PMID- 27640759 OWN - NLM STAT- MEDLINE DCOM- 20170321 LR - 20181202 IS - 1873-6424 (Electronic) IS - 0269-7491 (Linking) VI - 220 IP - Pt A DP - 2017 Jan TI - Evidence for persistent organic pollutants released from melting glacier in the central Tibetan Plateau, China. PG - 178-185 LID - S0269-7491(16)31272-6 [pii] LID - 10.1016/j.envpol.2016.09.037 [doi] AB - Glacier alluvial deposits record persistent organic pollutants (POPs) not only derived from the atmospheric deposition but also from the release of glacial melting. The evidence for melting glacier in the Tibetan Plateau (TP) as a secondary source of pollutants is introduced through investigating the concentration of organochlorine pesticides (OCPs) in four deposited profiles collected at the edge of the Changwengluozha glacier. Two concentration peaks were observed for dichlorodiphenyltrichloroethanes (DDTs) and hexachlorocyclohexanes (HCHs) in the past century. The first peak was observed in the 1970s, corresponding with the heavy usage of HCHs and DDTs in the surrounding countries and regions. The second one was in 2000 when the production and usage of DDTs and HCHs were strictly limited, which possibly indicated a significant release from melting glacier. This result was further supported by the enantiomeric fraction values for alpha-HCH and o,p'-DDT. On the other hand, the dramatic increase of polycyclic aromatic hydrocarbons (PAHs) from atmospheric deposition, which was associated with the socioeconomic development in Tibet, shaded the release of PAHs from melting glacier. This study reveals not only the air deposition history of legacy POPs but also a substantial release of OCPs from glacier to the adjacent environment. Our research supports the hypothesis that the melting glacier in the TP represents a secondary source of OCPs, which is consistent with the findings in the Alps glaciers. CI - Copyright A(c) 2016 Elsevier Ltd. All rights reserved. FAU - Li, Jun AU - Li J AD - State Key Laboratory of Biogeology and Environmental Geology, China University of Geosciences, Beijing 100083, China; School of the Earth Sciences and Resources, China University of Geosciences, Beijing 100083, China. FAU - Yuan, Guo-Li AU - Yuan GL AD - State Key Laboratory of Biogeology and Environmental Geology, China University of Geosciences, Beijing 100083, China; School of the Earth Sciences and Resources, China University of Geosciences, Beijing 100083, China. Electronic address: yuangl@cugb.edu.cn. FAU - Wu, Ming-Zhe AU - Wu MZ AD - School of the Earth Sciences and Resources, China University of Geosciences, Beijing 100083, China. FAU - Sun, Yong AU - Sun Y AD - School of the Earth Sciences and Resources, China University of Geosciences, Beijing 100083, China. FAU - Han, Peng AU - Han P AD - School of the Earth Sciences and Resources, China University of Geosciences, Beijing 100083, China. FAU - Wang, Gen-Hou AU - Wang GH AD - School of the Earth Sciences and Resources, China University of Geosciences, Beijing 100083, China. LA - eng PT - Journal Article DEP - 20160915 PL - England TA - Environ Pollut JT - Environmental pollution (Barking, Essex : 1987) JID - 8804476 RN - 0 (Hydrocarbons, Chlorinated) RN - 0 (Pesticides) RN - 0 (Polycyclic Aromatic Hydrocarbons) SB - IM MH - *Environmental Monitoring MH - Geologic Sediments/*chemistry MH - Hydrocarbons, Chlorinated/*analysis MH - Ice Cover/*chemistry MH - Pesticides/*analysis MH - Polycyclic Aromatic Hydrocarbons/*analysis MH - Tibet OTO - NOTNLM OT - Glacial release OT - Historical records OT - Organochlorine pesticides OT - Polycyclic aromatic hydrocarbons OT - Tibetan Plateau EDAT- 2016/09/20 06:00 MHDA- 2017/03/23 06:00 CRDT- 2016/09/20 06:00 PHST- 2016/07/01 00:00 [received] PHST- 2016/08/30 00:00 [revised] PHST- 2016/09/12 00:00 [accepted] PHST- 2016/09/20 06:00 [pubmed] PHST- 2017/03/23 06:00 [medline] PHST- 2016/09/20 06:00 [entrez] AID - S0269-7491(16)31272-6 [pii] AID - 10.1016/j.envpol.2016.09.037 [doi] PST - ppublish SO - Environ Pollut. 2017 Jan;220(Pt A):178-185. doi: 10.1016/j.envpol.2016.09.037. Epub 2016 Sep 15.