fife KY16 9ST , UK . Email: 
      eli.zysman-colman@st-andrews.ac.uk ; http://www.zysman-colman.com ; ; Tel: +44 
      (0)1334 463826.
FAU - Samuel, Ifor D W
AU  - Samuel ID
AD  - Organic Semiconductor Centre , SUPA , School of Physics and Astronomy , 
      University of St Andrews , Fife , KY16 9SS , UK.
FAU - Zysman-Colman, Eli
AU  - Zysman-Colman E
AD  - Organic Semiconductor Centre , EaStCHEM School of Chemistry , University of St 
      Andrews , St Andrews , Fife KY16 9ST , UK . Email: 
      eli.zysman-colman@st-andrews.ac.uk ; http://www.zysman-colman.com ; ; Tel: +44 
      (0)1334 463826.
LA  - eng
PT  - Journal Article
DEP - 20160211
PL  - England
TA  - J Mater Chem C Mater
JT  - Journal of materials chemistry. C
JID - 101601114
PMC - PMC4906369
EDAT- 2016/07/12 06:00
MHDA- 2016/07/12 06:01
PMCR- 2016/02/11
CRDT- 2016/07/12 06:00
PHST- 2016/01/12 00:00 [received]
PHST- 2016/02/04 00:00 [accepted]
PHST- 2016/07/12 06:00 [entrez]
PHST- 2016/07/12 06:00 [pubmed]
PHST- 2016/07/12 06:01 [medline]
PHST- 2016/02/11 00:00 [pmc-release]
AID - c6tc00151c [pii]
AID - 10.1039/c6tc00151c [doi]
PST - ppublish
SO  - J Mater Chem C Mater. 2016 May 7;4(17):3726-3737. doi: 10.1039/c6tc00151c. Epub 
      2016 Feb 11.