PMID- 28167765 OWN - NLM STAT- PubMed-not-MEDLINE DCOM- 20180404 LR - 20190111 IS - 1091-6490 (Electronic) IS - 0027-8424 (Print) IS - 0027-8424 (Linking) VI - 114 IP - 9 DP - 2017 Feb 28 TI - Low Hesperian P(CO2) constrained from in situ mineralogical analysis at Gale Crater, Mars. PG - 2166-2170 LID - 10.1073/pnas.1616649114 [doi] AB - Carbon dioxide is an essential atmospheric component in martian climate models that attempt to reconcile a faint young sun with planetwide evidence of liquid water in the Noachian and Early Hesperian. In this study, we use mineral and contextual sedimentary environmental data measured by the Mars Science Laboratory (MSL) Rover Curiosity to estimate the atmospheric partial pressure of CO(2) (P(CO2)) coinciding with a long-lived lake system in Gale Crater at approximately 3.5 Ga. A reaction-transport model that simulates mineralogy observed within the Sheepbed member at Yellowknife Bay (YKB), by coupling mineral equilibria with carbonate precipitation kinetics and rates of sedimentation, indicates atmospheric P(CO2) levels in the 10s mbar range. At such low P(CO2) levels, existing climate models are unable to warm Hesperian Mars anywhere near the freezing point of water, and other gases are required to raise atmospheric pressure to prevent lake waters from being lost to the atmosphere. Thus, either lacustrine features of Gale formed in a cold environment by a mechanism yet to be determined, or the climate models still lack an essential component that would serve to elevate surface temperatures, at least locally, on Hesperian Mars. Our results also impose restrictions on the potential role of atmospheric CO(2) in inferred warmer conditions and valley network formation of the late Noachian. FAU - Bristow, Thomas F AU - Bristow TF AD - Exobiology Branch, NASA Ames Research Center, Moffett Field, CA 94035; thomas.f.bristow@nasa.gov. FAU - Haberle, Robert M AU - Haberle RM AD - Planetary Systems Branch, NASA Ames Research Center, Moffett Field, CA 94035. FAU - Blake, David F AU - Blake DF AD - Exobiology Branch, NASA Ames Research Center, Moffett Field, CA 94035. FAU - Des Marais, David J AU - Des Marais DJ AD - Exobiology Branch, NASA Ames Research Center, Moffett Field, CA 94035. FAU - Eigenbrode, Jennifer L AU - Eigenbrode JL AD - Solar System Exploration Division, NASA Goddard Space Flight Center, Greenbelt, MD 20771. FAU - Fairen, Alberto G AU - Fairen AG AD - Department of Planetology and Habitability, Centro de Astrobiologia, Madrid 28850, Spain. FAU - Grotzinger, John P AU - Grotzinger JP AD - Division of Geological and Planetary Sciences, California Institute of Technology, Pasadena, CA 91125. FAU - Stack, Kathryn M AU - Stack KM AD - Jet Propulsion Laboratory, California Institute of Technology, Pasadena, CA 91109. FAU - Mischna, Michael A AU - Mischna MA AD - Jet Propulsion Laboratory, California Institute of Technology, Pasadena, CA 91109. FAU - Rampe, Elizabeth B AU - Rampe EB AD - Astromaterials Research and Exploration Science Division, NASA Johnson Space Center, Houston, TX 77058. FAU - Siebach, Kirsten L AU - Siebach KL AD - Division of Geological and Planetary Sciences, California Institute of Technology, Pasadena, CA 91125. FAU - Sutter, Brad AU - Sutter B AD - Jacobs Technology, Inc., NASA Johnson Space Center, Houston, TX 77058. FAU - Vaniman, David T AU - Vaniman DT AD - Planetary Science Institute, Tucson, AZ 85719. FAU - Vasavada, Ashwin R AU - Vasavada AR AD - Jet Propulsion Laboratory, California Institute of Technology, Pasadena, CA 91109. LA - eng PT - Journal Article PT - Research Support, Non-U.S. Gov't PT - Research Support, U.S. Gov't, Non-P.H.S. DEP - 20170206 PL - United States TA - Proc Natl Acad Sci U S A JT - Proceedings of the National Academy of Sciences of the United States of America JID - 7505876 PMC - PMC5338541 OTO - NOTNLM OT - Gale Crater OT - Hesperian Mars OT - Mars Science Laboratory OT - carbon dioxide OT - martian atmosphere COIS- The authors declare no conflict of interest. EDAT- 2017/02/09 06:00 MHDA- 2017/02/09 06:01 PMCR- 2017/02/06 CRDT- 2017/02/08 06:00 PHST- 2017/02/09 06:00 [pubmed] PHST- 2017/02/09 06:01 [medline] PHST- 2017/02/08 06:00 [entrez] PHST- 2017/02/06 00:00 [pmc-release] AID - 1616649114 [pii] AID - 201616649 [pii] AID - 10.1073/pnas.1616649114 [doi] PST - ppublish SO - Proc Natl Acad Sci U S A. 2017 Feb 28;114(9):2166-2170. doi: 10.1073/pnas.1616649114. Epub 2017 Feb 6.