PMID- 27815608
OWN - NLM
STAT- MEDLINE
DCOM- 20180221
LR  - 20221207
IS  - 1618-2650 (Electronic)
IS  - 1618-2642 (Linking)
VI  - 409
IP  - 1
DP  - 2017 Jan
TI  - In-syringe dispersive mu-SPE of estrogens using magnetic carbon microparticles 
      obtained from zeolitic imidazolate frameworks.
PG  - 225-234
LID - 10.1007/s00216-016-9988-8 [doi]
AB  - Herein, we propose for the first time the use of magnetic porous carbons (MPCs) 
      derived from zeolitic imidazolate frameworks (ZIFs) for the automated in-syringe 
      magnetic dispersive micro-solid phase extraction (D-mu-SPE) of environmental 
      pollutants prior to their analysis using GC-MS. MPCs with dual porosity are 
      obtained from the direct combustion of the ZIF-67, obtaining robust and magnetic 
      porous carbons on the micrometer scale. As proof of concept, this material has 
      been applied for the automated D-mu-SPE of estrogens (estrone, 17beta-estradiol, and 
      17alpha-ethynylestradiol) cataloged as Contaminants of Emergent Concern by the 
      Environmental Protection Agency of the United States (US-EPA). The automation of 
      the system provided a good precision given the low relative standard deviations 
      (RSDs) obtained, ranging from 2.70 to 5.90 % for intra-day precision and from 4.6 
      to 9.55 % for inter-day precision. Furthermore, the clean-up and preconcentration 
      of the sample is easy and quick, as the in-syringe magnetic D-mu-SPE is carried 
      out in less than 20 min. The high porosity, magnetism, and good stability of the 
      MPCs facilitated the automation of the SPE in dispersive mode enabling the 
      analysis of samples with a complex matrix without backpressure or problems 
      related with the clogging of the instrumentation conduits. The applicability of 
      the method to wastewater samples has been demonstrated given the good recoveries 
      attained ranging from 86 to 115 %. Graphical abstract In-syringe dispersive mu-SPE 
      of estrogens using magnetic carbon microparticles prior GC-MS.
FAU - Gonzalez, Alba
AU  - Gonzalez A
AD  - Group of Analytical Chemistry, Automation and Environment, Department of 
      Chemistry, University of the Balearic Islands, Carretera de Valldemossa km 7,5, 
      07122, Palma de Mallorca, Spain.
FAU - Avivar, Jessica
AU  - Avivar J
AD  - Sciware Systems, S.L. Spin-off of the University of the Balearic Islands, 07193, 
      Bunyola, Spain.
FAU - Maya, Fernando
AU  - Maya F
AD  - Group of Analytical Chemistry, Automation and Environment, Department of 
      Chemistry, University of the Balearic Islands, Carretera de Valldemossa km 7,5, 
      07122, Palma de Mallorca, Spain.
FAU - Palomino Cabello, Carlos
AU  - Palomino Cabello C
AD  - Group of Analytical Chemistry, Automation and Environment, Department of 
      Chemistry, University of the Balearic Islands, Carretera de Valldemossa km 7,5, 
      07122, Palma de Mallorca, Spain.
FAU - Turnes Palomino, Gemma
AU  - Turnes Palomino G
AD  - Group of Analytical Chemistry, Automation and Environment, Department of 
      Chemistry, University of the Balearic Islands, Carretera de Valldemossa km 7,5, 
      07122, Palma de Mallorca, Spain.
FAU - Cerda, Victor
AU  - Cerda V
AD  - Group of Analytical Chemistry, Automation and Environment, Department of 
      Chemistry, University of the Balearic Islands, Carretera de Valldemossa km 7,5, 
      07122, Palma de Mallorca, Spain. victor.cerda@uib.es.
AD  - Sciware Systems, S.L. Spin-off of the University of the Balearic Islands, 07193, 
      Bunyola, Spain. victor.cerda@uib.es.
LA  - eng
PT  - Evaluation Study
PT  - Journal Article
DEP - 20161104
PL  - Germany
TA  - Anal Bioanal Chem
JT  - Analytical and bioanalytical chemistry
JID - 101134327
RN  - 0 (Environmental Pollutants)
RN  - 0 (Estrogens)
RN  - 0 (Waste Water)
RN  - 0 (Water Pollutants, Chemical)
RN  - 1318-02-1 (Zeolites)
RN  - 7440-44-0 (Carbon)
SB  - IM
MH  - Carbon/*chemistry
MH  - Environmental Pollutants/analysis/*isolation & purification
MH  - Equipment Design
MH  - Estrogens/analysis/*isolation & purification
MH  - Gas Chromatography-Mass Spectrometry/methods
MH  - Limit of Detection
MH  - Magnets/*chemistry
MH  - Porosity
MH  - Solid Phase Microextraction/*instrumentation/methods
MH  - Syringes
MH  - Wastewater/analysis
MH  - Water Pollutants, Chemical/analysis/*isolation & purification
MH  - Zeolites/*chemistry
OTO - NOTNLM
OT  - Automation
OT  - Dispersive microsolid phase extraction
OT  - Estrogens
OT  - Gas chromatography-mass spectrometry
OT  - Magnetic porous carbons
OT  - Zeolitic imidazolate frameworks
EDAT- 2016/11/07 06:00
MHDA- 2018/02/22 06:00
CRDT- 2016/11/06 06:00
PHST- 2016/07/22 00:00 [received]
PHST- 2016/09/27 00:00 [accepted]
PHST- 2016/09/16 00:00 [revised]
PHST- 2016/11/07 06:00 [pubmed]
PHST- 2018/02/22 06:00 [medline]
PHST- 2016/11/06 06:00 [entrez]
AID - 10.1007/s00216-016-9988-8 [pii]
AID - 10.1007/s00216-016-9988-8 [doi]
PST - ppublish
SO  - Anal Bioanal Chem. 2017 Jan;409(1):225-234. doi: 10.1007/s00216-016-9988-8. Epub 
      2016 Nov 4.