PMID- 27993053
OWN - NLM
STAT- MEDLINE
DCOM- 20170608
LR  - 20180724
IS  - 1520-5851 (Electronic)
IS  - 0013-936X (Linking)
VI  - 50
IP  - 24
DP  - 2016 Dec 20
TI  - Exceptional Visible-Light Activities of TiO(2)-Coupled N-Doped Porous Perovskite 
      LaFeO(3) for 2,4-Dichlorophenol Decomposition and CO(2) Conversion.
PG  - 13600-13610
AB  - In this work, TiO(2)-coupled N-doped porous perovskite-type LaFeO(3) 
      nanocomposites as highly efficient, cheap, stable, and visible-light 
      photocatalysts have successfully been prepared via wet chemical processes. It is 
      shown that the amount-optimized nanocomposite exhibits exceptional visible-light 
      photocatalytic activities for 2,4-dichlorophenol (2,4-DCP) degradation by  approximately 3-time 
      enhancement and for CO(2) conversion to fuels by  approximately 4-time enhancement, compared to 
      the resulting porous LaFeO(3) with rather high photoactivity due to its large 
      surface area. It is clearly demonstrated, by means of various experimental data, 
      especially for the .OH amount evaluation, that the obviously enhanced 
      photoactivities are attributed to the increased specific surface area by 
      introducing pores, to the extended visible-light absorption by doping N to create 
      surface states, and to the promoted charge transfer and separation by coupling 
      TiO(2). Moreover, it is confirmed from radical trapping experiments that the 
      photogenerated holes are the predominant oxidants in the photocatalytic 
      degradation of 2,4-DCP. Furthermore, a possible photocatalytic degradation 
      mechanism for 2,4-DCP is proposed mainly based on the resultant crucial 
      intermediate, 2-chlorosuccinic acid with m/z = 153, that readily transform into 
      CO(2) and H(2)O. This work opens up a new feasible route to synthesize 
      visible-light-responsive high-activity perovskite-type nanophotocatalysts for 
      efficient environmental remediation and energy production.
FAU - Humayun, Muhammad
AU  - Humayun M
AD  - Key Laboratory of Functional Inorganic Materials Chemistry, Heilongjiang 
      University , Ministry of Education, School of Chemistry and Materials Science, 
      International Joint Research Center for Catalytic Technology, Harbin 150080, P. 
      R. China.
FAU - Qu, Yang
AU  - Qu Y
AD  - Key Laboratory of Functional Inorganic Materials Chemistry, Heilongjiang 
      University , Ministry of Education, School of Chemistry and Materials Science, 
      International Joint Research Center for Catalytic Technology, Harbin 150080, P. 
      R. China.
FAU - Raziq, Fazal
AU  - Raziq F
AD  - Key Laboratory of Functional Inorganic Materials Chemistry, Heilongjiang 
      University , Ministry of Education, School of Chemistry and Materials Science, 
      International Joint Research Center for Catalytic Technology, Harbin 150080, P. 
      R. China.
FAU - Yan, Rui
AU  - Yan R
AD  - Key Laboratory of Functional Inorganic Materials Chemistry, Heilongjiang 
      University , Ministry of Education, School of Chemistry and Materials Science, 
      International Joint Research Center for Catalytic Technology, Harbin 150080, P. 
      R. China.
FAU - Li, Zhijun
AU  - Li Z
AD  - Key Laboratory of Functional Inorganic Materials Chemistry, Heilongjiang 
      University , Ministry of Education, School of Chemistry and Materials Science, 
      International Joint Research Center for Catalytic Technology, Harbin 150080, P. 
      R. China.
FAU - Zhang, Xuliang
AU  - Zhang X
AD  - Key Laboratory of Functional Inorganic Materials Chemistry, Heilongjiang 
      University , Ministry of Education, School of Chemistry and Materials Science, 
      International Joint Research Center for Catalytic Technology, Harbin 150080, P. 
      R. China.
FAU - Jing, Liqiang
AU  - Jing L
AUID- ORCID: 0000-0002-3189-492X
AD  - Key Laboratory of Functional Inorganic Materials Chemistry, Heilongjiang 
      University , Ministry of Education, School of Chemistry and Materials Science, 
      International Joint Research Center for Catalytic Technology, Harbin 150080, P. 
      R. China.
LA  - eng
PT  - Journal Article
PT  - Research Support, Non-U.S. Gov't
DEP - 20161207
PL  - United States
TA  - Environ Sci Technol
JT  - Environmental science & technology
JID - 0213155
SB  - IM
MH  - Catalysis
MH  - *Light
MH  - Nanocomposites/*chemistry
MH  - Porosity
EDAT- 2016/12/21 06:00
MHDA- 2017/06/09 06:00
CRDT- 2016/12/21 06:00
PHST- 2016/12/21 06:00 [entrez]
PHST- 2016/12/21 06:00 [pubmed]
PHST- 2017/06/09 06:00 [medline]
AID - 10.1021/acs.est.6b04958 [doi]
PST - ppublish
SO  - Environ Sci Technol. 2016 Dec 20;50(24):13600-13610. doi: 
      10.1021/acs.est.6b04958. Epub 2016 Dec 7.