PMID- 27427399
OWN - NLM
STAT- PubMed-not-MEDLINE
DCOM- 20170801
LR  - 20170801
IS  - 1528-0691 (Electronic)
IS  - 1528-0691 (Linking)
VI  - 16
IP  - 4
DP  - 2016 Aug
TI  - Organocatalyzed Group Transfer Polymerization.
PG  - 2161-83
LID - 10.1002/tcr.201600034 [doi]
AB  - In contrast to the conventional group transfer polymerization (GTP) using a 
      catalyst of either an anionic nucleophile or a transition-metal compound, the 
      organocatalyzed GTP has to a great extent improved the living characteristics of 
      the polymerization from the viewpoints of synthesizing structurally well-defined 
      acrylic polymers and constructing defect-free polymer architectures. In this 
      article, we describe the organocatalyzed GTP from a relatively personal 
      perspective to provide our colleagues with a perspicuous and systematic overview 
      on its recent progress as well as a reply to the curiosity of how excellently the 
      organocatalysts have performed in this field. The stated perspectives of this 
      review mainly cover five aspects, in terms of the assessment of the livingness of 
      the polymerization, limit and scope of applicable monomers, mechanistic studies, 
      control of the polymer structure, and a new GTP methodology involving the use of 
      tris(pentafluorophenyl)borane and hydrosilane.
CI  - (c) 2016 The Chemical Society of Japan & Wiley-VCH Verlag GmbH & Co. KGaA, 
      Weinheim.
FAU - Chen, Yougen
AU  - Chen Y
AD  - Institute for Advanced Study Shenzhen University, Nanshan District Shenzhen, 
      Guangdong, 518060, P. R. China. chenyg@szu.edu.cn.
AD  - Frontier Chemistry Center Faculty of Engineering Hokkaido University, N13 W8, 
      Sapporo, 060-8628, Japan. chenyg@szu.edu.cn.
FAU - Kakuchi, Toyoji
AU  - Kakuchi T
AD  - Frontier Chemistry Center Faculty of Engineering Hokkaido University, N13 W8, 
      Sapporo, 060-8628, Japan.
AD  - Research Center for Polymer Materials School of Materials Science and Engineering 
      Changchun University of Science and Technology, Weixing Road 7989, Changchun 
      Jilin, 130022, P. R. China.
LA  - eng
PT  - Journal Article
PT  - Research Support, Non-U.S. Gov't
DEP - 20160718
PL  - United States
TA  - Chem Rec
JT  - Chemical record (New York, N.Y.)
JID - 101085550
OTO - NOTNLM
OT  - block copolymers
OT  - end functionalization
OT  - group transfer
OT  - organocatalysis
OT  - polymerization
EDAT- 2016/07/19 06:00
MHDA- 2016/07/19 06:01
CRDT- 2016/07/19 06:00
PHST- 2016/02/25 00:00 [received]
PHST- 2016/07/19 06:00 [entrez]
PHST- 2016/07/19 06:00 [pubmed]
PHST- 2016/07/19 06:01 [medline]
AID - 10.1002/tcr.201600034 [doi]
PST - ppublish
SO  - Chem Rec. 2016 Aug;16(4):2161-83. doi: 10.1002/tcr.201600034. Epub 2016 Jul 18.