PMID- 27640057
OWN - NLM
STAT- MEDLINE
DCOM- 20170522
LR  - 20191210
IS  - 1614-7499 (Electronic)
IS  - 0944-1344 (Linking)
VI  - 24
IP  - 7
DP  - 2017 Mar
TI  - Study of the degradation performance (TOC, BOD, and toxicity) of bisphenol A by 
      the photo-Fenton process.
PG  - 6241-6251
LID - 10.1007/s11356-016-7386-6 [doi]
AB  - Degradation of bisphenol A (BPA, 0.5 L, 30 mg L(-1)) was studied by photo-Fenton 
      treatment, while Fenton reagents were variables. The efficiency of the 
      degradation process was evaluated by the reduction of total organic carbon (TOC), 
      the biochemical oxygen demand (BOD), and toxicity. For toxicity analysis, 
      bacterial methods were found infeasible, but the in vitro assay of VERO cells 
      culture was successfully applied. Experiments according to a 2(2) design of 
      experiments (DOE) with star points and three center points for statistical 
      validity allowed selecting those process conditions (Fe(II) and H(2)O(2) load) 
      that maximized the process performance. Photo-Fenton process effectively 
      eliminated BPA and partly degraded its by-products (residual TOC <15 %) under 
      substoichiometric H(2)O(2) dose (100.62 mg L(-1)) and at least 4 mg L(-1) Fe(II), 
      after a 90-min treatment. All treated samples were at least partially 
      biodegradable. The cytotoxic concentration (LD(50)) of BPA for VERO cells was 
      7 mg L(-1). With small H(2)O(2) amount (15.24 mg L(-1)), only low BPA 
      mineralization (TOC = 92 %) was attained. Toxicity was also detected to 50 % of 
      cellular mortality even at long reaction times. However, 40.25 mg L(-1) of 
      H(2)O(2) decreased residual TOC to 70 % while cell mortality decreased down to 
      25 %. With more H(2)O(2), the residual TOC decreased down to 15 % but cell 
      mortality remained within the 20-25 % level. Photo-Fenton increased the 
      biodegradability and reduced the toxicity of the studied sample.
FAU - Perez-Moya, M
AU  - Perez-Moya M
AD  - EUETIB-CEIB, Chemical Engineering Department, UPC. BARCELONATECH, C/Comte 
      d'Urgell 187, 08036, Barcelona, Spain. montserrat.perez-moya@upc.edu.
FAU - Kaisto, T
AU  - Kaisto T
AD  - Faculty of Technology, Lahti University of Applied Sciences, Niemenkatu 73, 
      15101, Lahti, Finland.
FAU - Navarro, M
AU  - Navarro M
AD  - EUETIB-CEIB, Chemical Engineering Department, UPC. BARCELONATECH, C/Comte 
      d'Urgell 187, 08036, Barcelona, Spain.
FAU - Del Valle, L J
AU  - Del Valle LJ
AD  - Center for Research in Nano-Engineering (CrNE), and ETSEIB, Chemical Engineering 
      Department, UPC. BARCELONATECH, Av Diagonal 647, 08028, Barcelona, Spain.
LA  - eng
PT  - Journal Article
DEP - 20160917
PL  - Germany
TA  - Environ Sci Pollut Res Int
JT  - Environmental science and pollution research international
JID - 9441769
RN  - 0 (Benzhydryl Compounds)
RN  - 0 (Fenton's reagent)
RN  - 0 (Phenols)
RN  - 0 (Water Pollutants, Chemical)
RN  - 7440-44-0 (Carbon)
RN  - BBX060AN9V (Hydrogen Peroxide)
RN  - E1UOL152H7 (Iron)
RN  - MLT3645I99 (bisphenol A)
SB  - IM
MH  - Animals
MH  - Benzhydryl Compounds/*chemistry/*toxicity
MH  - *Biological Oxygen Demand Analysis
MH  - Carbon/*analysis
MH  - Chlorocebus aethiops
MH  - Hydrogen Peroxide/*chemistry
MH  - Iron/*chemistry
MH  - Oxidation-Reduction
MH  - Phenols/*chemistry/*toxicity
MH  - *Photolysis
MH  - Vero Cells
MH  - Water Pollutants, Chemical/chemistry/toxicity
OTO - NOTNLM
OT  - Advanced oxidation processes
OT  - Biodegradability
OT  - Bisphenol A
OT  - Contaminant of emerging concern
OT  - Fenton and photo-Fenton reactions
OT  - Toxicity
EDAT- 2016/09/19 06:00
MHDA- 2017/05/23 06:00
CRDT- 2016/09/19 06:00
PHST- 2016/02/29 00:00 [received]
PHST- 2016/08/03 00:00 [accepted]
PHST- 2016/09/19 06:00 [pubmed]
PHST- 2017/05/23 06:00 [medline]
PHST- 2016/09/19 06:00 [entrez]
AID - 10.1007/s11356-016-7386-6 [pii]
AID - 10.1007/s11356-016-7386-6 [doi]
PST - ppublish
SO  - Environ Sci Pollut Res Int. 2017 Mar;24(7):6241-6251. doi: 
      10.1007/s11356-016-7386-6. Epub 2016 Sep 17.