PMID- 27770453
OWN - NLM
STAT- MEDLINE
DCOM- 20170929
LR  - 20180412
IS  - 1522-2683 (Electronic)
IS  - 0173-0835 (Linking)
VI  - 38
IP  - 3-4
DP  - 2017 Feb
TI  - Capillary electrophoresis with contactless conductivity detection for the 
      quantification of fluoride in lithium ion battery electrolytes and in ionic 
      liquids-A comparison to the results gained with a fluoride ion-selective 
      electrode.
PG  - 533-539
LID - 10.1002/elps.201600361 [doi]
AB  - In this study, an optimized method using capillary electrophoresis (CE) with a 
      direct contactless conductivity detector (C(4) D) for a new application field is 
      presented for the quantification of fluoride in common used lithium ion battery 
      (LIB) electrolyte using LiPF(6) in organic carbonate solvents and in ionic 
      liquids (ILs) after contacted to Li metal. The method development for finding the 
      right buffer and the suitable CE conditions for the quantification of fluoride 
      was investigated. The results of the concentration of fluoride in different LIB 
      electrolyte samples were compared to the results from the ion-selective electrode 
      (ISE). The relative standard deviations (RSDs) and recovery rates for fluoride 
      were obtained with a very high accuracy in both methods. The results of the 
      fluoride concentration in the LIB electrolytes were in very good agreement for 
      both methods. In addition, the limit of detection (LOD) and limit of 
      quantification (LOQ) values were determined for the CE method. The CE method has 
      been applied also for the quantification of fluoride in ILs. In the fresh IL 
      sample, the concentration of fluoride was under the LOD. Another sample of the IL 
      mixed with Li metal has been investigated as well. It was possible to quantify 
      the fluoride concentration in this sample.
CI  - (c) 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
FAU - Pyschik, Marcelina
AU  - Pyschik M
AD  - University of Muenster, MEET Battery Research Center, Institute of Physical 
      Chemistry, Munster, Germany.
FAU - Klein-Hitpass, Marcel
AU  - Klein-Hitpass M
AD  - University of Muenster, MEET Battery Research Center, Institute of Physical 
      Chemistry, Munster, Germany.
FAU - Girod, Sabrina
AU  - Girod S
AD  - University of Muenster, MEET Battery Research Center, Institute of Physical 
      Chemistry, Munster, Germany.
FAU - Winter, Martin
AU  - Winter M
AD  - University of Muenster, MEET Battery Research Center, Institute of Physical 
      Chemistry, Munster, Germany.
AD  - Helmholtz Institute Munster, IEK-12, Forschungszentrum Julich, Munster, Germany.
FAU - Nowak, Sascha
AU  - Nowak S
AD  - University of Muenster, MEET Battery Research Center, Institute of Physical 
      Chemistry, Munster, Germany.
LA  - eng
PT  - Journal Article
DEP - 20161115
PL  - Germany
TA  - Electrophoresis
JT  - Electrophoresis
JID - 8204476
RN  - 0 (Electrolytes)
RN  - 0 (Ionic Liquids)
RN  - 9FN79X2M3F (Lithium)
RN  - Q80VPU408O (Fluorides)
SB  - IM
MH  - Electric Conductivity
MH  - Electric Power Supplies
MH  - Electrolytes/*chemistry
MH  - Electrophoresis, Capillary/instrumentation/*methods
MH  - Fluorides/*analysis
MH  - Ion-Selective Electrodes
MH  - Ionic Liquids/*chemistry
MH  - Limit of Detection
MH  - Lithium
MH  - Reproducibility of Results
OTO - NOTNLM
OT  - Capillary electrophoresis
OT  - Contactless conductivity detector
OT  - Fluoride quantification
OT  - Ionic liquids
OT  - Lithium ion battery electrolytes
EDAT- 2016/10/23 06:00
MHDA- 2017/09/30 06:00
CRDT- 2016/10/23 06:00
PHST- 2016/08/03 00:00 [received]
PHST- 2016/10/18 00:00 [revised]
PHST- 2016/10/19 00:00 [accepted]
PHST- 2016/10/23 06:00 [pubmed]
PHST- 2017/09/30 06:00 [medline]
PHST- 2016/10/23 06:00 [entrez]
AID - 10.1002/elps.201600361 [doi]
PST - ppublish
SO  - Electrophoresis. 2017 Feb;38(3-4):533-539. doi: 10.1002/elps.201600361. Epub 2016 
      Nov 15.