PMID- 27974151 OWN - NLM STAT- PubMed-not-MEDLINE DCOM- 20180314 LR - 20180314 IS - 1879-1026 (Electronic) IS - 0048-9697 (Linking) VI - 580 DP - 2017 Feb 15 TI - Using a passive air sampler to monitor air-soil exchange of organochlorine pesticides in the pasture of the central Tibetan Plateau. PG - 958-965 LID - S0048-9697(16)32733-4 [pii] LID - 10.1016/j.scitotenv.2016.12.046 [doi] AB - Air-soil exchange is a key process controlling the fate of persistent organic pollutants (POPs). However, the "sink effect" of soil for POPs in Tibetan pasture has not been clear. In NamCo, in the central Tibetan Plateau (TP) where the land is covered by grass, a modified passive air sampler (PAS) (thickness: 2cm) was tested. Using the PAS, the atmospheric gaseous phase organochlorine pesticides (OCPs) at 11 heights from close-to-surface (2cm) to 200cm above ground, in summer and in winter, were measured. Concentrations of OCPs in summer were higher than those in winter. Both in summer and winter, atmospheric concentrations of OCPs decreased with decreasing height from 200 to 2cm, indicating that OCPs were being deposited from air to soil. Air deposition of OCPs was possibly driven by wind speed. Furthermore, based on air OCPs at 0-3cm near the surface, the interface exchange of OCPs between air and soil was studied by the fugacity method. The results showed that pastural soil in the TP was a "sink" of OCPs even in summer. The mean deposition fluxes of alpha-HCH, gamma-HCH and o,p'-DDT were 0.72, 0.24 and 0.54pg/h/m(2), respectively, and it was estimated that the level of these pollutants in the soil will double every 24, 66 and 206years, respectively. This study will contribute to the further understanding of global cycling of POPs in different land covers. CI - Copyright (c) 2016 Elsevier B.V. All rights reserved. FAU - Wang, Chuanfei AU - Wang C AD - Key Laboratory of Tibetan Environment Changes and Land Surface Processes, Institute of Tibetan Plateau Research, Chinese Academy of Sciences, Beijing 100101, China; CAS Center for Excellence in Tibetan Plateau Earth Sciences, Beijing, 100101, China. FAU - Wang, Xiaoping AU - Wang X AD - Key Laboratory of Tibetan Environment Changes and Land Surface Processes, Institute of Tibetan Plateau Research, Chinese Academy of Sciences, Beijing 100101, China; CAS Center for Excellence in Tibetan Plateau Earth Sciences, Beijing, 100101, China. Electronic address: wangxp@itpcas.ac.cn. FAU - Ren, Jiao AU - Ren J AD - Key Laboratory of Tibetan Environment Changes and Land Surface Processes, Institute of Tibetan Plateau Research, Chinese Academy of Sciences, Beijing 100101, China; University of Chinese Academy of Sciences, Beijing 100049, China. FAU - Gong, Ping AU - Gong P AD - Key Laboratory of Tibetan Environment Changes and Land Surface Processes, Institute of Tibetan Plateau Research, Chinese Academy of Sciences, Beijing 100101, China; CAS Center for Excellence in Tibetan Plateau Earth Sciences, Beijing, 100101, China. FAU - Yao, Tandong AU - Yao T AD - Key Laboratory of Tibetan Environment Changes and Land Surface Processes, Institute of Tibetan Plateau Research, Chinese Academy of Sciences, Beijing 100101, China; CAS Center for Excellence in Tibetan Plateau Earth Sciences, Beijing, 100101, China. LA - eng PT - Journal Article DEP - 20161211 PL - Netherlands TA - Sci Total Environ JT - The Science of the total environment JID - 0330500 OTO - NOTNLM OT - Air-soil exchange OT - OCPs OT - Passive air sampler OT - Pasture OT - Tibetan Plateau EDAT- 2016/12/16 06:00 MHDA- 2016/12/16 06:01 CRDT- 2016/12/16 06:00 PHST- 2016/10/26 00:00 [received] PHST- 2016/12/06 00:00 [revised] PHST- 2016/12/07 00:00 [accepted] PHST- 2016/12/16 06:00 [pubmed] PHST- 2016/12/16 06:01 [medline] PHST- 2016/12/16 06:00 [entrez] AID - S0048-9697(16)32733-4 [pii] AID - 10.1016/j.scitotenv.2016.12.046 [doi] PST - ppublish SO - Sci Total Environ. 2017 Feb 15;580:958-965. doi: 10.1016/j.scitotenv.2016.12.046. Epub 2016 Dec 11.