PMID- 27810532
OWN - NLM
STAT- MEDLINE
DCOM- 20170329
LR  - 20181202
IS  - 1879-1298 (Electronic)
IS  - 0045-6535 (Linking)
VI  - 168
DP  - 2017 Feb
TI  - Mechanochemical remediation of PCB contaminated soil.
PG  - 333-340
LID - S0045-6535(16)31458-8 [pii]
LID - 10.1016/j.chemosphere.2016.10.073 [doi]
AB  - Soil contaminated by polychlorinated biphenyls (PCBs) is a ubiquitous problem in 
      the world, which can cause significant risks to human health and the environment. 
      Mechanochemical destruction (MCD) has been recognized as a promising technology 
      for the destruction of persistent organic pollutants (POPs) and other organic 
      molecules in both solid waste and contaminated soil. However, few studies have 
      been published about the application of MCD technology for the remediation of PCB 
      contaminated soil. In the present study, the feasibility of destroying PCBs in 
      contaminated soil by co-grinding with and without additives in a planetary ball 
      mill was investigated. After 4 h milling time, more than 96% of PCBs in 
      contaminated soil samples were destroyed. The residual concentrations of PCBs 
      decreased from 1000 mg/kg to below the provisional Basel Convention limit of less 
      than 50 mg/kg. PCDD/F present in the original soil at levels of 4200 ng TEQ/kg 
      was also destroyed with even a slightly higher destruction efficiency. Only minor 
      dechlorinations of the PCBs were observed and the destruction of the hydrocarbon 
      skeleton is proposed as the main degradation pathway of PCBs.
CI  - Copyright (c) 2016 Elsevier Ltd. All rights reserved.
FAU - Wang, Haizhu
AU  - Wang H
AD  - State Key Joint Laboratory of Environment Simulation and Pollution Control 
      (SKJLESPC), Beijing Key Laboratory for Emerging Organic Contaminants Control, 
      School of Environment, POPs Research Center, Tsinghua University, Beijing, 
      100084, PR China; State Key Laboratory of High Power Semiconductor Laser, 
      Changchun University of Science and Technology, Changchun, 130022, PR China.
FAU - Hwang, Jisu
AU  - Hwang J
AD  - State Key Joint Laboratory of Environment Simulation and Pollution Control 
      (SKJLESPC), Beijing Key Laboratory for Emerging Organic Contaminants Control, 
      School of Environment, POPs Research Center, Tsinghua University, Beijing, 
      100084, PR China.
FAU - Huang, Jun
AU  - Huang J
AD  - State Key Joint Laboratory of Environment Simulation and Pollution Control 
      (SKJLESPC), Beijing Key Laboratory for Emerging Organic Contaminants Control, 
      School of Environment, POPs Research Center, Tsinghua University, Beijing, 
      100084, PR China. Electronic address: huangjun@tsinghua.edu.cn.
FAU - Xu, Ying
AU  - Xu Y
AD  - School of Physics, Northeast Normal University, Changchun, 130024, PR China.
FAU - Yu, Gang
AU  - Yu G
AD  - State Key Joint Laboratory of Environment Simulation and Pollution Control 
      (SKJLESPC), Beijing Key Laboratory for Emerging Organic Contaminants Control, 
      School of Environment, POPs Research Center, Tsinghua University, Beijing, 
      100084, PR China.
FAU - Li, Wenchao
AU  - Li W
AD  - CSD IDEA (Beijing) Environmental Test & Analysis Co. Ltd, Beijing, 100192, PR 
      China.
FAU - Zhang, Kunlun
AU  - Zhang K
AD  - State Key Joint Laboratory of Environment Simulation and Pollution Control 
      (SKJLESPC), Beijing Key Laboratory for Emerging Organic Contaminants Control, 
      School of Environment, POPs Research Center, Tsinghua University, Beijing, 
      100084, PR China.
FAU - Liu, Kai
AU  - Liu K
AD  - State Key Joint Laboratory of Environment Simulation and Pollution Control 
      (SKJLESPC), Beijing Key Laboratory for Emerging Organic Contaminants Control, 
      School of Environment, POPs Research Center, Tsinghua University, Beijing, 
      100084, PR China.
FAU - Cao, Zhiguo
AU  - Cao Z
AD  - State Key Joint Laboratory of Environment Simulation and Pollution Control 
      (SKJLESPC), Beijing Key Laboratory for Emerging Organic Contaminants Control, 
      School of Environment, POPs Research Center, Tsinghua University, Beijing, 
      100084, PR China.
FAU - Ma, Xiaohui
AU  - Ma X
AD  - State Key Laboratory of High Power Semiconductor Laser, Changchun University of 
      Science and Technology, Changchun, 130022, PR China.
FAU - Wei, Zhipeng
AU  - Wei Z
AD  - State Key Laboratory of High Power Semiconductor Laser, Changchun University of 
      Science and Technology, Changchun, 130022, PR China.
FAU - Wang, Quhui
AU  - Wang Q
AD  - State Key Laboratory of High Power Semiconductor Laser, Changchun University of 
      Science and Technology, Changchun, 130022, PR China.
LA  - eng
PT  - Journal Article
DEP - 20161027
PL  - England
TA  - Chemosphere
JT  - Chemosphere
JID - 0320657
RN  - 0 (Soil)
RN  - 0 (Soil Pollutants)
RN  - 24H4NWX5CO (Kaolin)
RN  - DFC2HB4I0K (Polychlorinated Biphenyls)
SB  - IM
MH  - China
MH  - Environmental Pollution/prevention & control
MH  - Humans
MH  - Kaolin
MH  - Polychlorinated Biphenyls/analysis/*chemistry
MH  - Soil/*chemistry
MH  - Soil Pollutants/*chemistry
OTO - NOTNLM
OT  - Dechlorination
OT  - Mechanochemical technology
OT  - PCB contaminated soil
EDAT- 2016/11/05 06:00
MHDA- 2017/03/31 06:00
CRDT- 2016/11/05 06:00
PHST- 2016/08/16 00:00 [received]
PHST- 2016/10/18 00:00 [revised]
PHST- 2016/10/20 00:00 [accepted]
PHST- 2016/11/05 06:00 [pubmed]
PHST- 2017/03/31 06:00 [medline]
PHST- 2016/11/05 06:00 [entrez]
AID - S0045-6535(16)31458-8 [pii]
AID - 10.1016/j.chemosphere.2016.10.073 [doi]
PST - ppublish
SO  - Chemosphere. 2017 Feb;168:333-340. doi: 10.1016/j.chemosphere.2016.10.073. Epub 
      2016 Oct 27.