PMID- 27841277 OWN - NLM STAT- PubMed-not-MEDLINE DCOM- 20180404 LR - 20181113 IS - 2045-2322 (Electronic) IS - 2045-2322 (Linking) VI - 6 DP - 2016 Nov 14 TI - Layered double hydroxide of Cd-Al/C for the Mineralization and De-coloration of Dyes in Solar and Visible Light Exposure. PG - 35107 LID - 10.1038/srep35107 [doi] LID - 35107 AB - Cd-Al/C layered double hydroxide (Cd-Al/C-LDH) and Cd-Sb/C nanocatalyst are reported here for the de-coloration and mineralization of organic dyes. These catalysts were largely characterized by FESEM, EDS, XRD, FTIR, XPS, PL and DRS. The diffuse reflectance data showed a band gap at 2.92 and 2.983 eV for Cd-Al/C-LDH and Cd-Sb/C respectively. The band gap suggested that both catalysts work well in visible range. The photoluminescence spectra indicated a peak at 623 nm for both the catalysts which further support the effectiveness of the respective catalyst in visible range. Both catalysts also showed good recyclability and durability till 4(th) cycle. Five dyes, acridine orange (AO), malachite green (MG), crystal violet (CV), congo red (CR) and methyl orange (MO) were used in this experiment. Various parameters of different light intensity such as visible, ultraviolet, sunlight and dark condition are observed for the de-coloration of these dyes. The de-coloration phenomenon was proceeded through adsorption assisted phot-degradation. The low cost, abundant nature, good recyclability and better dye removal efficiency make these catalysts suitable candidates for the de-coloration and mineralization of organic dyes. FAU - Khan, Shahid Ali AU - Khan SA AD - Center of Excellence for Advanced Materials Research, King Abdulaziz University, Jeddah 21589, P. O. Box 80203, Saudi Arabia. AD - Chemistry Department, Faculty of Science, King Abdulaziz University, P. O. Box 80203, Jeddah 21589, Saudi Arabia. FAU - Khan, Sher Bahadar AU - Khan SB AD - Center of Excellence for Advanced Materials Research, King Abdulaziz University, Jeddah 21589, P. O. Box 80203, Saudi Arabia. AD - Chemistry Department, Faculty of Science, King Abdulaziz University, P. O. Box 80203, Jeddah 21589, Saudi Arabia. FAU - Asiri, Abdullah M AU - Asiri AM AD - Center of Excellence for Advanced Materials Research, King Abdulaziz University, Jeddah 21589, P. O. Box 80203, Saudi Arabia. AD - Chemistry Department, Faculty of Science, King Abdulaziz University, P. O. Box 80203, Jeddah 21589, Saudi Arabia. LA - eng PT - Journal Article DEP - 20161114 PL - England TA - Sci Rep JT - Scientific reports JID - 101563288 PMC - PMC5107898 EDAT- 2016/11/15 06:00 MHDA- 2016/11/15 06:01 PMCR- 2016/11/14 CRDT- 2016/11/15 06:00 PHST- 2016/05/27 00:00 [received] PHST- 2016/09/26 00:00 [accepted] PHST- 2016/11/15 06:00 [entrez] PHST- 2016/11/15 06:00 [pubmed] PHST- 2016/11/15 06:01 [medline] PHST- 2016/11/14 00:00 [pmc-release] AID - srep35107 [pii] AID - 10.1038/srep35107 [doi] PST - epublish SO - Sci Rep. 2016 Nov 14;6:35107. doi: 10.1038/srep35107.