PMID- 28688847 OWN - NLM STAT- MEDLINE DCOM- 20171102 LR - 20181202 IS - 1879-1298 (Electronic) IS - 0045-6535 (Linking) VI - 185 DP - 2017 Oct TI - Pesticide residues in raw and processed maize grains and flour from selected areas in Dar es Salaam and Ruvuma, Tanzania. PG - 137-144 LID - S0045-6535(17)31057-3 [pii] LID - 10.1016/j.chemosphere.2017.07.014 [doi] AB - This study investigated the levels of pesticide residues in maize grains and flour and the effects of processing methods on their levels in maize products in samples collected in Dar es Salaam and Ruvuma regions. Analysis of cleaned-up extracts was done using gas chromatography-mass spectrometry (GC-MS). Twelve pesticides were detected in maize grains and their highest concentrations were up to 676.1, 11200 and 14 mug/kg for organochlorines, organophosphorous and pyrethroid pesticides, respectively. In maize flour, eight pesticides were detected and the concentrations for organochlorines, organophosphorous and pyrethroid pesticides were up to 333.3, 2220 and 2 mug/kg, respectively. Only dieldrin was detected in cooked samples at a concentration of 2 mug/kg. The concentrations of p,p'-DDD, aldrin, dieldrin, chlorpyrifos and pirimiphos methyl in some grains and flour samples exceeded the maximum residue limit (MRLs). The findings indicate risks and concerns for public health. Processing methods were found to cause transformation and reduction of the pesticides. CI - Copyright (c) 2017 Elsevier Ltd. All rights reserved. FAU - Mahugija, John Andrew Marco AU - Mahugija JAM AD - Chemistry Department, University of Dar es Salaam, P.O. Box 35061, Dar es Salaam, Tanzania. Electronic address: mahugija@udsm.ac.tz. FAU - Kayombo, Auguster AU - Kayombo A AD - Chemistry Department, University of Dar es Salaam, P.O. Box 35061, Dar es Salaam, Tanzania. FAU - Peter, Regina AU - Peter R AD - Chemistry Department, University of Dar es Salaam, P.O. Box 35061, Dar es Salaam, Tanzania. LA - eng PT - Journal Article DEP - 20170704 PL - England TA - Chemosphere JT - Chemosphere JID - 0320657 RN - 0 (Hydrocarbons, Chlorinated) RN - 0 (Pesticide Residues) RN - 0 (Pesticides) RN - OZE3CLY605 (Aldrin) SB - IM MH - Aldrin/analysis MH - *Environmental Monitoring MH - Flour/analysis MH - Gas Chromatography-Mass Spectrometry MH - Hydrocarbons, Chlorinated/analysis MH - Pesticide Residues/*analysis MH - Pesticides/analysis MH - Tanzania MH - Zea mays/*chemistry OTO - NOTNLM OT - Maize OT - Organochlorine OT - Organophosphorus OT - Pesticides OT - Pyrethroid OT - Tanzania EDAT- 2017/07/10 06:00 MHDA- 2017/11/03 06:00 CRDT- 2017/07/10 06:00 PHST- 2017/04/25 00:00 [received] PHST- 2017/07/02 00:00 [revised] PHST- 2017/07/03 00:00 [accepted] PHST- 2017/07/10 06:00 [pubmed] PHST- 2017/11/03 06:00 [medline] PHST- 2017/07/10 06:00 [entrez] AID - S0045-6535(17)31057-3 [pii] AID - 10.1016/j.chemosphere.2017.07.014 [doi] PST - ppublish SO - Chemosphere. 2017 Oct;185:137-144. doi: 10.1016/j.chemosphere.2017.07.014. Epub 2017 Jul 4.