PMID- 27847312
OWN - NLM
STAT- PubMed-not-MEDLINE
DCOM- 20180108
LR  - 20180717
IS  - 1873-3557 (Electronic)
IS  - 1386-1425 (Linking)
VI  - 173
DP  - 2017 Feb 15
TI  - The alternative use of layered double hydroxides as extraction medium coupled 
      with microcomplexation for determination of phosphate in water samples.
PG  - 994-1000
LID - S1386-1425(16)30655-2 [pii]
LID - 10.1016/j.saa.2016.11.002 [doi]
AB  - A simple, rapid, in situ, and green extraction combined with a microcomplexation 
      has been developed for the spectrophotometric determination of phosphate in water 
      samples. Through their formation, layered double hydroxides (LDHs) were employed 
      as the extraction medium, instantly commenced by a rapid addition of a mixed 
      solution of Mg(2+) and Al(3+) ions into alkaline phosphate solution. After the 
      extraction, LDH precipitate containing phosphate was dissolved by sulfuric acid 
      and the released phosphate was subsequently detected via its complexation with 
      molybdate in the presence of antimonyl and ascorbic acid. Under optimum 
      conditions, the linearity in the range of 5-200mugL(-1), with the correlation 
      coefficient (r(2)) of 0.9969, and the enrichment factor (EF) of 14 were obtained. 
      The limit of detection (LOD) of 5mugL(-1) and good precision, with the relative 
      standard deviations (RSDs) less than 8.16%, were achieved. The proposed method 
      was successfully applied to determine phosphate in water samples and the relative 
      recoveries of 72.97-115.32% were obtained.
CI  - Copyright (c) 2016 Elsevier B.V. All rights reserved.
FAU - Gissawong, Netsirin
AU  - Gissawong N
AD  - Materials Chemistry Research Center, Department of Chemistry and Center of 
      Excellence for Innovation in Chemistry, Faculty of Science, Khon Kaen University, 
      Khon Kaen 40002, Thailand.
FAU - Sansuk, Sira
AU  - Sansuk S
AD  - Materials Chemistry Research Center, Department of Chemistry and Center of 
      Excellence for Innovation in Chemistry, Faculty of Science, Khon Kaen University, 
      Khon Kaen 40002, Thailand.
FAU - Srijaranai, Supalax
AU  - Srijaranai S
AD  - Materials Chemistry Research Center, Department of Chemistry and Center of 
      Excellence for Innovation in Chemistry, Faculty of Science, Khon Kaen University, 
      Khon Kaen 40002, Thailand. Electronic address: supalax@kku.ac.th.
LA  - eng
PT  - Journal Article
DEP - 20161103
PL  - England
TA  - Spectrochim Acta A Mol Biomol Spectrosc
JT  - Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy
JID - 9602533
OTO - NOTNLM
OT  - Extraction medium
OT  - Layered double hydroxides
OT  - Phosphate
OT  - UV-vis spectrophotometry
OT  - Water sample
EDAT- 2016/11/17 06:00
MHDA- 2016/11/17 06:01
CRDT- 2016/11/17 06:00
PHST- 2016/04/07 00:00 [received]
PHST- 2016/08/12 00:00 [revised]
PHST- 2016/11/01 00:00 [accepted]
PHST- 2016/11/17 06:00 [pubmed]
PHST- 2016/11/17 06:01 [medline]
PHST- 2016/11/17 06:00 [entrez]
AID - S1386-1425(16)30655-2 [pii]
AID - 10.1016/j.saa.2016.11.002 [doi]
PST - ppublish
SO  - Spectrochim Acta A Mol Biomol Spectrosc. 2017 Feb 15;173:994-1000. doi: 
      10.1016/j.saa.2016.11.002. Epub 2016 Nov 3.