PMID- 27877778
OWN - NLM
STAT- PubMed-not-MEDLINE
LR  - 20240326
IS  - 1468-6996 (Print)
IS  - 1878-5514 (Electronic)
IS  - 1468-6996 (Linking)
VI  - 16
IP  - 2
DP  - 2015 Apr
TI  - Electronic conduction in La-based perovskite-type oxides.
PG  - 026001
LID - 026001
AB  - A systematic study of La-based perovskite-type oxides from the viewpoint of their 
      electronic conduction properties was performed. LaCo(0.5)Ni(0.5)O(3+/-delta) was found 
      to be a promising candidate as a replacement for standard metals used in oxide 
      electrodes and wiring that are operated at temperatures up to 1173 K in air 
      because of its high electrical conductivity and stability at high temperatures. 
      LaCo(0.5)Ni(0.5)O(3+/-delta) exhibits a high conductivity of 1.9 x 10(3) S cm(-1) at 
      room temperature (R.T.) because of a high carrier concentration n of 2.2 x 10(22) 
      cm(-3) and a small effective mass m * of 0.10 m(e). Notably, 
      LaCo(0.5)Ni(0.5)O(3+/-delta) exhibits this high electrical conductivity from R.T. to 
      1173 K, and little change in the oxygen content occurs under these conditions. 
      LaCo(0.5)Ni(0.5)O(3+/-delta) is the most suitable for the fabrication of oxide 
      electrodes and wiring, though La(1-x) Sr (x) CoO(3+/-delta) and La(1-x) Sr (x) MnO(3+/-delta) 
      also exhibit high electronic conductivity at R.T., with maximum electrical 
      conductivities of 4.4 x 10(3) S cm(-1) for La(0.5)Sr(0.5)CoO(3+/-delta) and 1.5 x 10(3) 
      S cm(-1) for La(0.6)Sr(0.4)MnO(3+/-delta) because oxygen release occurs in La(1-x) Sr 
      (x) CoO(3+/-delta) as elevating temperature and the electrical conductivity of 
      La(0.6)Sr(0.4)MnO(3+/-delta) slightly decreases at temperatures above 400 K.
FAU - Kozuka, Hisashi
AU  - Kozuka H
AD  - NGK Spark Plug Co., Ltd, 2808, Iwasaki, Komaki-shi, Aichi 485-8510, Japan.
FAU - Ohbayashi, Kazushige
AU  - Ohbayashi K
AD  - NGK Spark Plug Co., Ltd, 2808, Iwasaki, Komaki-shi, Aichi 485-8510, Japan.
FAU - Koumoto, Kunihito
AU  - Koumoto K
AD  - Department of Applied Chemistry, Graduate School of Engineering, Nagoya 
      University, Furo-cho Chikusa-ku, Nagoya 464-8603, Japan.
LA  - eng
PT  - Journal Article
PT  - Review
DEP - 20150310
PL  - United States
TA  - Sci Technol Adv Mater
JT  - Science and technology of advanced materials
JID - 101614420
PMC - PMC5036473
OTO - NOTNLM
OT  - carrier concentration
OT  - carrier mobility
OT  - effective mass
OT  - electrical conductivity
OT  - electronic conduction
OT  - relaxation time
EDAT- 2015/03/10 00:00
MHDA- 2015/03/10 00:01
PMCR- 2015/03/10
CRDT- 2016/11/24 06:00
PHST- 2014/10/15 00:00 [received]
PHST- 2015/01/28 00:00 [revised]
PHST- 2015/01/28 00:00 [accepted]
PHST- 2016/11/24 06:00 [entrez]
PHST- 2015/03/10 00:00 [pubmed]
PHST- 2015/03/10 00:01 [medline]
PHST- 2015/03/10 00:00 [pmc-release]
AID - TSTA11661273 [pii]
AID - 10.1088/1468-6996/16/2/026001 [doi]
PST - epublish
SO  - Sci Technol Adv Mater. 2015 Mar 10;16(2):026001. doi: 
      10.1088/1468-6996/16/2/026001. eCollection 2015 Apr.