PMID- 28550746 OWN - NLM STAT- MEDLINE DCOM- 20181015 LR - 20181015 IS - 1095-7103 (Electronic) IS - 0021-9797 (Linking) VI - 504 DP - 2017 Oct 15 TI - Zn doped CdO nanoparticles: Structural, morphological, optical, photocatalytic and anti-bacterial properties. PG - 164-170 LID - S0021-9797(17)30546-5 [pii] LID - 10.1016/j.jcis.2017.05.026 [doi] AB - Pure and zinc-doped CdO NPs (Zn-CdO NPs) were synthesized through a facile co-precipitation method. The structural, morphology, chemical composition, optical and antibacterial activity of the NPs were studied with respect to pure and Zn-doped CdO concentration (0-7.5mol.%). Scanning electron microscope (SEM) images reveal that pure and Zn-doped CdO NPs were in the nano-scale regime with different crystalline morphology. The energy dispersive X-ray spectroscopy (EDS) spectrum predicts the presence of Cadmium (Cd), Zinc (Zn) and Oxygen (O) in the prepared samples. Optical studies divulge that Zn(2+) doping CdO decreases the band gap energy (Eg) (3.36-3.02eV) with an increase in Zn(2+) doping concentration. Optical absorption spectrum of CdO red-shifted as the Zn concentration varied from 2.5mol.% to 7.5mol.%. PL spectra displayed a strong UV emission peak at 380nm. Enhanced Visible emission at 430 and 522nm with Zn(2+) doping interprets the defect density in CdO by occupying Cd(2+) vacancies with Zn(2+) ions. Photocatalytic studies revealed that 7.5% Zn-doped CdO NPs show maximum degradation for atrazine (ATZ) as herbicide pollution under UV irradiation. Antibacterial studies against (Gram positive) and (Gram negative) bacteria's authenticate that Zn(2+) doped CdO nanostructures exhibit excellent antibacterial activity against all bacteria's with an increase in doping concentration. CI - Copyright (c) 2017 Elsevier Inc. All rights reserved. FAU - Gupta, Vinod Kumar AU - Gupta VK AD - Department of Applied Chemistry, University of Johannesburg, Johannesburg, South Africa. Electronic address: vinodg@uj.ac.za. FAU - Fakhri, Ali AU - Fakhri A AD - Young Researchers and Elites Club, Science and Research Branch, Islamic Azad University, Tehran, Iran; Department of Chemistry, Central Tehran Branch, Islamic Azad University, Tehran, Iran. Electronic address: ali.fakhri88@yahoo.com. FAU - Tahami, Shiva AU - Tahami S AD - Department of Biology, Karaj Branch, Islamic Azad University, Karaj, Iran. FAU - Agarwal, Shilpi AU - Agarwal S AD - Department of Applied Chemistry, University of Johannesburg, Johannesburg, South Africa. LA - eng PT - Journal Article DEP - 20170521 PL - United States TA - J Colloid Interface Sci JT - Journal of colloid and interface science JID - 0043125 RN - 0 (Anti-Bacterial Agents) RN - 0 (Cadmium Compounds) RN - 0 (Oxides) RN - 0 (Pesticides) RN - 0H3KWS8KJ3 (cadmium oxide) RN - J41CSQ7QDS (Zinc) RN - QJA9M5H4IM (Atrazine) SB - IM MH - Anti-Bacterial Agents/*chemistry/pharmacology MH - Atrazine/chemistry MH - Bacteria/drug effects MH - Bacterial Infections/prevention & control MH - Cadmium Compounds/*chemistry/pharmacology MH - Catalysis MH - Humans MH - Nanoparticles/*chemistry MH - Oxides/*chemistry/pharmacology MH - Pesticides/chemistry MH - Photolysis MH - Ultraviolet Rays MH - Zinc/*chemistry/pharmacology OTO - NOTNLM OT - Antibacterial studies OT - Cadmium oxide NPs OT - Doping OT - Photocatalytic OT - Zinc EDAT- 2017/05/28 06:00 MHDA- 2018/10/16 06:00 CRDT- 2017/05/28 06:00 PHST- 2017/02/14 00:00 [received] PHST- 2017/05/08 00:00 [revised] PHST- 2017/05/09 00:00 [accepted] PHST- 2017/05/28 06:00 [pubmed] PHST- 2018/10/16 06:00 [medline] PHST- 2017/05/28 06:00 [entrez] AID - S0021-9797(17)30546-5 [pii] AID - 10.1016/j.jcis.2017.05.026 [doi] PST - ppublish SO - J Colloid Interface Sci. 2017 Oct 15;504:164-170. doi: 10.1016/j.jcis.2017.05.026. Epub 2017 May 21.