PMID- 27847230 OWN - NLM STAT- MEDLINE DCOM- 20170501 LR - 20221207 IS - 1879-2456 (Electronic) IS - 0956-053X (Linking) VI - 59 DP - 2017 Jan TI - Fate of emerging and priority micropollutants during the sewage sludge treatment: Case study of Paris conurbation. Part 1: Contamination of the different types of sewage sludge. PG - 379-393 LID - S0956-053X(16)30668-7 [pii] LID - 10.1016/j.wasman.2016.11.010 [doi] AB - This article provides data on the contamination of different kinds of sludge (raw, centrifuged, digested, thermally dried sludge and sludge cake) from Paris conurbation by 71 various pollutants including pharmaceutical products (PHPs), hormones, perfluorinated acids (PFAs), linear alkylbenzene sulfonate (LAS), alkylphenols (APs), phthalates (PAEs), polycyclic aromatic hydrocarbons (PAHs) and polychlorobiphenyls (PCBs). Very high contents of LAS (0.1-10g/kg dry matter - DM) compared to other compounds were found in all types of sludge followed by DEHP (10-100mg/kg DM) and fluoroquinolones (1-100mg/kg DM). APs were measured at intermediary contents in Parisian sludge, lying in the 2-20mg/kg DM range. Finally, hormones, PAHs, PCBs, PAEs, PFAs and the remaining PHPs were all found at contents lower than 1mg/kg DM. For most compounds (PHPs, PFOS, DEHP, PAHs), no significant differences in the micropollutant contents were found for similar types of sludge from different WWTP in Paris, highlighting the homogeneity of sludge contamination in downstream Paris catchment. The variability of concentration is rather high (coefficient of variation >100%) for several PHPs, PFAs or PCBs while it is moderate (<100%) or low (<50%) for fluoroquinolones, hormones, PAHs, APs or LAS. In addition, digestion seems to have a buffer effect as variabilities are lower in digested sludge for PHPs, PFAs, APs and PCBs. During sludge treatment (centrifugation, digestion, thermal drying, sludge conditioning+press filtration), the hormones, LAS, APs, PAHs, DEHP and PCBs concentrations increased, while those of PHPs and PFAs decreased. In the case of digestion, the increase of content can be explained by no pollutant removal or a lower removal than DM removal (concentration phenomenon) whereas the decrease underlines that the compound is more removed than the DM. In any case, these concentration variations presuppose the mechanisms of dissipation that could be attributed to volatilization, biotic or abiotic transformation (complete or with metabolites production), bound residues formation. In addition, data on sludge liquors - centrifuged (CW) and condensed (TDW) waters - from respectively centrifugation and thermal drying were collected. Several hormones, PHPs, PFAs, LAS, PAEs, APs, PCBs and PAHs were quantified in CW and TDW, displaying a transfer through the water removal. The concentrations observed are rather comparable to those found in wastewater. CI - Copyright (c) 2016 Elsevier Ltd. All rights reserved. FAU - Mailler, R AU - Mailler R AD - SIAAP, Direction du Developpement et de la Prospective, 82 avenue Kleber, 92700 Colombes, France. Electronic address: romain.mailler@siaap.fr. FAU - Gasperi, J AU - Gasperi J AD - LEESU (UMR MA 102, Universite Paris-Est, Agro ParisTech), 61 avenue du General De Gaulle, 94010 Creteil Cedex, France. Electronic address: gasperi@u-pec.fr. FAU - Patureau, D AU - Patureau D AD - LBE, INRA, 11100 Narbonne, France. FAU - Vulliet, E AU - Vulliet E AD - Universite de Lyon, Institut des Sciences Analytiques, UMR 5280 CNRS, Universite Lyon 1, ENS-Lyon, 5 rue de la Doua, 69100 Villeurbanne, France. FAU - Delgenes, N AU - Delgenes N AD - LBE, INRA, 11100 Narbonne, France. FAU - Danel, A AU - Danel A AD - LBE, INRA, 11100 Narbonne, France. FAU - Deshayes, S AU - Deshayes S AD - LEESU (UMR MA 102, Universite Paris-Est, Agro ParisTech), 61 avenue du General De Gaulle, 94010 Creteil Cedex, France; LCPP (UMR 0050, INRA), 39 bis rue de Dantzig, 75015 Paris, France. FAU - Eudes, V AU - Eudes V AD - LCPP (UMR 0050, INRA), 39 bis rue de Dantzig, 75015 Paris, France. FAU - Guerin, S AU - Guerin S AD - SIAAP, Direction du Developpement et de la Prospective, 82 avenue Kleber, 92700 Colombes, France. FAU - Moilleron, R AU - Moilleron R AD - LEESU (UMR MA 102, Universite Paris-Est, Agro ParisTech), 61 avenue du General De Gaulle, 94010 Creteil Cedex, France. FAU - Chebbo, G AU - Chebbo G AD - LEESU (UMR MA 102, Universite Paris-Est, Agro ParisTech), 6-8 avenue Blaise Pascal, Champs-sur-Marne, 77455 Marne-la-Vallee Cedex 2, France. FAU - Rocher, V AU - Rocher V AD - SIAAP, Direction du Developpement et de la Prospective, 82 avenue Kleber, 92700 Colombes, France. Electronic address: vincent.rocher@siaap.fr. LA - eng PT - Journal Article DEP - 20161112 PL - United States TA - Waste Manag JT - Waste management (New York, N.Y.) JID - 9884362 RN - 0 (Alkanesulfonic Acids) RN - 0 (Hormones) RN - 0 (Pharmaceutical Preparations) RN - 0 (Polycyclic Aromatic Hydrocarbons) RN - 0 (Sewage) RN - 0 (Waste Water) RN - 0 (Water Pollutants, Chemical) RN - 0 (alkylbenzyl sulfonic acid) RN - DFC2HB4I0K (Polychlorinated Biphenyls) SB - IM MH - Alkanesulfonic Acids/chemistry MH - Desiccation MH - Hormones/analysis MH - Paris MH - Pharmaceutical Preparations/analysis MH - Polychlorinated Biphenyls/*analysis MH - Polycyclic Aromatic Hydrocarbons/*chemistry MH - Sewage/chemistry MH - Temperature MH - Waste Disposal, Fluid/*methods MH - Wastewater/*chemistry MH - Water Pollutants, Chemical/*analysis MH - Water Purification/methods OTO - NOTNLM OT - Emerging pollutants OT - Priority substances OT - Sewage sludge OT - Sludge liquor OT - Sludge treatment EDAT- 2016/11/17 06:00 MHDA- 2017/05/02 06:00 CRDT- 2016/11/17 06:00 PHST- 2016/06/09 00:00 [received] PHST- 2016/09/27 00:00 [revised] PHST- 2016/11/04 00:00 [accepted] PHST- 2016/11/17 06:00 [pubmed] PHST- 2017/05/02 06:00 [medline] PHST- 2016/11/17 06:00 [entrez] AID - S0956-053X(16)30668-7 [pii] AID - 10.1016/j.wasman.2016.11.010 [doi] PST - ppublish SO - Waste Manag. 2017 Jan;59:379-393. doi: 10.1016/j.wasman.2016.11.010. Epub 2016 Nov 12.