PMID- 28412884 OWN - NLM STAT- MEDLINE DCOM- 20180816 LR - 20181202 IS - 1479-487X (Electronic) IS - 0959-3330 (Linking) VI - 39 IP - 8 DP - 2018 Apr TI - Horizontally rotating disc recirculated photoreactor with TiO(2)-P25 nanoparticles immobilized onto a HDPE plate for photocatalytic removal of p-nitrophenol. PG - 1061-1070 LID - 10.1080/09593330.2017.1320431 [doi] AB - In this study, a horizontally rotating disc recirculated (HRDR) photoreactor equipped with two UV lamps (6 W) was designed and fabricated for photocatalytic removal of p-nitrophenol (PNP). Photocatalyst (TiO(2)) nanoparticles were immobilized onto a high-density polyethylene (HDPE) disc, and PNP containing solution was allowed to flow (flow rate of 310 mL min(-1)) in radial direction along the surface of the rotating disc illuminated with UV light. The efficiency of direct photolysis and photocatalysis and the effect of rotating speed on the removal of PNP were studied in the HRDR photoreactor. It was found that TiO(2)-P25 nanoparticles are needed for the effective removal of PNP and there was an optimum rotating speed (450 rpm) for the efficient performance of the HRDR photoreactor. Then effects of operational variables on the removal efficiency were optimized using response surface methodology. The results showed that the predicted values of removal efficiency are consistent with experimental results with an R(2) of 0.9656. Optimization results showed that maximum removal percent (82.6%) was achieved in the HRDR photoreactor at the optimum operational conditions. Finally, the reusability of the HRDR photoreactor was evaluated and the results showed high reusability and stability without any significant decrease in the photocatalytic removal efficiency. FAU - Behnajady, Mohammad A AU - Behnajady MA AUID- ORCID: 0000-0002-9929-8921 AD - a Department of Chemistry , Tabriz Branch, Islamic Azad University , Tabriz , Iran. FAU - Dadkhah, Hojjat AU - Dadkhah H AUID- ORCID: 0000-0001-5288-5283 AD - a Department of Chemistry , Tabriz Branch, Islamic Azad University , Tabriz , Iran. FAU - Eskandarloo, Hamed AU - Eskandarloo H AUID- ORCID: 0000-0001-7241-119X AD - b School of Chemistry, College of Science , University of Tehran , Tehran , Iran. LA - eng PT - Journal Article DEP - 20170505 PL - England TA - Environ Technol JT - Environmental technology JID - 9884939 RN - 0 (Nitrophenols) RN - 15FIX9V2JP (titanium dioxide) RN - 9002-88-4 (Polyethylene) RN - D1JT611TNE (Titanium) RN - Y92ZL45L4R (4-nitrophenol) SB - IM MH - Catalysis MH - *Nanoparticles MH - Nitrophenols/*chemistry MH - Photolysis MH - Polyethylene MH - Titanium/*chemistry MH - Ultraviolet Rays MH - Water Purification OTO - NOTNLM OT - Rotating disc photoreactor OT - immobilized TiO2-P25 OT - p-nitrophenol OT - photocatalytic removal OT - response surface methodology EDAT- 2017/04/18 06:00 MHDA- 2018/08/17 06:00 CRDT- 2017/04/18 06:00 PHST- 2017/04/18 06:00 [pubmed] PHST- 2018/08/17 06:00 [medline] PHST- 2017/04/18 06:00 [entrez] AID - 10.1080/09593330.2017.1320431 [doi] PST - ppublish SO - Environ Technol. 2018 Apr;39(8):1061-1070. doi: 10.1080/09593330.2017.1320431. Epub 2017 May 5.