PMID- 27745676
OWN - NLM
STAT- MEDLINE
DCOM- 20170216
LR  - 20170906
IS  - 1001-0742 (Print)
IS  - 1001-0742 (Linking)
VI  - 48
DP  - 2016 Oct
TI  - Enhanced dechlorination of 2,4-dichlorophenol by recoverable Ni/Fe-Fe(3)O(4) 
      nanocomposites.
PG  - 92-101
LID - S1001-0742(16)30041-9 [pii]
LID - 10.1016/j.jes.2015.10.033 [doi]
AB  - Ni/Fe-Fe(3)O(4) nanocomposites were synthesized for dechlorination of 
      2,4-dichlorophenol (2,4-DCP). The effects of the Ni content in Ni/Fe-Fe(3)O(4) 
      nanocomposites, solution pH, and common dissolved ions on the dechlorination 
      efficiency were investigated, in addition to the reusability of the 
      nanocomposites. The results showed that increasing content of Ni in 
      Ni/Fe-Fe(3)O(4) nanocomposites, from 1 to 5wt.%, greatly increased the 
      dechlorination efficiency; the Ni/Fe-Fe(3)O(4) nanocomposites had much higher 
      dechlorination efficiency than bare Ni/Fe nanoparticles. Ni content of 5wt.% and 
      initial pH below 6.0 was found to be the optimal conditions for the catalytic 
      dechlorination of 2,4-DCP. Both 2,4-DCP and the intermediate product 
      2-chlorophenol (2-CP) were completely removed, and the concentration of the final 
      product phenol was close to the theoretical phenol production from complete 
      dechlorination of 20mg/L of 2,4-DCP, after 3hr reaction at initial pH value of 
      6.0, 3g/L Ni/Fe-Fe(3)O(4), 5wt.% Ni content in the composite, and temperature of 
      22 degrees C. 2,4-DCP dechlorination was enhanced by Cl(-) and inhibited by NO(3)(-) and 
      SO(4)(2-). The nanocomposites were easily separated from the solution by an 
      applied magnetic field. When the catalyst was reused, the removal efficiency of 
      2,4-DCP was almost 100% for the first seven uses, and gradually decreased to 75% 
      in cycles 8-10. Therefore, the Ni/Fe-Fe(3)O(4) nanocomposites can be considered 
      as a potentially effective tool for remediation of pollution by 2,4-DCP.
CI  - Copyright (c) 2016. Published by Elsevier B.V.
FAU - Xu, Cancan
AU  - Xu C
AD  - Zhejiang Provincial Key Laboratory of Water Science and Technology, Department of 
      Environment, Yangtze Delta Region Institute of Tsinghua University, Zhejiang, 
      Jiaxing 314006, China. Electronic address: xucancan523127@163.com.
FAU - Liu, Rui
AU  - Liu R
AD  - Zhejiang Provincial Key Laboratory of Water Science and Technology, Department of 
      Environment, Yangtze Delta Region Institute of Tsinghua University, Zhejiang, 
      Jiaxing 314006, China. Electronic address: liuruitsinghuazj@gmail.com.
FAU - Chen, Lvjun
AU  - Chen L
AD  - Zhejiang Provincial Key Laboratory of Water Science and Technology, Department of 
      Environment, Yangtze Delta Region Institute of Tsinghua University, Zhejiang, 
      Jiaxing 314006, China; School of Environment, Tsinghua University, Beijing 
      100084, China. Electronic address: chenlj@tsinghua.edu.cn.
FAU - Tang, Jialu
AU  - Tang J
AD  - Zhejiang Provincial Key Laboratory of Water Science and Technology, Department of 
      Environment, Yangtze Delta Region Institute of Tsinghua University, Zhejiang, 
      Jiaxing 314006, China.
LA  - eng
PT  - Journal Article
DEP - 20160325
PL  - Netherlands
TA  - J Environ Sci (China)
JT  - Journal of environmental sciences (China)
JID - 100967627
RN  - 0 (Chlorophenols)
RN  - 0 (Ferrous Compounds)
RN  - 0 (Water Pollutants, Chemical)
RN  - 7OV03QG267 (Nickel)
RN  - G7036X8B5H (ferrous oxide)
RN  - R669TG1950 (2,4-dichlorophenol)
SB  - IM
MH  - Chlorophenols/*chemistry
MH  - Environmental Restoration and Remediation/*methods
MH  - Ferrous Compounds/*chemistry
MH  - Halogenation
MH  - Nanocomposites/*chemistry
MH  - Nickel/*chemistry
MH  - Waste Disposal, Fluid/methods
MH  - Water Pollutants, Chemical/*chemistry
OTO - NOTNLM
OT  - 2,4-Dichlorophenol
OT  - Catalytic dechlorination
OT  - Common dissolved ions
OT  - Ni/Fe-Fe(3)O(4) nanocomposites
OT  - Recoverable
EDAT- 2016/10/18 06:00
MHDA- 2017/02/17 06:00
CRDT- 2016/10/18 06:00
PHST- 2015/04/17 00:00 [received]
PHST- 2015/10/09 00:00 [revised]
PHST- 2015/10/21 00:00 [accepted]
PHST- 2016/10/18 06:00 [entrez]
PHST- 2016/10/18 06:00 [pubmed]
PHST- 2017/02/17 06:00 [medline]
AID - S1001-0742(16)30041-9 [pii]
AID - 10.1016/j.jes.2015.10.033 [doi]
PST - ppublish
SO  - J Environ Sci (China). 2016 Oct;48:92-101. doi: 10.1016/j.jes.2015.10.033. Epub 
      2016 Mar 25.