PMID- 27618901 OWN - NLM STAT- MEDLINE DCOM- 20180205 LR - 20181113 IS - 1424-8220 (Electronic) IS - 1424-8220 (Linking) VI - 16 IP - 9 DP - 2016 Aug 27 TI - Identifying Plant Part Composition of Forest Logging Residue Using Infrared Spectral Data and Linear Discriminant Analysis. LID - 10.3390/s16091375 [doi] LID - 1375 AB - As new markets, technologies and economies evolve in the low carbon bioeconomy, forest logging residue, a largely untapped renewable resource will play a vital role. The feedstock can however be variable depending on plant species and plant part component. This heterogeneity can influence the physical, chemical and thermochemical properties of the material, and thus the final yield and quality of products. Although it is challenging to control compositional variability of a batch of feedstock, it is feasible to monitor this heterogeneity and make the necessary changes in process parameters. Such a system will be a first step towards optimization, quality assurance and cost-effectiveness of processes in the emerging biofuel/chemical industry. The objective of this study was therefore to qualitatively classify forest logging residue made up of different plant parts using both near infrared spectroscopy (NIRS) and Fourier transform infrared spectroscopy (FTIRS) together with linear discriminant analysis (LDA). Forest logging residue harvested from several Pinus taeda (loblolly pine) plantations in Alabama, USA, were classified into three plant part components: clean wood, wood and bark and slash (i.e., limbs and foliage). Five-fold cross-validated linear discriminant functions had classification accuracies of over 96% for both NIRS and FTIRS based models. An extra factor/principal component (PC) was however needed to achieve this in FTIRS modeling. Analysis of factor loadings of both NIR and FTIR spectra showed that, the statistically different amount of cellulose in the three plant part components of logging residue contributed to their initial separation. This study demonstrated that NIR or FTIR spectroscopy coupled with PCA and LDA has the potential to be used as a high throughput tool in classifying the plant part makeup of a batch of forest logging residue feedstock. Thus, NIR/FTIR could be employed as a tool to rapidly probe/monitor the variability of forest biomass so that the appropriate online adjustments to parameters can be made in time to ensure process optimization and product quality. FAU - Acquah, Gifty E AU - Acquah GE AD - Forest Products Development Center, School of Forestry and Wildlife Sciences, Auburn University, 520 Devall Drive, Auburn, AL 36849, USA. gea0002@auburn.edu. FAU - Via, Brian K AU - Via BK AD - Forest Products Development Center, School of Forestry and Wildlife Sciences, Auburn University, 520 Devall Drive, Auburn, AL 36849, USA. bkv0003@auburn.edu. FAU - Billor, Nedret AU - Billor N AD - Department of Mathematics and Statistics, Auburn University, Auburn, AL 36849, USA. billone@auburn.edu. FAU - Fasina, Oladiran O AU - Fasina OO AD - Center for Bioenergy and Bioproducts, Department of Biosystems Engineering, Auburn University, 350 Mell Street, Auburn, AL 36849, USA. fasinoo@auburn.edu. FAU - Eckhardt, Lori G AU - Eckhardt LG AD - Forest Health Dynamics Laboratory, School of Forestry and Wildlife Sciences, Auburn University, 602 Duncan Drive, Auburn, AL 36849, USA. eckhalg@auburn.edu. LA - eng PT - Journal Article DEP - 20160827 PL - Switzerland TA - Sensors (Basel) JT - Sensors (Basel, Switzerland) JID - 101204366 SB - IM MH - *Discriminant Analysis MH - *Forests MH - Plants/*anatomy & histology MH - Principal Component Analysis MH - Reproducibility of Results MH - Spectroscopy, Fourier Transform Infrared MH - Spectroscopy, Near-Infrared PMC - PMC5038653 OTO - NOTNLM OT - bioeconomy OT - forest biomass OT - fourier transform infrared spectroscopy OT - linear discriminant analysis OT - near infrared spectroscopy OT - principal component analysis OT - process optimization COIS- The authors declare no conflict of interest. EDAT- 2016/09/14 06:00 MHDA- 2018/02/06 06:00 PMCR- 2016/09/01 CRDT- 2016/09/14 06:00 PHST- 2016/05/21 00:00 [received] PHST- 2016/08/22 00:00 [revised] PHST- 2016/08/23 00:00 [accepted] PHST- 2016/09/14 06:00 [entrez] PHST- 2016/09/14 06:00 [pubmed] PHST- 2018/02/06 06:00 [medline] PHST- 2016/09/01 00:00 [pmc-release] AID - s16091375 [pii] AID - sensors-16-01375 [pii] AID - 10.3390/s16091375 [doi] PST - epublish SO - Sensors (Basel). 2016 Aug 27;16(9):1375. doi: 10.3390/s16091375.