PMID- 28527415
OWN - NLM
STAT- MEDLINE
DCOM- 20170922
LR  - 20221207
IS  - 1879-1298 (Electronic)
IS  - 0045-6535 (Linking)
VI  - 182
DP  - 2017 Sep
TI  - Trace bromide ion impurity leads to formation of chlorobromoaromatic by-products 
      in peroxymonosulfate-based oxidation of chlorophenols.
PG  - 624-629
LID - S0045-6535(17)30769-5 [pii]
LID - 10.1016/j.chemosphere.2017.05.065 [doi]
AB  - Trace bromide (Br(-)) released from industrial effluents or brominated compounds 
      is able to directly react with peroxymonosulfate (PMS) to generate a series of 
      reactive oxidants which can oxidize and also halogenate organics. We report the 
      identification and evolution of by-products during 2,4,6-trichlorophenol (TCP) 
      degradation in the presence of PMS and trace Br(-). The influencing factors, 
      including Br(-) concentration and pH, were investigated. The depletion of TCP was 
      accelerated with increasing trace Br(-) concentration (0-0.2 mM) and was affected 
      by the initial pH (3.0-7.0). The chlorinated and brominated compounds were 
      identified in simulated wastewater during treatment with PMS. Notably, the 
      potential formation of chlorobromoaromatic by-products was demonstrated for the 
      first time in the presence of PMS and trace Br(-). The possible reaction pathways 
      of TCP and its derivatives are discussed. These findings have important 
      implications for the future applications of PMS-based oxidation processes.
CI  - Copyright (c) 2017 Elsevier Ltd. All rights reserved.
FAU - Fang, Changling
AU  - Fang C
AD  - State Environmental Protection Engineering Center for Pollution Treatment and 
      Control in Textile Industry, College of Environmental Science and Engineering, 
      Donghua University, Shanghai, 201620, China.
FAU - Wang, Zhaohui
AU  - Wang Z
AD  - State Environmental Protection Engineering Center for Pollution Treatment and 
      Control in Textile Industry, College of Environmental Science and Engineering, 
      Donghua University, Shanghai, 201620, China; International Centre for Balanced 
      Land Use (ICBLU), The University of Newcastle, Callaghan, NSW 2308, Australia. 
      Electronic address: zhaohuiwang@dhu.edu.cn.
FAU - Feng, Min
AU  - Feng M
AD  - State Environmental Protection Engineering Center for Pollution Treatment and 
      Control in Textile Industry, College of Environmental Science and Engineering, 
      Donghua University, Shanghai, 201620, China.
FAU - Huang, Ying
AU  - Huang Y
AD  - State Environmental Protection Engineering Center for Pollution Treatment and 
      Control in Textile Industry, College of Environmental Science and Engineering, 
      Donghua University, Shanghai, 201620, China.
FAU - Yang, Fei
AU  - Yang F
AD  - State Environmental Protection Engineering Center for Pollution Treatment and 
      Control in Textile Industry, College of Environmental Science and Engineering, 
      Donghua University, Shanghai, 201620, China.
FAU - Liu, Jianshe
AU  - Liu J
AD  - State Environmental Protection Engineering Center for Pollution Treatment and 
      Control in Textile Industry, College of Environmental Science and Engineering, 
      Donghua University, Shanghai, 201620, China. Electronic address: 
      liujianshe@dhu.edu.cn.
LA  - eng
PT  - Journal Article
DEP - 20170515
PL  - England
TA  - Chemosphere
JT  - Chemosphere
JID - 0320657
RN  - 0 (Bromides)
RN  - 0 (Chlorophenols)
RN  - 0 (Peroxides)
RN  - 0 (Waste Water)
RN  - 0 (Water Pollutants, Chemical)
RN  - 22047-43-4 (peroxymonosulfate)
RN  - MHS8C5BAUZ (2,4,6-trichlorophenol)
SB  - IM
MH  - Bromides/*chemistry
MH  - Chlorophenols/*chemistry
MH  - Environmental Restoration and Remediation/*methods
MH  - Halogenation
MH  - Hydrogen-Ion Concentration
MH  - Oxidation-Reduction
MH  - Peroxides/*chemistry
MH  - Research
MH  - Wastewater/chemistry
MH  - Water Pollutants, Chemical/*chemistry
OTO - NOTNLM
OT  - Bromination
OT  - Chlorobromoaromatic by-products
OT  - Chlorophenol
OT  - Peroxymonosulfate
EDAT- 2017/05/21 06:00
MHDA- 2017/09/25 06:00
CRDT- 2017/05/21 06:00
PHST- 2017/03/14 00:00 [received]
PHST- 2017/05/03 00:00 [revised]
PHST- 2017/05/11 00:00 [accepted]
PHST- 2017/05/21 06:00 [pubmed]
PHST- 2017/09/25 06:00 [medline]
PHST- 2017/05/21 06:00 [entrez]
AID - S0045-6535(17)30769-5 [pii]
AID - 10.1016/j.chemosphere.2017.05.065 [doi]
PST - ppublish
SO  - Chemosphere. 2017 Sep;182:624-629. doi: 10.1016/j.chemosphere.2017.05.065. Epub 
      2017 May 15.