PMID- 28063642
OWN - NLM
STAT- MEDLINE
DCOM- 20170320
LR  - 20181202
IS  - 1873-3778 (Electronic)
IS  - 0021-9673 (Linking)
VI  - 1483
DP  - 2017 Feb 3
TI  - Preparation and characterization of magnetic Wells-Dawson heteropoly acid 
      nanoparticles for magnetic solid-phase extraction of aromatic amines in water 
      samples.
PG  - 64-70
LID - S0021-9673(16)31749-6 [pii]
LID - 10.1016/j.chroma.2016.12.083 [doi]
AB  - In this work, aminopropyl modified silica-coated magnetite nanoparticles with 
      Wells-Dawson heteropoly acid (P(2)W(17)Fe@APSCMNPs) was first synthesized and 
      underwent highly efficient magnetic solid-phase extraction (MSPE) of aromatic 
      amines from aqueous samples. The resulted nanomaterials were characterized with 
      different physicochemical techniques such as Fourier transform infrared (FT-IR), 
      scanning electron microscopy (SEM), transmission electron microscopy (TEM) and 
      vibrating sample magnetometry (VSM). Aniline, N,N-dimethylaniline, o-toluidine 
      and 3-chloroaniline were selected as target compounds. The sample quantification 
      was carried out using gas chromatography-flame ionization detector (GC-FID). 
      Under optimal working conditions, the developed method showed good linearity 
      (R>0.9912) in the range of 0.01-100ngmL(-1). The method displays detection limits 
      (at an S/N ration of 3) in the range from 0.003 to 0.01ngmL(-1), and the limits 
      of quantification (at an S/N ratio of 10) are between 0.01 and 0.04ngmL(-1). The 
      enrichment factors (EFs) were in the range of 75-113. Relative standard 
      deviations (RSDs) are 4.8-8.3%. The applicability of the developed method was 
      examined by analyzing different water samples (river water, tap water, well water 
      and wastewater) and the relative recovery values for the spiked water samples 
      were found to be in the range of 90.7-99.8%.
CI  - Copyright (c) 2016 Elsevier B.V. All rights reserved.
FAU - Amiri, Amirhassan
AU  - Amiri A
AD  - Department of Chemistry, Faculty of Sciences, Hakim Sabzevari University, 
      9617976487 Sabzevar, Iran. Electronic address: Amiri_amirhassan@yahoo.com.
FAU - Saadati-Moshtaghin, Hamid Reza
AU  - Saadati-Moshtaghin HR
AD  - Department of Chemistry, Faculty of Sciences, Hakim Sabzevari University, 
      9617976487 Sabzevar, Iran.
FAU - Zonoz, Farokhzad Mohammadi
AU  - Zonoz FM
AD  - Department of Chemistry, Faculty of Sciences, Hakim Sabzevari University, 
      9617976487 Sabzevar, Iran.
FAU - Targhoo, Azadeh
AU  - Targhoo A
AD  - Department of Chemistry, Faculty of Sciences, Hakim Sabzevari University, 
      9617976487 Sabzevar, Iran.
LA  - eng
PT  - Journal Article
DEP - 20161231
PL  - Netherlands
TA  - J Chromatogr A
JT  - Journal of chromatography. A
JID - 9318488
RN  - 0 (Acids)
RN  - 0 (Amines)
RN  - 0 (Magnetite Nanoparticles)
RN  - 0 (Solvents)
RN  - 0 (Water Pollutants, Chemical)
RN  - 059QF0KO0R (Water)
SB  - IM
MH  - Acids/*chemistry
MH  - Adsorption
MH  - Amines/*analysis
MH  - Hydrogen-Ion Concentration
MH  - Limit of Detection
MH  - Magnetics/*methods
MH  - Magnetite Nanoparticles/*chemistry
MH  - Solid Phase Extraction/*methods
MH  - Solvents
MH  - Spectroscopy, Fourier Transform Infrared
MH  - Water/*chemistry
MH  - Water Pollutants, Chemical/*analysis
OTO - NOTNLM
OT  - Aromatic amines
OT  - Magnetic nanoparticles
OT  - Magnetic solid-phase extraction
OT  - Water samples
OT  - Wells-Dawson heteropoly acid
EDAT- 2017/01/09 06:00
MHDA- 2017/03/21 06:00
CRDT- 2017/01/09 06:00
PHST- 2016/10/14 00:00 [received]
PHST- 2016/12/09 00:00 [revised]
PHST- 2016/12/30 00:00 [accepted]
PHST- 2017/01/09 06:00 [pubmed]
PHST- 2017/03/21 06:00 [medline]
PHST- 2017/01/09 06:00 [entrez]
AID - S0021-9673(16)31749-6 [pii]
AID - 10.1016/j.chroma.2016.12.083 [doi]
PST - ppublish
SO  - J Chromatogr A. 2017 Feb 3;1483:64-70. doi: 10.1016/j.chroma.2016.12.083. Epub 
      2016 Dec 31.