PMID- 27763696
OWN - NLM
STAT- MEDLINE
DCOM- 20180509
LR  - 20180509
IS  - 1521-3765 (Electronic)
IS  - 0947-6539 (Linking)
VI  - 22
IP  - 52
DP  - 2016 Dec 23
TI  - Nanoscale Mn(II) -Coordination Polymers for Cell Imaging and Heterogeneous 
      Catalysis.
PG  - 18963-18974
LID - 10.1002/chem.201604604 [doi]
AB  - A mixed ligand approach was exploited to synthesize a new series of Mn(II) -based 
      coordination polymers (CPs), namely, CP1 [Mn(mu-dpa)(mu-4,4'-bp)]⋅MeOH(infinity) , CP2 
      [Mn(3) (mu-dpa)(3) (2,2'-bp)(2) ](infinity) , CP3 [Mn(3) (mu-dpa)(3) (1,10-phen)(2) 
      ]⋅2 H(2) O(infinity) , CP4 [Mn(mu-dpa)(mu-4,4'-bpe)(1.5) ]⋅H(2) O(infinity) , CP5 [Mn(2) 
      (mu-dpa)(2) (mu-4,4'-bpe)(2) ]⋅1/2  DEF(infinity) , and CP6 [Mn(mu-dpa)(mu-4,4'-bpe)(1.5) 
      ]⋅1/2  DMA(infinity) (dpa=3,5-dicarboxyphenyl azide, 2,2'-bp=2,2'-bipyridine, 
      1,10-phen=1,10-phenanthroline, 4,4'-bpe=1,2-bis(4-pyridyl)ethylene, 
      4,4'-bp=4,4'-bipyridine, DEF=N,N-diethylformamide, DMA=N,N-dimethylacetamide), to 
      develop multifunctional CPs. Various techniques, such as single-crystal X-ray 
      diffraction (SXRD), FTIR spectroscopy, elemental analysis, and thermogravimetric 
      analysis, were employed to fully characterize these CPs. The majority of the CPs 
      displayed a four-connected sql topology, whereas CP4 and CP6 exhibited a 
      two-dimensional SnS network architecture, which was further entangled in a 
      polycatenation mode. Compound CP1 displayed an open framework structure. The CPs 
      were scaled down to the nanoregime in a ball mill for cell imaging studies. 
      Whereas CP2 and CP4 were employed for cell imaging with RAW264.7 cells, CP1 was 
      exploited for both cell imaging and heterogeneous catalysis in a cyanosilylation 
      reaction.
CI  - (c) 2016 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
FAU - Sarkar, Koushik
AU  - Sarkar K
AD  - Department of Organic Chemistry, Indian Association for the Cultivation of 
      Science (IACS), 2 A and 2 B, Raja S. C. Mullick Road, Jadavpur, Kolkata, 700032, 
      West Bengal, India.
FAU - Dastidar, Parthasarathi
AU  - Dastidar P
AUID- ORCID: 0000-0002-1011-2386
AD  - Department of Organic Chemistry, Indian Association for the Cultivation of 
      Science (IACS), 2 A and 2 B, Raja S. C. Mullick Road, Jadavpur, Kolkata, 700032, 
      West Bengal, India.
LA  - eng
PT  - Journal Article
DEP - 20161116
PL  - Germany
TA  - Chemistry
JT  - Chemistry (Weinheim an der Bergstrasse, Germany)
JID - 9513783
RN  - 0 (Coordination Complexes)
RN  - 0 (Ligands)
RN  - 0 (Phenanthrolines)
RN  - 0 (Polymers)
RN  - 42Z2K6ZL8P (Manganese)
RN  - 617-84-5 (N,N-diethylformamide)
RN  - 8696NH0Y2X (Dimethylformamide)
RN  - W4X6ZO7939 (1,10-phenanthroline)
SB  - IM
EIN - Chemistry. 2019 Sep 18;25(52):12228. PMID: 31531904
MH  - Catalysis
MH  - Coordination Complexes/*chemistry
MH  - Crystallography, X-Ray
MH  - Dimethylformamide/*analogs & derivatives/chemistry
MH  - Ligands
MH  - Manganese/*chemistry
MH  - Nanotechnology
MH  - Phenanthrolines/*chemistry
MH  - Polymers/*chemistry
MH  - X-Ray Diffraction
OTO - NOTNLM
OT  - SnS topology
OT  - cell imaging
OT  - coordination polymers
OT  - cyanosilylation
OT  - polycatenation
EDAT- 2016/10/21 06:00
MHDA- 2018/05/10 06:00
CRDT- 2016/10/21 06:00
PHST- 2016/09/29 00:00 [received]
PHST- 2016/10/21 06:00 [pubmed]
PHST- 2018/05/10 06:00 [medline]
PHST- 2016/10/21 06:00 [entrez]
AID - 10.1002/chem.201604604 [doi]
PST - ppublish
SO  - Chemistry. 2016 Dec 23;22(52):18963-18974. doi: 10.1002/chem.201604604. Epub 2016 
      Nov 16.