PMID- 28490103
OWN - NLM
STAT- MEDLINE
DCOM- 20170901
LR  - 20181202
IS  - 1873-7072 (Electronic)
IS  - 0308-8146 (Linking)
VI  - 232
DP  - 2017 Oct 1
TI  - Speciation analysis of organoarsenic compounds in livestock feed by 
      microwave-assisted extraction and high performance liquid chromatography coupled 
      to atomic fluorescence spectrometry.
PG  - 493-500
LID - S0308-8146(17)30574-5 [pii]
LID - 10.1016/j.foodchem.2017.04.012 [doi]
AB  - The development of a new method to determine the presence of the organoarsenic 
      additives p-arsanilic acid (ASA), roxarsone (ROX) and nitarsone (NIT) in 
      livestock feeds by high performance liquid chromatography coupled to ultraviolet 
      oxidation hydride generation atomic fluorescence spectrometry (HPLC-UV/HG-AFS) 
      after microwave assisted extraction (MAE) was proposed. Chromatographic 
      separation was achieved on a C18 column with 2% acetic acid/methanol (96:4, v/v) 
      as the mobile phase. The limits of detection (LODs) were 0.13, 0.09 and 
      0.08mgL(-1), and the limits of quantification (LOQs) were 0.44, 0.30 and 
      0.28mgL(-1). The relative standard deviations (RSDs) for ASA, ROX and NIT 
      determined from five measurements of the mixed calibration standard were 3.3, 
      5.3, and 5.4%, respectively. MAE extraction of phenylated arsenic compounds using 
      1.5M H(3)PO(4) at 120 degrees C for 45min allowed for maximum recoveries (%) of total 
      arsenic (As) and organoarsenic species, with no degradation of these compounds. 
      The extraction of total As was approximately 97%, and the As species recoveries 
      were between 95.2 and 97.0%. The results of the analysis were validated using 
      mass balance by comparing the sum of extracted As with the total concentration of 
      As in the corresponding samples. The method was successfully applied to determine 
      the presence of these compounds in feed samples. ASA was the only As species 
      detected in chicken feed samples, with a concentration between 0.72 and 
      12.91mgkg(-1).
CI  - Copyright (c) 2017 Elsevier Ltd. All rights reserved.
FAU - Saucedo-Velez, A A
AU  - Saucedo-Velez AA
AD  - Universidad Autonoma de Nuevo Leon, UANL, Facultad de Ciencias Quimicas, Cd. 
      Universitaria, San Nicolas de los Garza, Nuevo Leon C.P. 66455, Mexico.
FAU - Hinojosa-Reyes, L
AU  - Hinojosa-Reyes L
AD  - Universidad Autonoma de Nuevo Leon, UANL, Facultad de Ciencias Quimicas, Cd. 
      Universitaria, San Nicolas de los Garza, Nuevo Leon C.P. 66455, Mexico.
FAU - Villanueva-Rodriguez, M
AU  - Villanueva-Rodriguez M
AD  - Universidad Autonoma de Nuevo Leon, UANL, Facultad de Ciencias Quimicas, Cd. 
      Universitaria, San Nicolas de los Garza, Nuevo Leon C.P. 66455, Mexico.
FAU - Caballero-Quintero, A
AU  - Caballero-Quintero A
AD  - Laboratorio de Quimica Forense, Criminalistica y Servicios Periciales, 
      Procuraduria General de Justicia del Estado de Nuevo Leon. Av. Gonzalitos 452, 
      Col. Residencial Galerias, Monterrey, NL C.P. 64649, Mexico.
FAU - Hernandez-Ramirez, A
AU  - Hernandez-Ramirez A
AD  - Universidad Autonoma de Nuevo Leon, UANL, Facultad de Ciencias Quimicas, Cd. 
      Universitaria, San Nicolas de los Garza, Nuevo Leon C.P. 66455, Mexico.
FAU - Guzman-Mar, J L
AU  - Guzman-Mar JL
AD  - Universidad Autonoma de Nuevo Leon, UANL, Facultad de Ciencias Quimicas, Cd. 
      Universitaria, San Nicolas de los Garza, Nuevo Leon C.P. 66455, Mexico. 
      Electronic address: jorge.guzmanmr@uanl.edu.mx.
LA  - eng
PT  - Journal Article
DEP - 20170405
PL  - England
TA  - Food Chem
JT  - Food chemistry
JID - 7702639
RN  - N712M78A8G (Arsenic)
SB  - IM
MH  - *Animal Feed
MH  - Animals
MH  - Arsenic
MH  - Chromatography, High Pressure Liquid
MH  - Food Analysis
MH  - *Livestock
MH  - Microwaves
MH  - Spectrometry, Fluorescence
OTO - NOTNLM
OT  - Atomic fluorescence spectrometry
OT  - Livestock feed samples
OT  - Microwave assisted extraction
OT  - Phenyl arsenic compounds
OT  - Reversed phase chromatography
EDAT- 2017/05/12 06:00
MHDA- 2017/09/02 06:00
CRDT- 2017/05/12 06:00
PHST- 2016/08/22 00:00 [received]
PHST- 2017/03/29 00:00 [revised]
PHST- 2017/04/03 00:00 [accepted]
PHST- 2017/05/12 06:00 [entrez]
PHST- 2017/05/12 06:00 [pubmed]
PHST- 2017/09/02 06:00 [medline]
AID - S0308-8146(17)30574-5 [pii]
AID - 10.1016/j.foodchem.2017.04.012 [doi]
PST - ppublish
SO  - Food Chem. 2017 Oct 1;232:493-500. doi: 10.1016/j.foodchem.2017.04.012. Epub 2017 
      Apr 5.