PMID- 27915157
OWN - NLM
STAT- MEDLINE
DCOM- 20180807
LR  - 20180807
IS  - 1873-3557 (Electronic)
IS  - 1386-1425 (Linking)
VI  - 174
DP  - 2017 Mar 5
TI  - Double injection/single detection asymmetric flow injection manifold for 
      spectrophotometric determination of ascorbic acid and uric acid: Selection the 
      optimal conditions by MCDM approach based on different criteria weighting 
      methods.
PG  - 203-213
LID - S1386-1425(16)30685-0 [pii]
LID - 10.1016/j.saa.2016.11.031 [doi]
AB  - A simple and sensitive double injection/single detector flow injection analysis 
      (FIA) method is proposed for the simultaneous kinetic determination of ascorbic 
      acid (AA) and uric acid (UA). This method is based upon the difference between 
      the rates of the AA and UA reactions with Fe(3+) in the presence of 1, 
      10-phenanthroline (phen). The absorbance of Fe(2+)/1, 10-phenanthroline (Fe-phen) 
      complex obtained as the product was measured spectrophotometrically at 510nm. To 
      reach a good accuracy in the differential kinetic determination via the 
      mathematical manipulations of the transient signals, different criteria were 
      considered in the selection of the optimum conditions. The multi criteria 
      decision making (MCDM) approach was applied for the selection of the optimum 
      conditions. The importance weights of the evaluation criteria were determined 
      using the analytic hierarchy process, entropy method, and compromised weighting 
      (CW). The experimental conditions (alternatives) were ranked by the technique for 
      order preference by similarity to an ideal solution. Under the selected optimum 
      conditions, the obtained analytical signals were linear in the ranges of 
      0.50-5.00 and 0.50-4.00mgL(-1) for AA and UA, respectively. The 3sigma detection 
      limits were 0.07mgL(-1) for AA and 0.12mgL(-1) for UA. The relative standard 
      deviations for four replicate determinations of AA and UA were 2.03% and 3.30% 
      respectively. The method was also applied for the analysis of analytes in the 
      blood serum, Vitamine C tablets, and tap water with satisfactory results.
CI  - Copyright (c) 2016. Published by Elsevier B.V.
FAU - Boroumand, Samira
AU  - Boroumand S
AD  - College of Chemistry, Shahrood University of Technology, Shahrood, P.O. Box 
      36155-316, Iran.
FAU - Chamjangali, Mansour Arab
AU  - Chamjangali MA
AD  - College of Chemistry, Shahrood University of Technology, Shahrood, P.O. Box 
      36155-316, Iran. Electronic address: marab@shahroodut.ac.ir.
FAU - Bagherian, Ghadamali
AU  - Bagherian G
AD  - College of Chemistry, Shahrood University of Technology, Shahrood, P.O. Box 
      36155-316, Iran.
LA  - eng
PT  - Journal Article
DEP - 20161120
PL  - England
TA  - Spectrochim Acta A Mol Biomol Spectrosc
JT  - Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy
JID - 9602533
RN  - 0 (Indicators and Reagents)
RN  - 0 (Phenanthrolines)
RN  - 268B43MJ25 (Uric Acid)
RN  - E1UOL152H7 (Iron)
RN  - PQ6CK8PD0R (Ascorbic Acid)
SB  - IM
MH  - Ascorbic Acid/*analysis
MH  - *Decision Making
MH  - Flow Injection Analysis/*methods
MH  - Hydrogen-Ion Concentration
MH  - Indicators and Reagents
MH  - Iron/chemistry
MH  - Osmolar Concentration
MH  - Phenanthrolines/chemistry
MH  - Spectrophotometry/*methods
MH  - Uric Acid/*analysis
OTO - NOTNLM
OT  - Ascorbic acid and uric acid
OT  - Flow injection analysis
OT  - Multi criteria decision making (MCDM)
OT  - Simultaneous determination
OT  - TOPSIS
EDAT- 2016/12/05 06:00
MHDA- 2018/08/08 06:00
CRDT- 2016/12/05 06:00
PHST- 2016/05/18 00:00 [received]
PHST- 2016/11/07 00:00 [revised]
PHST- 2016/11/16 00:00 [accepted]
PHST- 2016/12/05 06:00 [pubmed]
PHST- 2018/08/08 06:00 [medline]
PHST- 2016/12/05 06:00 [entrez]
AID - S1386-1425(16)30685-0 [pii]
AID - 10.1016/j.saa.2016.11.031 [doi]
PST - ppublish
SO  - Spectrochim Acta A Mol Biomol Spectrosc. 2017 Mar 5;174:203-213. doi: 
      10.1016/j.saa.2016.11.031. Epub 2016 Nov 20.