PMID- 27569252
OWN - NLM
STAT- MEDLINE
DCOM- 20170417
LR  - 20170417
IS  - 1521-3927 (Electronic)
IS  - 1022-1336 (Linking)
VI  - 37
IP  - 20
DP  - 2016 Oct
TI  - A Highly Stretchable and Autonomous Self-Healing Polymer Based on Combination of 
      Pt...Pt and pi-pi Interactions.
PG  - 1667-1675
LID - 10.1002/marc.201600428 [doi]
AB  - A new self-healing polymer has been obtained by incorporating a cyclometalated 
      platinum(II) complex Pt(C(wedge) N(wedge) N)Cl (C(wedge) N(wedge) N = 6-phenyl-2,2'-bipyridyl) 
      into a polydimethylsiloxane (PDMS) backbone. The molecular interactions (a 
      combination of Pt...Pt and pi-pi interactions) between cyclometalated platinum(II) 
      complexes are strong enough to crosslink the linear PDMS polymer chains into an 
      elastic film. The as prepared polymer can be stretched to over 20 times of its 
      original length. When damaged, the polymer can be healed at room temperature 
      without any healants or external stimuli. Moreover, the self-healing is 
      insensitive to surface aging. This work represents the first example where the 
      attractive metallophilic inter-actions are utilized to design self-healing 
      materials. Moreover, our results suggest that the stretchability and self-healing 
      properties can be obtained simultaneously without any conflict by optimizing the 
      strength of crosslinking interactions.
CI  - (c) 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
FAU - Mei, Jin-Feng
AU  - Mei JF
AD  - State Key laboratory of Coordination Chemistry, School of Chemistry and Chemical 
      Engineering, Collaborative Innovation Center of Advanced Microstructures, Nanjing 
      University, Nanjing, 210093, China.
FAU - Jia, Xiao-Yong
AU  - Jia XY
AD  - State Key laboratory of Coordination Chemistry, School of Chemistry and Chemical 
      Engineering, Collaborative Innovation Center of Advanced Microstructures, Nanjing 
      University, Nanjing, 210093, China.
FAU - Lai, Jian-Cheng
AU  - Lai JC
AD  - State Key laboratory of Coordination Chemistry, School of Chemistry and Chemical 
      Engineering, Collaborative Innovation Center of Advanced Microstructures, Nanjing 
      University, Nanjing, 210093, China.
FAU - Sun, Yang
AU  - Sun Y
AD  - State Key laboratory of Coordination Chemistry, School of Chemistry and Chemical 
      Engineering, Collaborative Innovation Center of Advanced Microstructures, Nanjing 
      University, Nanjing, 210093, China.
AD  - National Laboratory of Solid State Microstructure, Department of Physics, 
      Collaborative Innovation Center of Advanced Microstructures, Nanjing University, 
      Nanjing, 210093, China.
FAU - Li, Cheng-Hui
AU  - Li CH
AD  - State Key laboratory of Coordination Chemistry, School of Chemistry and Chemical 
      Engineering, Collaborative Innovation Center of Advanced Microstructures, Nanjing 
      University, Nanjing, 210093, China. chli@nju.edu.cn.
FAU - Wu, Jun-Hua
AU  - Wu JH
AD  - National Laboratory of Solid State Microstructure, Department of Physics, 
      Collaborative Innovation Center of Advanced Microstructures, Nanjing University, 
      Nanjing, 210093, China.
FAU - Cao, Yi
AU  - Cao Y
AD  - National Laboratory of Solid State Microstructure, Department of Physics, 
      Collaborative Innovation Center of Advanced Microstructures, Nanjing University, 
      Nanjing, 210093, China.
FAU - You, Xiao-Zeng
AU  - You XZ
AD  - State Key laboratory of Coordination Chemistry, School of Chemistry and Chemical 
      Engineering, Collaborative Innovation Center of Advanced Microstructures, Nanjing 
      University, Nanjing, 210093, China. youxz@nju.edu.cn.
FAU - Bao, Zhenan
AU  - Bao Z
AD  - Department of Chemical Engineering, Stanford University, Stanford, CA, 94305, 
      USA. zbao@stanford.edu.
LA  - eng
PT  - Journal Article
DEP - 20160829
PL  - Germany
TA  - Macromol Rapid Commun
JT  - Macromolecular rapid communications
JID - 9888239
RN  - 0 (Organoplatinum Compounds)
RN  - 0 (Polymers)
SB  - IM
MH  - Microscopy, Atomic Force
MH  - Organoplatinum Compounds/*chemistry
MH  - Polymers/chemical synthesis/*chemistry
OTO - NOTNLM
OT  - platinum complexes
OT  - polymers
OT  - self-healing
OT  - stretchable
EDAT- 2016/10/19 06:00
MHDA- 2017/04/18 06:00
CRDT- 2016/08/30 06:00
PHST- 2016/07/08 00:00 [received]
PHST- 2016/07/21 00:00 [revised]
PHST- 2016/10/19 06:00 [pubmed]
PHST- 2017/04/18 06:00 [medline]
PHST- 2016/08/30 06:00 [entrez]
AID - 10.1002/marc.201600428 [doi]
PST - ppublish
SO  - Macromol Rapid Commun. 2016 Oct;37(20):1667-1675. doi: 10.1002/marc.201600428. 
      Epub 2016 Aug 29.