PMID- 28646774 OWN - NLM STAT- MEDLINE DCOM- 20180807 LR - 20181202 IS - 1879-1026 (Electronic) IS - 0048-9697 (Linking) VI - 603-604 DP - 2017 Dec 15 TI - Observations of black carbon aerosols characteristics over an urban environment: Radiative forcing and related implications. PG - 319-329 LID - S0048-9697(17)31486-9 [pii] LID - 10.1016/j.scitotenv.2017.06.082 [doi] AB - With observations of black carbon (BC) aerosol concentrations, optical and radiative properties were obtained over the urban city of Karachi during the period of March 2006-December 2008. BC concentrations were continuously measured using an Aethalometer, while optical and radiative properties were estimated through the Optical Properties of Aerosols and Clouds (OPAC) and Santa Barbra DISORT Atmospheric Radiative Transfer (SBDART) models, respectively. For the study period, the measured BC concentrations were higher during January, February and November, while lower during May, June, July and August. A maximum peak value was observed during January 2007 while the minimum value was observed during June 2006. The Short Wave (SW) BC Aerosol Radiative Forcing (ARF) both at Top of the Atmosphere (ToA) and within ATMOSphere (ATMOS) were positive during all the months, whereas negative SW BC ARF was found at the SurFaCe (SFC). Overall, SW BC ARF was higher during January, February and November, while relatively lower ARF was found during May, June, July and August. Conversely, the Long Wave (LW) BC ARF at ToA and SFC remained positive, whereas within ATMOS it shifted towards positive values (heating effect) during June-August. Finally, the net (SW+LW) BC ARF were found to be positive at ToA and in ATMOS, while negative at SFC. Moreover, a systematic increase in Atmospheric Heating Rate (AHR) was found during October to January. Additionally, we found highest correlation between Absorption Aerosol Optical Depth (AOD(abs)) and SW BC ARF within ATMOS followed by SFC and ToA. Overall, the contribution of BC to the total ARF was found to greater than 84% for the whole observational period while contributing up to 93% during January 2007. CI - Copyright (c) 2017 Elsevier B.V. All rights reserved. FAU - Bibi, Samina AU - Bibi S AD - Department of Physics, University of Peshawar, Khyber Pakhtunkhwa, Pakistan. FAU - Alam, Khan AU - Alam K AD - Department of Physics, University of Peshawar, Khyber Pakhtunkhwa, Pakistan. Electronic address: khanalam@upesh.edu.pk. FAU - Chishtie, Farrukh AU - Chishtie F AD - Theoretical Research Institute, Pakistan Academy of Sciences, Islamabad, Pakistan. FAU - Bibi, Humera AU - Bibi H AD - Department of Physics, University of Peshawar, Khyber Pakhtunkhwa, Pakistan. FAU - Rahman, Said AU - Rahman S AD - Pakistan Space and Upper Atmosphere Research Commission (SUPARCO), P.O. Box 8402, Off University Road, Karachi 75270, Pakistan. LA - eng PT - Journal Article DEP - 20170621 PL - Netherlands TA - Sci Total Environ JT - The Science of the total environment JID - 0330500 RN - 0 (Aerosols) RN - 0 (Air Pollutants) RN - 0 (Soot) SB - IM MH - Aerosols/analysis MH - Air Pollutants/*analysis MH - Cities MH - *Environmental Monitoring MH - Pakistan MH - Seasons MH - Soot/*analysis OTO - NOTNLM OT - AOD OT - Absorbing aerosol OT - Black carbon OT - Forcing OT - OPAC OT - SBDART EDAT- 2017/06/25 06:00 MHDA- 2018/08/08 06:00 CRDT- 2017/06/25 06:00 PHST- 2017/02/05 00:00 [received] PHST- 2017/06/09 00:00 [revised] PHST- 2017/06/10 00:00 [accepted] PHST- 2017/06/25 06:00 [pubmed] PHST- 2018/08/08 06:00 [medline] PHST- 2017/06/25 06:00 [entrez] AID - S0048-9697(17)31486-9 [pii] AID - 10.1016/j.scitotenv.2017.06.082 [doi] PST - ppublish SO - Sci Total Environ. 2017 Dec 15;603-604:319-329. doi: 10.1016/j.scitotenv.2017.06.082. Epub 2017 Jun 21.