PMID- 27754679
OWN - NLM
STAT- PubMed-not-MEDLINE
DCOM- 20180608
LR  - 20180608
IS  - 1523-7052 (Electronic)
IS  - 1523-7052 (Linking)
VI  - 18
IP  - 21
DP  - 2016 Nov 4
TI  - The Catalyst-Controlled Regiodivergent Chlorination of Phenols.
PG  - 5476-5479
AB  - Different catalysts are demonstrated to overcome or augment a substrate's innate 
      regioselectivity. Nagasawa's bis-thiourea catalyst was found to overcome the 
      innate para-selectivity of electrophilic phenol chlorination, yielding 
      ortho-chlorinated phenols that are not readily obtainable via canonical 
      electrophilic chlorinations. Conversely, a phosphine sulfide derived from 
      2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl (BINAP) was found to enhance the 
      innate para-preference of phenol chlorination.
FAU - Maddox, Sean M
AU  - Maddox SM
AD  - Department of Chemistry and Biochemistry, San Diego State University , 5500 
      Campanile Drive, San Diego, California 92182, United States.
FAU - Dinh, Andrew N
AU  - Dinh AN
AD  - Department of Chemistry and Biochemistry, San Diego State University , 5500 
      Campanile Drive, San Diego, California 92182, United States.
FAU - Armenta, Felipe
AU  - Armenta F
AD  - Department of Chemistry and Biochemistry, San Diego State University , 5500 
      Campanile Drive, San Diego, California 92182, United States.
FAU - Um, Joann
AU  - Um J
AD  - Department of Physical Sciences, Southwestern College , 900 Otay Lakes Road, 
      Chula Vista, California 91910, United States.
FAU - Gustafson, Jeffrey L
AU  - Gustafson JL
AD  - Department of Chemistry and Biochemistry, San Diego State University , 5500 
      Campanile Drive, San Diego, California 92182, United States.
LA  - eng
PT  - Journal Article
PT  - Research Support, Non-U.S. Gov't
DEP - 20161018
PL  - United States
TA  - Org Lett
JT  - Organic letters
JID - 100890393
EDAT- 2016/11/05 06:00
MHDA- 2016/11/05 06:01
CRDT- 2016/11/05 06:00
PHST- 2016/11/05 06:00 [pubmed]
PHST- 2016/11/05 06:01 [medline]
PHST- 2016/11/05 06:00 [entrez]
AID - 10.1021/acs.orglett.6b02650 [doi]
PST - ppublish
SO  - Org Lett. 2016 Nov 4;18(21):5476-5479. doi: 10.1021/acs.orglett.6b02650. Epub 
      2016 Oct 18.