PMID- 28530193 OWN - NLM STAT- MEDLINE DCOM- 20170817 LR - 20220204 IS - 1751-8741 (Print) IS - 1751-875X (Electronic) IS - 1751-8741 (Linking) VI - 11 IP - 4 DP - 2017 Jun TI - Surface adsorption of poisonous Pb(II) ions from water using chitosan functionalised magnetic nanoparticles. PG - 433-442 LID - 10.1049/iet-nbt.2016.0166 [doi] AB - In this study, chitosan functionalised magnetic nano-particles (CMNP) was synthesised and utilised as an effective adsorbent for the removal of Pb(II) ions from aqueous solution. The experimental studies reveal that adsorbent material has finer adsorption capacity for the removal of heavy metal ions. Parameters affecting the adsorption of Pb(II) ions on CMNP, such as initial Pb(II) ion concentration, contact time, solution pH, adsorbent dosage and temperature were studied. The adsorption equilibrium study showed that present adsorption system followed a Freundlich isotherm model. The experimental kinetic studies on the adsorption of Pb(II) ions exhibited that present adsorption process best obeyed with pseudo-first order kinetics. The maximum monolayer adsorption capacity of CMNP for the removal of Pb(II) ions was found to be 498.6 mg g(-1). The characterisation of present adsorbent material was done by FTIR, energy disperse X-ray analysis and vibrating sample magnetometer studies. Thermodynamic parameters such as Gibbs free energy (DeltaG degrees ), enthalpy (DeltaH degrees ) and entropy (DeltaS degrees ) have declared that the adsorption process was feasible, exothermic and spontaneous in nature. Sticking probability reported that adsorption of Pb(II) ions on CMNP was favourable at lower temperature and sticking capacity of Pb(II) ions was very high. FAU - Christopher, Femina Carolin AU - Christopher FC AD - Department of Chemical Engineering, SSN College of Engineering, Chennai 603110, India. FAU - Anbalagan, Saravanan AU - Anbalagan S AD - Department of Chemical Engineering, SSN College of Engineering, Chennai 603110, India. FAU - Kumar, Ponnusamy Senthil AU - Kumar PS AD - Department of Chemical Engineering, SSN College of Engineering, Chennai 603110, India. senthilchem8582@gmail.com. FAU - Pannerselvam, Sundar Rajan AU - Pannerselvam SR AD - Department of Chemical Engineering, SSN College of Engineering, Chennai 603110, India. FAU - Vaidyanathan, Vinoth Kumar AU - Vaidyanathan VK AD - Department of Biotechnology, School of Engineering, SRM University, Kattankulathur, Chennai 603203, India. LA - eng PT - Journal Article PL - England TA - IET Nanobiotechnol JT - IET nanobiotechnology JID - 101303205 RN - 0 (Ions) RN - 0 (Magnetite Nanoparticles) RN - 0 (Water Pollutants, Chemical) RN - 059QF0KO0R (Water) RN - 2P299V784P (Lead) RN - 9012-76-4 (Chitosan) SB - IM MH - Adsorption MH - Chitosan/*chemistry MH - Ions MH - Lead/chemistry/*isolation & purification MH - Magnetite Nanoparticles/*chemistry/ultrastructure MH - Materials Testing MH - Particle Size MH - Surface Properties MH - Ultrafiltration/methods MH - Water/*chemistry MH - Water Pollutants, Chemical/chemistry/*isolation & purification MH - Water Purification/*methods PMC - PMC8676542 EDAT- 2017/05/23 06:00 MHDA- 2017/08/18 06:00 PMCR- 2017/03/01 CRDT- 2017/05/23 06:00 PHST- 2017/05/23 06:00 [entrez] PHST- 2017/05/23 06:00 [pubmed] PHST- 2017/08/18 06:00 [medline] PHST- 2017/03/01 00:00 [pmc-release] AID - NBT2BF00247 [pii] AID - 10.1049/iet-nbt.2016.0166 [doi] PST - ppublish SO - IET Nanobiotechnol. 2017 Jun;11(4):433-442. doi: 10.1049/iet-nbt.2016.0166.