PMID- 28242530 OWN - NLM STAT- PubMed-not-MEDLINE DCOM- 20180118 LR - 20180118 IS - 1873-3336 (Electronic) IS - 0304-3894 (Linking) VI - 331 DP - 2017 Jun 5 TI - Unintentional production of persistent chlorinated and brominated organic pollutants during iron ore sintering processes. PG - 63-70 LID - S0304-3894(17)30115-2 [pii] LID - 10.1016/j.jhazmat.2017.02.027 [doi] AB - Iron ore sintering (SNT) processes are major sources of unintentionally produced chlorinated persistent organic pollutants (POPs), including polychlorinated dibenzo-p-dioxins/dibenzofurans (PCDD/Fs), polychlorinated biphenyls (PCBs), and polychlorinated naphthalenes (PCNs). However, few studies of emissions of brominated POPs, such as polybrominated dibenzo-p-dioxins/dibenzofurans (PBDD/Fs) and polybrominated diphenyl ethers (PBDEs), during SNT have been performed. Stack gas and fly ash samples from six typical SNT plants in China were collected and analyzed to determine the concentrations and profiles of PCDD/Fs, PCBs, PCNs, PBDD/Fs, and PBDEs, as well as any correlations among these compounds. The PCDD/F, PCB, PCN, PBDD/F, and PBDE emission factors were 2.47, 0.61, 552, 0.32, and 107mugt(-1), respectively (109, 4.07, 10.4, 4.41 and 0.02ng toxic equivalents t(-1), respectively). PCBs were the most abundant compounds by mass, while PCNs were the next most abundant, contributing 51% and 42% to the total POP concentration, respectively. However, PCDD/Fs were the dominant contributors to the chlorinated and brominated POP toxic equivalent concentrations, contributing 89% to the total toxic equivalent concentration. The PCDD/F and other chlorinated and brominated POP concentrations were positively correlated, indicating that chlorinated and brominated POP emissions could be synergistically decreased using the best available technologies/best environmental practices already developed for PCDD/Fs. CI - Copyright (c) 2017 Elsevier B.V. All rights reserved. FAU - Li, Sumei AU - Li S AD - State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085, China; School of Environment, Tsinghua University, Beijing 100084, China. FAU - Liu, Guorui AU - Liu G AD - State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085, China. Electronic address: grliu@rcees.ac.cn. FAU - Zheng, Minghui AU - Zheng M AD - State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085, China. FAU - Liu, Wenbin AU - Liu W AD - State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085, China. FAU - Li, Jinhui AU - Li J AD - School of Environment, Tsinghua University, Beijing 100084, China. FAU - Wang, Mei AU - Wang M AD - State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085, China. FAU - Li, Changliang AU - Li C AD - State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085, China. FAU - Chen, Yuan AU - Chen Y AD - School of Environment, Tsinghua University, Beijing 100084, China. LA - eng PT - Journal Article DEP - 20170220 PL - Netherlands TA - J Hazard Mater JT - Journal of hazardous materials JID - 9422688 OTO - NOTNLM OT - Dioxins OT - Iron ore sintering OT - Persistent organic pollutants OT - Polychlorinated naphthalenes OT - Profiles EDAT- 2017/03/01 06:00 MHDA- 2017/03/01 06:01 CRDT- 2017/03/01 06:00 PHST- 2016/10/17 00:00 [received] PHST- 2017/01/23 00:00 [revised] PHST- 2017/02/16 00:00 [accepted] PHST- 2017/03/01 06:00 [pubmed] PHST- 2017/03/01 06:01 [medline] PHST- 2017/03/01 06:00 [entrez] AID - S0304-3894(17)30115-2 [pii] AID - 10.1016/j.jhazmat.2017.02.027 [doi] PST - ppublish SO - J Hazard Mater. 2017 Jun 5;331:63-70. doi: 10.1016/j.jhazmat.2017.02.027. Epub 2017 Feb 20.