PMID- 28274462
OWN - NLM
STAT- MEDLINE
DCOM- 20170424
LR  - 20191210
IS  - 1873-7072 (Electronic)
IS  - 0308-8146 (Linking)
VI  - 227
DP  - 2017 Jul 15
TI  - Extraction of melamine from milk using a magnetic molecularly imprinted polymer.
PG  - 85-92
LID - S0308-8146(16)32111-2 [pii]
LID - 10.1016/j.foodchem.2016.12.090 [doi]
AB  - A novel magnetic molecularly imprinted polymer (MMIP) for the preconcentration of 
      melamine, a non-protein nitrogen food additive from complex matrices was 
      synthesized and characterized using FT-IR, XRD, SEM and VSM techniques. Surface 
      imprinting was done on vinyltrimethoxysilane coated Fe(3)O(4) (Fe(3)O(4)-VTMS) 
      using 2-acrylamido-2-methylpropane sulfonic acid (AMPS), 
      N,N'-methylenebisacrylamide (MBA) and potassium persulfate (KPS) as functional 
      monomer, crosslinker and initiator respectively. Saturation magnetization value 
      obtained for MMIP was 1.72emug(-1). Binding studies showed that MMIP exhibits 
      good recognition to melamine compared to magnetic non imprinted polymer (MNIP). 
      The optimum pH for the binding of melamine was found to be 4.5. Binding process 
      was very fast and pseudo-second-order model fitted well with the kinetic data. 
      Binding isotherm followed Langmuir isotherm model of monolayer adsorption with a 
      maximum melamine binding efficiency of 62.25mgg(-1). The HPLC-UV analysis results 
      revealed the applicability of MMIP in solid phase extraction and determination of 
      melamine from milk samples.
CI  - Copyright (c) 2017 Elsevier Ltd. All rights reserved.
FAU - Anirudhan, T S
AU  - Anirudhan TS
AD  - Department of Chemistry, School of Physical and Mathematical Sciences, University 
      of Kerala, Kariavattom, Trivandrum 695 581, India. Electronic address: 
      tsani@rediffmail.com.
FAU - Christa, J
AU  - Christa J
AD  - Department of Chemistry, School of Physical and Mathematical Sciences, University 
      of Kerala, Kariavattom, Trivandrum 695 581, India.
FAU - Deepa, J R
AU  - Deepa JR
AD  - Department of Chemistry, School of Physical and Mathematical Sciences, University 
      of Kerala, Kariavattom, Trivandrum 695 581, India.
LA  - eng
PT  - Evaluation Study
PT  - Journal Article
DEP - 20161228
PL  - England
TA  - Food Chem
JT  - Food chemistry
JID - 7702639
RN  - 0 (Acrylamides)
RN  - 0 (Polymers)
RN  - 0 (Triazines)
RN  - EDK4RIE19C (N,N'-methylenebisacrylamide)
RN  - N3GP2YSD88 (melamine)
SB  - IM
MH  - Acrylamides/chemistry
MH  - Adsorption
MH  - Animals
MH  - Cattle
MH  - Food Contamination/*analysis
MH  - Magnetics/instrumentation/*methods
MH  - Milk/*chemistry
MH  - Molecular Imprinting
MH  - Polymers/chemical synthesis/*chemistry
MH  - Solid Phase Extraction/instrumentation/*methods
MH  - Spectroscopy, Fourier Transform Infrared
MH  - Triazines/analysis/*isolation & purification
OTO - NOTNLM
OT  - 2-Acrylamido-2-methylpropane sulfonic acid
OT  - Adsorption
OT  - Free radical polymerization
OT  - Magnetic molecularly imprinted polymer
OT  - Melamine
OT  - Vinyltrimethoxysilane
EDAT- 2017/03/10 06:00
MHDA- 2017/04/25 06:00
CRDT- 2017/03/10 06:00
PHST- 2016/01/16 00:00 [received]
PHST- 2016/12/12 00:00 [revised]
PHST- 2016/12/27 00:00 [accepted]
PHST- 2017/03/10 06:00 [entrez]
PHST- 2017/03/10 06:00 [pubmed]
PHST- 2017/04/25 06:00 [medline]
AID - S0308-8146(16)32111-2 [pii]
AID - 10.1016/j.foodchem.2016.12.090 [doi]
PST - ppublish
SO  - Food Chem. 2017 Jul 15;227:85-92. doi: 10.1016/j.foodchem.2016.12.090. Epub 2016 
      Dec 28.