PMID- 27550439 OWN - NLM STAT- MEDLINE DCOM- 20161228 LR - 20191210 IS - 1573-2959 (Electronic) IS - 0167-6369 (Linking) VI - 188 IP - 9 DP - 2016 Sep TI - Chronic and acute risk assessment of human exposed to novaluron-bifenthrin mixture in cabbage. PG - 528 LID - 10.1007/s10661-016-5536-4 [doi] AB - Based on the dissipation and residual level in cabbage determined by gas chromatography coupled with an electron capture detector (GC-ECD), chronic and acute risk assessments of the novaluron and bifenthrin were investigated. At different spiked levels, mean recoveries were between 81 and 108 % with relative standard deviations (RSDs) from 1.1 to 6.8 %. The limit of quantification (LOQ) was 0.01 mg kg(-1), and good linearity with correlation coefficient (>0.9997) were obtained. The half-lives of novaluron and bifenthrin in cabbage were in the range of 3.2~10 days. Based on the consumption data in China, the risk quotients (RQs) of novaluron and bifenthrin were all below 100 %. The chronic and acute risk of novaluron in cabbage was relatively low, while bifenthrin exerts higher acute risk to humans than chronic risk. The obtained results indicated that the use of novaluron-bifenthrin mixture does not seem to pose any chronic or acute risk to humans even if cabbages are consumed at high application dosages and short preharvest interval (PHI). FAU - Shi, Kaiwei AU - Shi K AD - College of Science, China Agricultural University, Beijing, 100193, China. AD - State Key Laboratory of Integrated Management of Pest Insects and Rodents, Institute of Zoology, Chinese Academy of Sciences, Beijing, 100101, China. FAU - Li, Li AU - Li L AD - State Key Laboratory of Integrated Management of Pest Insects and Rodents, Institute of Zoology, Chinese Academy of Sciences, Beijing, 100101, China. lili2008@ioz.ac.cn. FAU - Li, Wei AU - Li W AD - State Key Laboratory of Integrated Management of Pest Insects and Rodents, Institute of Zoology, Chinese Academy of Sciences, Beijing, 100101, China. FAU - Yuan, Longfei AU - Yuan L AD - State Key Laboratory of Integrated Management of Pest Insects and Rodents, Institute of Zoology, Chinese Academy of Sciences, Beijing, 100101, China. FAU - Liu, Fengmao AU - Liu F AD - College of Science, China Agricultural University, Beijing, 100193, China. liufengmao@cau.edu.cn. LA - eng PT - Journal Article PT - Validation Study DEP - 20160822 PL - Netherlands TA - Environ Monit Assess JT - Environmental monitoring and assessment JID - 8508350 RN - 0 (Pesticide Residues) RN - 0 (Phenylurea Compounds) RN - 0 (Pyrethrins) RN - 6B66JED0KN (bifenthrin) RN - Z8H1B3CW0B (novaluron) SB - IM MH - Brassica/*chemistry MH - China MH - Chromatography, Gas MH - Environmental Monitoring/methods MH - Half-Life MH - Pesticide Residues/*analysis MH - Phenylurea Compounds/*analysis MH - Pyrethrins/*analysis MH - Risk Assessment OTO - NOTNLM OT - Bifenthrin OT - Cabbage OT - Novaluron OT - Risk assessment EDAT- 2016/08/24 06:00 MHDA- 2016/12/29 06:00 CRDT- 2016/08/24 06:00 PHST- 2016/02/29 00:00 [received] PHST- 2016/08/09 00:00 [accepted] PHST- 2016/08/24 06:00 [entrez] PHST- 2016/08/24 06:00 [pubmed] PHST- 2016/12/29 06:00 [medline] AID - 10.1007/s10661-016-5536-4 [pii] AID - 10.1007/s10661-016-5536-4 [doi] PST - ppublish SO - Environ Monit Assess. 2016 Sep;188(9):528. doi: 10.1007/s10661-016-5536-4. Epub 2016 Aug 22.