PMID- 28213257
OWN - NLM
STAT- MEDLINE
DCOM- 20180918
LR  - 20180918
IS  - 1873-3573 (Electronic)
IS  - 0039-9140 (Linking)
VI  - 166
DP  - 2017 May 1
TI  - A zeolitic imidazolate framework based nanoporous carbon as a novel fiber coating 
      for solid-phase microextraction of pyrethroid pesticides.
PG  - 46-53
LID - S0039-9140(17)30142-X [pii]
LID - 10.1016/j.talanta.2017.01.042 [doi]
AB  - A high-surface-area nanoporous carbon (NPC) has been successfully synthesized by 
      using the metal-organic framework ZIF-90 as both the template and precursor 
      together with furfuryl alcohol as a secondary carbon source. The prepared ZIF-90 
      templated NPC (ZIF-90-NPC) was then coated onto a stainless steel wire by a 
      simple physical adhesion approach to prepare solid-phase microextraction (SPME) 
      fiber. By coupling the ZIF-90-NPC coated fiber-based SPME with gas 
      chromatography-microelectron capture detection (GC-muECD), the developed method 
      gave a large enhancement factor (984-2869), low limit of detection 
      (0.1-0.5ngg(-1)) and good linearity (0.3-50ngg(-1)) for the determination of some 
      pyrethroid pesticides (bifenthrin, fenpropathrin, cyhalothrin, permethrin, 
      cyfluthrin, flucythrinate, fenvalerate and deltamethrin) from different fruits 
      and vegetables. The relative standard deviations (RSDs) for six replicate 
      extractions of the pyrethroids by the ZIF-90-NPC coated fiber ranged from 4.3% to 
      8.0%. The recoveries of the spiked pyrethroids (5ngg(-1) and 20ngg(-1)) from 
      fruit and vegetable samples were in the range of 88.0-104.0% and 86.0-103.5% with 
      the RSDs ranging from 4.8% to 12.9% and 5.0-10.8%, respectively. Besides, the 
      ZIF-90-NPC coated fiber was stable enough for 100 extraction cycles without a 
      significant loss of extraction efficiency. The method was successfully applied to 
      the determination of the pyrethroids in fruit and vegetable samples.
CI  - Copyright A(c) 2017 Elsevier B.V. All rights reserved.
FAU - Zhang, Shuaihua
AU  - Zhang S
AD  - Department of Chemistry, College of Science, Hebei Agricultural University, 
      Baoding 071001, China.
FAU - Yang, Qian
AU  - Yang Q
AD  - College of Science and Technology, Hebei Agricultural University, Cangzhou 
      061100, China.
FAU - Yang, Xiumin
AU  - Yang X
AD  - Department of Chemistry, College of Science, Hebei Agricultural University, 
      Baoding 071001, China.
FAU - Wang, Wenchang
AU  - Wang W
AD  - Department of Chemistry, College of Science, Hebei Agricultural University, 
      Baoding 071001, China.
FAU - Li, Zhi
AU  - Li Z
AD  - Department of Chemistry, College of Science, Hebei Agricultural University, 
      Baoding 071001, China.
FAU - Zhang, Lihong
AU  - Zhang L
AD  - Department of Chemistry, College of Science, Hebei Agricultural University, 
      Baoding 071001, China.
FAU - Wang, Chun
AU  - Wang C
AD  - Department of Chemistry, College of Science, Hebei Agricultural University, 
      Baoding 071001, China.
FAU - Wang, Zhi
AU  - Wang Z
AD  - Department of Chemistry, College of Science, Hebei Agricultural University, 
      Baoding 071001, China. Electronic address: zhiwang2013@aliyun.com.
LA  - eng
PT  - Journal Article
DEP - 20170114
PL  - Netherlands
TA  - Talanta
JT  - Talanta
JID - 2984816R
RN  - 0 (Imidazoles)
RN  - 0 (Pesticides)
RN  - 0 (Pyrethrins)
RN  - 0 (Silicones)
RN  - 1318-02-1 (Zeolites)
RN  - 7440-44-0 (Carbon)
SB  - IM
MH  - Carbon/*chemistry
MH  - Food Contamination/analysis
MH  - Imidazoles/*chemistry
MH  - Models, Molecular
MH  - Molecular Conformation
MH  - Nanostructures/*chemistry
MH  - Pesticides/chemistry/*isolation & purification
MH  - Porosity
MH  - Pyrethrins/chemistry/*isolation & purification
MH  - Silicones/chemistry
MH  - Solid Phase Microextraction/*methods
MH  - Vegetables/chemistry
MH  - Zeolites/*chemistry
OTO - NOTNLM
OT  - Fruit and vegetable samples
OT  - Nanoporous carbon
OT  - Pyrethroid pesticides
OT  - Solid-phase microextraction
OT  - Zeolitic imidazolate framework-90
EDAT- 2017/02/19 06:00
MHDA- 2018/09/19 06:00
CRDT- 2017/02/19 06:00
PHST- 2016/09/07 00:00 [received]
PHST- 2017/01/10 00:00 [revised]
PHST- 2017/01/13 00:00 [accepted]
PHST- 2017/02/19 06:00 [entrez]
PHST- 2017/02/19 06:00 [pubmed]
PHST- 2018/09/19 06:00 [medline]
AID - S0039-9140(17)30142-X [pii]
AID - 10.1016/j.talanta.2017.01.042 [doi]
PST - ppublish
SO  - Talanta. 2017 May 1;166:46-53. doi: 10.1016/j.talanta.2017.01.042. Epub 2017 Jan 
      14.