PMID- 27749082
OWN - NLM
STAT- PubMed-not-MEDLINE
DCOM- 20180608
LR  - 20180608
IS  - 1520-5827 (Electronic)
IS  - 0743-7463 (Linking)
VI  - 32
IP  - 44
DP  - 2016 Nov 8
TI  - Metal-Organic Framework-Polymer Composite as a Highly Efficient Sorbent for 
      Sulfonamide Adsorption and Desorption: Effect of Coordinatively Unsaturated Metal 
      Site and Topology.
PG  - 11465-11473
AB  - In this study, we first demonstrated the effect of two types of metal-organic 
      framework-polymer (MOF-polymer) monoliths on in-tube solid-phase microextraction 
      (IT-SPME) of sulfonamides. Sulfonamides were successfully adsorbed onto 
      MIL-101(Cr)-polymer but were difficult to elute due to these sulfonamides could 
      interact via Lewis acid-base interaction with the presence of Cr(III) 
      coordinatively unsaturated metal sites (CUS). Moreover, the cage-type topology of 
      MIL-101(Cr) that could produce multiple pathways thus complicates the desorption 
      of the test analytes from the sorbent. Contrastingly, MIL-53(Al)-polymer provided 
      weaker Al(III) CUS, and its one-dimensional channel pore structure could provide 
      an unhindered pathway for sulfonamides transfer during elution. After optimizing 
      the IT-SPME condition such as MOF content, pH of sample matrix, column length, 
      extraction flow rate, and elution volume, the calculated extraction recovery of 
      sulfonamides in MIL-53(Al)-polymer as analyzed by microemulsion electrokinetic 
      chromatography (MEEKC) were in the range of 40%-90% with relative standard 
      deviations (RSDs) below 5% and a reusability of at least 30 times.
FAU - Shih, Yung-Han
AU  - Shih YH
AD  - Department of Chemistry, Chung Yuan Christian University 200 Chung Pei Road, 
      Chung Li District, Taoyuan City, 320, Taiwan, R.O.C.
FAU - Wang, Kuen-Yun
AU  - Wang KY
AD  - Department of Chemistry, Chung Yuan Christian University 200 Chung Pei Road, 
      Chung Li District, Taoyuan City, 320, Taiwan, R.O.C.
FAU - Singco, Brenda
AU  - Singco B
AD  - Department of Chemistry, Chung Yuan Christian University 200 Chung Pei Road, 
      Chung Li District, Taoyuan City, 320, Taiwan, R.O.C.
FAU - Lin, Chia-Her
AU  - Lin CH
AD  - Department of Chemistry, Chung Yuan Christian University 200 Chung Pei Road, 
      Chung Li District, Taoyuan City, 320, Taiwan, R.O.C.
FAU - Huang, Hsi-Ya
AU  - Huang HY
AD  - Department of Chemistry, Chung Yuan Christian University 200 Chung Pei Road, 
      Chung Li District, Taoyuan City, 320, Taiwan, R.O.C.
LA  - eng
PT  - Journal Article
PT  - Research Support, Non-U.S. Gov't
DEP - 20161024
PL  - United States
TA  - Langmuir
JT  - Langmuir : the ACS journal of surfaces and colloids
JID - 9882736
EDAT- 2016/10/18 06:00
MHDA- 2016/10/18 06:01
CRDT- 2016/10/18 06:00
PHST- 2016/10/18 06:00 [pubmed]
PHST- 2016/10/18 06:01 [medline]
PHST- 2016/10/18 06:00 [entrez]
AID - 10.1021/acs.langmuir.6b03067 [doi]
PST - ppublish
SO  - Langmuir. 2016 Nov 8;32(44):11465-11473. doi: 10.1021/acs.langmuir.6b03067. Epub 
      2016 Oct 24.