PMID- 27667650
OWN - NLM
STAT- MEDLINE
DCOM- 20170223
LR  - 20181202
IS  - 1873-3778 (Electronic)
IS  - 0021-9673 (Linking)
VI  - 1468
DP  - 2016 Oct 14
TI  - Hydrothermally grown and self-assembled modified titanium and nickel oxide 
      composite nanosheets on Nitinol-based fibers for efficient solid phase 
      microextraction.
PG  - 33-41
LID - S0021-9673(16)31254-7 [pii]
LID - 10.1016/j.chroma.2016.09.038 [doi]
AB  - A novel titanium and nickel oxide composite nanosheets (TiO(2)/NiOCNSs) coating 
      was in situ grown on a Nitinol (NiTi) wire by direct hydrothermal treatment and 
      modified by self-assembly of trichlorophenylsilane for solid phase 
      microextraction (SPME). TiO(2)/NiOCNSs were radially oriented and chemically 
      bonded to the NiTi substrate with double-faced open access sites. Moreover the 
      phenyl modified TiO(2)/NiOCNSs (TiO(2)/NiOCNSs-Ph) coating exhibited original 
      surface supporting framework favorable for effective SPME. The extraction 
      performance of TiO(2)/NiOCNSs-Ph coated NiTi (NiTi-TiO(2)/NiOCNSs-Ph) fiber was 
      investigated for the concentration and detection of ultraviolet (UV) filters, 
      polycyclic aromatic hydrocarbons (PAHs), phthalate acid esters and 
      polychlorinated biphenyls coupled to HPLC with UV detection. The novel fiber 
      exhibited better selectivity for UV filters and PAHs and presented greater 
      extraction capability compared to commercial polydimethylsiloxane and 
      polyacrylate fibers. Under the optimized conditions for SPME of UV filters, the 
      proposed method presented linear ranges from 0.1 to 300mug/L with correlation 
      coefficients of higher than 0.999 and limits of detection from 0.030mug/L to 
      0.064mug/L. Relative standard deviations (RSDs) were below 7.16% and 8.42% for 
      intra-day and inter-day measurements with the single fiber, respectively. 
      Furthermore RSDs for fiber-to-fiber reproducibility from 6.57% to 8.93% were 
      achieved. The NiTi-TiO(2)/NiOCNSs-Ph fiber can be used up to 200 times. The 
      proposed method was successfully applied to the preconcentration and 
      determination of trace target UV filters in different environmental water 
      samples. The relative recoveries from 87.3% to 104% were obtained with RSDs less 
      than 8.7%.
CI  - Copyright (c) 2016 Elsevier B.V. All rights reserved.
FAU - Wang, Huiju
AU  - Wang H
AD  - College of Chemistry and Chemical Engineering, Northwest Normal University, 
      Lanzhou, 730070, China.
FAU - Song, Wenlan
AU  - Song W
AD  - College of Chemistry and Chemical Engineering, Northwest Normal University, 
      Lanzhou, 730070, China.
FAU - Zhang, Min
AU  - Zhang M
AD  - College of Chemistry and Chemical Engineering, Northwest Normal University, 
      Lanzhou, 730070, China.
FAU - Zhen, Qi
AU  - Zhen Q
AD  - College of Chemistry and Chemical Engineering, Northwest Normal University, 
      Lanzhou, 730070, China.
FAU - Guo, Mei
AU  - Guo M
AD  - College of Chemistry and Chemical Engineering, Northwest Normal University, 
      Lanzhou, 730070, China.
FAU - Zhang, Yida
AU  - Zhang Y
AD  - College of Chemistry and Chemical Engineering, Northwest Normal University, 
      Lanzhou, 730070, China.
FAU - Du, Xinzhen
AU  - Du X
AD  - College of Chemistry and Chemical Engineering, Northwest Normal University, 
      Lanzhou, 730070, China; Key Lab of Bioelectrochemistry & Environmental Analysis 
      of Gansu, Lanzhou, 730070, China. Electronic address: duxz@nwnu.edu.cn.
LA  - eng
PT  - Journal Article
DEP - 20160920
PL  - Netherlands
TA  - J Chromatogr A
JT  - Journal of chromatography. A
JID - 9318488
RN  - 0 (Alloys)
RN  - 0 (Phthalic Acids)
RN  - 0 (Polycyclic Aromatic Hydrocarbons)
RN  - 0 (Water Pollutants, Chemical)
RN  - 2EWL73IJ7F (nitinol)
RN  - 6O7F7IX66E (phthalic acid)
RN  - 7OV03QG267 (Nickel)
RN  - C3574QBZ3Y (nickel monoxide)
RN  - D1JT611TNE (Titanium)
SB  - IM
MH  - Alloys/*chemistry
MH  - Chemistry Techniques, Analytical/*methods
MH  - Chromatography, High Pressure Liquid
MH  - Nickel/*chemistry
MH  - Phthalic Acids/analysis
MH  - Polycyclic Aromatic Hydrocarbons/analysis
MH  - Reproducibility of Results
MH  - Solid Phase Microextraction/*methods
MH  - Titanium/*chemistry
MH  - Water Pollutants, Chemical/*analysis
OTO - NOTNLM
OT  - *Aromatic compounds
OT  - *Environmental water
OT  - *Hydrothermal growth
OT  - *Nitinol
OT  - *Solid phase microextraction
OT  - *Titanium and nickel oxide composite nanosheets
EDAT- 2016/09/27 06:00
MHDA- 2017/02/24 06:00
CRDT- 2016/09/27 06:00
PHST- 2016/04/20 00:00 [received]
PHST- 2016/09/14 00:00 [revised]
PHST- 2016/09/19 00:00 [accepted]
PHST- 2016/09/27 06:00 [pubmed]
PHST- 2017/02/24 06:00 [medline]
PHST- 2016/09/27 06:00 [entrez]
AID - S0021-9673(16)31254-7 [pii]
AID - 10.1016/j.chroma.2016.09.038 [doi]
PST - ppublish
SO  - J Chromatogr A. 2016 Oct 14;1468:33-41. doi: 10.1016/j.chroma.2016.09.038. Epub 
      2016 Sep 20.