PMID- 28063203
OWN - NLM
STAT- MEDLINE
DCOM- 20170606
LR  - 20180117
IS  - 1864-564X (Electronic)
IS  - 1864-5631 (Linking)
VI  - 10
IP  - 7
DP  - 2017 Apr 10
TI  - Simultaneous Au(III) Extraction and In Situ Formation of Polymeric 
      Membrane-Supported Au Nanoparticles: A Sustainable Process with Application in 
      Catalysis.
PG  - 1482-1493
LID - 10.1002/cssc.201601883 [doi]
AB  - A polymeric membrane-supported catalyst with immobilized gold nanoparticles 
      (AuNPs) was prepared through the extraction and in situ reduction of Au(III) 
      salts in a one-step strategy. Polymeric inclusion membranes (PIMs) and polymeric 
      nanoporous membranes (PNMs) were tested as different membrane-support systems. 
      Transport experiments indicated that PIMs composed of cellulose triacetate, 
      2-nitrophenyloctyl ether, and an aliphatic tertiary amine (Adogen 364 or 
      Alamine 336) were the most efficient supports for Au(III) extraction. The 
      simultaneous extraction and reduction processes were proven to be the result of a 
      synergic phenomenon in which all the membrane components were involved. Scanning 
      electron microscopy characterization of cross-sectional samples suggested a 
      distribution of AuNPs throughout the membrane. Transmission electron microscopy 
      characterization of the AuNPs indicated average particle sizes of 36.7 and 2.9 nm 
      for the PIMs and PNMs, respectively. AuNPs supported on PIMs allowed for >95.4 % 
      reduction of a 0.05 mmol L(-1) 4-nitrophenol aqueous solution with 10 mmol L(-1) 
      NaBH(4) solution within 25 min.
CI  - (c) 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
FAU - Mora-Tamez, Lucia
AU  - Mora-Tamez L
AUID- ORCID: 0000-0001-5532-6866
AD  - Departamento de Quimica Analitica, Facultad de Quimica, UNAM, Ciudad 
      Universitaria, 04510, D.F., Mexico.
FAU - Esquivel-Pena, Vicente
AU  - Esquivel-Pena V
AUID- ORCID: 0000-0003-4876-7318
AD  - Departamento de Quimica Analitica, Facultad de Quimica, UNAM, Ciudad 
      Universitaria, 04510, D.F., Mexico.
FAU - Ocampo, Ana L
AU  - Ocampo AL
AUID- ORCID: 0000-0001-9595-3901
AD  - Departamento de Quimica Analitica, Facultad de Quimica, UNAM, Ciudad 
      Universitaria, 04510, D.F., Mexico.
FAU - Rodriguez de San Miguel, Eduardo
AU  - Rodriguez de San Miguel E
AUID- ORCID: 0000-0001-6465-9363
AD  - Departamento de Quimica Analitica, Facultad de Quimica, UNAM, Ciudad 
      Universitaria, 04510, D.F., Mexico.
FAU - Grande, Daniel
AU  - Grande D
AD  - Equipe "Systemes Polymeres Complexes", Institut de Chimie et des Materiaux 
      Paris-Est, UMR 7182 CNRS Universite Paris-Est Creteil, 2 rue Henri Dunant, 94320, 
      Thiais, France.
FAU - de Gyves, Josefina
AU  - de Gyves J
AUID- ORCID: 0000-0002-7756-0415
AD  - Departamento de Quimica Analitica, Facultad de Quimica, UNAM, Ciudad 
      Universitaria, 04510, D.F., Mexico.
LA  - eng
PT  - Journal Article
PT  - Research Support, Non-U.S. Gov't
DEP - 20170215
PL  - Germany
TA  - ChemSusChem
JT  - ChemSusChem
JID - 101319536
RN  - 0 (Aminophenols)
RN  - 0 (Membranes, Artificial)
RN  - 0 (Nitrophenols)
RN  - 0 (Polymers)
RN  - 059QF0KO0R (Water)
RN  - 7440-57-5 (Gold)
RN  - R7P8FRP05V (4-aminophenol)
RN  - Y92ZL45L4R (4-nitrophenol)
SB  - IM
MH  - Aminophenols/chemistry
MH  - Catalysis
MH  - Gold/*chemistry/*isolation & purification
MH  - Green Chemistry Technology
MH  - *Membranes, Artificial
MH  - Metal Nanoparticles/*chemistry
MH  - Nitrophenols/chemistry
MH  - Oxidation-Reduction
MH  - Polymers/*chemistry
MH  - Water/chemistry
OTO - NOTNLM
OT  - catalytic membranes
OT  - gold
OT  - in situ reduction
OT  - nanoparticles
OT  - supported catalysts
EDAT- 2017/01/08 06:00
MHDA- 2017/06/07 06:00
CRDT- 2017/01/08 06:00
PHST- 2016/12/22 00:00 [received]
PHST- 2017/01/03 00:00 [revised]
PHST- 2017/01/08 06:00 [pubmed]
PHST- 2017/06/07 06:00 [medline]
PHST- 2017/01/08 06:00 [entrez]
AID - 10.1002/cssc.201601883 [doi]
PST - ppublish
SO  - ChemSusChem. 2017 Apr 10;10(7):1482-1493. doi: 10.1002/cssc.201601883. Epub 2017 
      Feb 15.