PMID- 28530759
OWN - NLM
STAT- PubMed-not-MEDLINE
DCOM- 20180220
LR  - 20180220
IS  - 1477-9234 (Electronic)
IS  - 1477-9226 (Linking)
VI  - 46
IP  - 21
DP  - 2017 May 30
TI  - A dual-emission probe to detect moisture and water in organic solvents based on 
      green-Tb(3+) post-coordinated metal-organic frameworks with red carbon dots.
PG  - 7098-7105
LID - 10.1039/c7dt01352c [doi]
AB  - Using p-phenylenediamine as a precursor, p-carbon dots (p-CDs) with strong 
      red-light emission were encapsulated into a metal-organic framework (MOF) 
      followed by introduction of green light-emitting Tb(3+) to form a two-color 
      light-emitting hybrid (Tb(3+)@p-CDs/MOF). The as-prepared 
      fluorescent-functionalized MOF not only maintained the excellent optical 
      properties of p-CDs and Tb(3+) to give strong emission, but also had good 
      chemical and physical properties. The chosen p-CDs were aggregated readily in 
      water, which led to only very weak photoluminescence, whereas the opposite effect 
      was noted in the organic solvents ethanol, dimethylformamide and cyclopropane. 
      Therefore, the as-prepared hybrid showed different color light emission in water 
      or organic solvents, and acted as a ratiometric and colorimetric fluorescent 
      probe to detect water content in organic solvents. Moreover, this hybrid also 
      served as a ratiometric luminescent sensor for detection of relative humidity 
      (RH): the ratio of light intensity at 545 nm to that at 605 nm increased linearly 
      with increasing RH from 33.0% to 85.1% in the atmosphere.
FAU - Wu, Jing-Xing
AU  - Wu JX
AD  - China-Australia Joint Laboratory for Functional Molecules and Ordered Matters, 
      School of Chemical Science and Engineering, Tongji University, Shanghai 200092, 
      P. R. China. byan@tongji.edu.cn.
FAU - Yan, Bing
AU  - Yan B
LA  - eng
PT  - Journal Article
PL  - England
TA  - Dalton Trans
JT  - Dalton transactions (Cambridge, England : 2003)
JID - 101176026
EDAT- 2017/05/23 06:00
MHDA- 2017/05/23 06:01
CRDT- 2017/05/23 06:00
PHST- 2017/05/23 06:00 [pubmed]
PHST- 2017/05/23 06:01 [medline]
PHST- 2017/05/23 06:00 [entrez]
AID - 10.1039/c7dt01352c [doi]
PST - ppublish
SO  - Dalton Trans. 2017 May 30;46(21):7098-7105. doi: 10.1039/c7dt01352c.