PMID- 28440643 OWN - NLM STAT- MEDLINE DCOM- 20171215 LR - 20181202 IS - 1520-5851 (Electronic) IS - 0013-936X (Linking) VI - 51 IP - 10 DP - 2017 May 16 TI - Field Calibration of XAD-Based Passive Air Sampler on the Tibetan Plateau: Wind Influence and Configuration Improvement. PG - 5642-5649 LID - 10.1021/acs.est.7b01029 [doi] AB - The passive air sampler based on XAD-2 resin (XAD-PAS) has proven useful for collecting atmospheric persistent organic pollutants (POPs) in remote regions. Whereas laboratory studies have shown that, due to the open bottom of its housing, the passive sampling rate (PSR) of the XAD-PAS is susceptible to wind and other processes causing air turbulence, the sampler has not been calibrated in the field at sites experiencing high winds. In this study, the PSRs of the XAD-PAS were calibrated at three sites on the Tibetan Plateau, covering a wide range in temperature (T), pressure (P) and wind speed (v). At sites with low wind speeds (i.e., in a forest and an urban site), the PSRs are proportional to the ratio T(1.75)/ P; at windy sites with an average wind speed above 3 m/s, the influence of v on PSRs cannot be ignored. Moreover, the open bottom of the XAD-PAS housing causes the PSRs to be influenced by wind angle and air turbulence caused by sloped terrain. Field calibration, wind speed measurements, and computational fluid dynamics (CFD) simulations indicate that a modified design incorporating an air spoiler consisting of 4 metal sheets dampens the turbulence caused by wind angle and sloped terrain and caps the PSR at approximately 5 m(3)/day, irrespective of ambient wind. Therefore, the original XAD-PAS with an open bottom is suitable for deployment in urban areas and other less windy places, the modified design is preferable in mountain regions and other places where air circulation is complicated and strong. FAU - Gong, Ping AU - Gong P AD - Key Laboratory of Tibetan Environmental Changes and Land Surface Process, Institute of Tibetan Plateau Research, Chinese Academy of Sciences (CAS) , Beijing 100101, China. AD - CAS Center for Excellence in Tibetan Plateau Earth Sciences, Beijing 100101, China. FAU - Wang, Xiaoping AU - Wang X AUID- ORCID: 0000-0001-7524-7540 AD - Key Laboratory of Tibetan Environmental Changes and Land Surface Process, Institute of Tibetan Plateau Research, Chinese Academy of Sciences (CAS) , Beijing 100101, China. AD - CAS Center for Excellence in Tibetan Plateau Earth Sciences, Beijing 100101, China. FAU - Liu, Xiande AU - Liu X AD - Chinese Research Academy of Environmental Sciences, Beijing 100012, China. FAU - Wania, Frank AU - Wania F AUID- ORCID: 0000-0003-3836-0901 AD - University of Toronto Scarborough , Department of Physical and Environmental Sciences, 1265 Military Trail, Toronto, Ontario Canada , M1C 1A4. LA - eng PT - Journal Article DEP - 20170502 PL - United States TA - Environ Sci Technol JT - Environmental science & technology JID - 0213155 RN - 0 (Air Pollutants) SB - IM MH - *Air Pollutants MH - Calibration MH - Environmental Monitoring MH - Tibet MH - *Wind EDAT- 2017/04/26 06:00 MHDA- 2017/12/16 06:00 CRDT- 2017/04/26 06:00 PHST- 2017/04/26 06:00 [pubmed] PHST- 2017/12/16 06:00 [medline] PHST- 2017/04/26 06:00 [entrez] AID - 10.1021/acs.est.7b01029 [doi] PST - ppublish SO - Environ Sci Technol. 2017 May 16;51(10):5642-5649. doi: 10.1021/acs.est.7b01029. Epub 2017 May 2.