PMID- 28160707
OWN - NLM
STAT- MEDLINE
DCOM- 20180309
LR  - 20181202
IS  - 1095-7103 (Electronic)
IS  - 0021-9797 (Linking)
VI  - 494
DP  - 2017 May 15
TI  - Optimization of cellulose and sugarcane bagasse oxidation: Application for 
      adsorptive removal of crystal violet and auramine-O from aqueous solution.
PG  - 223-241
LID - S0021-9797(17)30107-8 [pii]
LID - 10.1016/j.jcis.2017.01.085 [doi]
AB  - Cellulose (Cel) and sugarcane bagasse (SB) were oxidized with an 
      H(3)PO(4)-NaNO(2) mixture to obtain adsorbent materials with high contents of 
      carboxylic groups. The oxidation reactions of Cel and SB were optimized using 
      design of experiments (DOE) and response surface methodology (RSM). The optimized 
      synthesis conditions yielded Cox and SBox with 4.8mmol/g and 4.5mmol/g of 
      carboxylic acid groups, respectively. Cox and SBox were characterized by FTIR, 
      TGA, PZC and solid-state (13)C NMR. The adsorption of the model cationic dyes 
      crystal violet (CV) and auramine-O (AO) on Cox and SBox in aqueous solution was 
      investigated as a function of the solution pH, the contact time and the initial 
      dye concentration. The adsorption of CV and AO on Cox was described by the 
      Elovich equation and the pseudo-first-order kinetic model respectively, while the 
      adsorption of CV and AO on SBox was described by the pseudo-second-order kinetic 
      model. Adsorption isotherms were well fitted by the Langmuir and Konda models, 
      with maximum adsorption capacities (Q(max)) of 1117.8mg/g of CV and 1223.3mg/g of 
      AO on Cox and 1018.2mg/g of CV and 682.8mg/g of AO on SBox. Desorption 
      efficiencies were in the range of 50-52% and re-adsorption capacities varied from 
      65 to 81%, showing the possibility of reuse of both adsorbent materials.
CI  - Copyright (c) 2017 Elsevier Inc. All rights reserved.
FAU - Martins, Luide Rodrigo
AU  - Martins LR
AD  - Departamento de Quimica, Instituto de Ciencias Exatas e Biologicas, Universidade 
      Federal de Ouro Preto, Campus Universitario Morro do Cruzeiro, s/n degrees , Bauxita, 
      35400-000 Ouro Preto, Minas Gerais, Brazil.
FAU - Rodrigues, Josilene Aparecida Vieira
AU  - Rodrigues JAV
AD  - Departamento de Quimica, Instituto de Ciencias Exatas e Biologicas, Universidade 
      Federal de Ouro Preto, Campus Universitario Morro do Cruzeiro, s/n degrees , Bauxita, 
      35400-000 Ouro Preto, Minas Gerais, Brazil.
FAU - Adarme, Oscar Fernando Herrera
AU  - Adarme OFH
AD  - Departamento de Quimica, Instituto de Ciencias Exatas e Biologicas, Universidade 
      Federal de Ouro Preto, Campus Universitario Morro do Cruzeiro, s/n degrees , Bauxita, 
      35400-000 Ouro Preto, Minas Gerais, Brazil.
FAU - Melo, Tania Marcia Sacramento
AU  - Melo TMS
AD  - Departamento de Quimica, Instituto de Ciencias Exatas e Biologicas, Universidade 
      Federal de Ouro Preto, Campus Universitario Morro do Cruzeiro, s/n degrees , Bauxita, 
      35400-000 Ouro Preto, Minas Gerais, Brazil.
FAU - Gurgel, Leandro Vinicius Alves
AU  - Gurgel LVA
AD  - Departamento de Quimica, Instituto de Ciencias Exatas e Biologicas, Universidade 
      Federal de Ouro Preto, Campus Universitario Morro do Cruzeiro, s/n degrees , Bauxita, 
      35400-000 Ouro Preto, Minas Gerais, Brazil.
FAU - Gil, Laurent Frederic
AU  - Gil LF
AD  - Departamento de Quimica, Instituto de Ciencias Exatas e Biologicas, Universidade 
      Federal de Ouro Preto, Campus Universitario Morro do Cruzeiro, s/n degrees , Bauxita, 
      35400-000 Ouro Preto, Minas Gerais, Brazil. Electronic address: 
      laurent@iceb.ufop.br.
LA  - eng
PT  - Journal Article
PT  - Research Support, Non-U.S. Gov't
DEP - 20170125
PL  - United States
TA  - J Colloid Interface Sci
JT  - Journal of colloid and interface science
JID - 0043125
RN  - 0 (Anti-Infective Agents)
RN  - 0 (Coloring Agents)
RN  - 0 (Water Pollutants, Chemical)
RN  - 2465-27-2 (Benzophenoneidum)
RN  - 9004-34-6 (Cellulose)
RN  - 9006-97-7 (bagasse)
RN  - J4Z741D6O5 (Gentian Violet)
SB  - IM
MH  - Adsorption
MH  - Anti-Infective Agents/chemistry/isolation & purification
MH  - Benzophenoneidum/*chemistry/*isolation & purification
MH  - Cellulose/*chemistry
MH  - Coloring Agents/chemistry/isolation & purification
MH  - Gentian Violet/*chemistry/*isolation & purification
MH  - Hydrogen-Ion Concentration
MH  - Kinetics
MH  - Saccharum/*chemistry
MH  - Water Pollutants, Chemical/chemistry/isolation & purification
OTO - NOTNLM
OT  - Adsorption
OT  - Auramine-O
OT  - Crystal violet
OT  - Desorption
OT  - Oxidized cellulose
OT  - Oxidized sugarcane bagasse
EDAT- 2017/02/06 06:00
MHDA- 2018/03/10 06:00
CRDT- 2017/02/05 06:00
PHST- 2016/10/26 00:00 [received]
PHST- 2017/01/19 00:00 [revised]
PHST- 2017/01/22 00:00 [accepted]
PHST- 2017/02/06 06:00 [pubmed]
PHST- 2018/03/10 06:00 [medline]
PHST- 2017/02/05 06:00 [entrez]
AID - S0021-9797(17)30107-8 [pii]
AID - 10.1016/j.jcis.2017.01.085 [doi]
PST - ppublish
SO  - J Colloid Interface Sci. 2017 May 15;494:223-241. doi: 
      10.1016/j.jcis.2017.01.085. Epub 2017 Jan 25.