PMID- 28711833 OWN - NLM STAT- PubMed-not-MEDLINE DCOM- 20180126 LR - 20180126 IS - 1873-3336 (Electronic) IS - 0304-3894 (Linking) VI - 340 DP - 2017 Oct 15 TI - Assessment of nanoparticles release into the environment during drilling of carbon nanotubes/epoxy and carbon nanofibres/epoxy nanocomposites. PG - 57-66 LID - S0304-3894(17)30478-8 [pii] LID - 10.1016/j.jhazmat.2017.06.057 [doi] AB - The risk assessment, exposure and understanding of the release of embedded carbon nanotubes (CNTs) and carbon nanofibers (CNFs) from commercial high performance composites during machining processes are yet to be fully evaluated and quantified. In this study, CNTs and CNFs were dispersed in epoxy matrix through calendaring process to form nanocomposites. The automated drilling was carried out in a specially designed drilling chamber that allowed elimination of background noise from the measurements. Emission measurements were taken using condensed particle counter (CPC), scanning mobility particle sizer (SMPS) and DMS50 Fast Particulate Size Spectrometer. In comparison to the neat epoxy, the study results revealed that the nano-filled samples produced an increase of 102% and 227% for the EP/CNF and EP/CNT sample respectively in average particle number concentration emission. The particle mass concentration indicated that the EP/CNT and EP/CNF samples released demands a vital new perspective on CNTs and CNFs embedded within nanocomposite materials to be considered and evaluated for occupational exposure assessment. Importantly, the increased concentration observed at 10nm aerosol particle sizes measurements strongly suggest that there are independent CNTs being released at this range. CI - Copyright (c) 2017 Elsevier B.V. All rights reserved. FAU - Starost, Kristof AU - Starost K AD - Centre for Advanced Engineering Materials, School of Engineering, Robert Gordon University, Aberdeen, AB10 7GJ, United Kingdom. FAU - Frijns, Evelien AU - Frijns E AD - VITO NV, Boeratang 200, 2400 Mol, Belgium. FAU - Van Laer, Jo AU - Van Laer J AD - VITO NV, Boeratang 200, 2400 Mol, Belgium. FAU - Faisal, Nadimul AU - Faisal N AD - Centre for Advanced Engineering Materials, School of Engineering, Robert Gordon University, Aberdeen, AB10 7GJ, United Kingdom. FAU - Egizabal, Ainhoa AU - Egizabal A AD - TECNALIA, Mikeletegi pasealekua, 2 E-20009, Donostia Spain. FAU - Elizextea, Cristina AU - Elizextea C AD - TECNALIA, Mikeletegi pasealekua, 2 E-20009, Donostia Spain. FAU - Blazquez, Maria AU - Blazquez M AD - INKOA SISTEMAS, SL. Ribera de Axpe 11, Edificio D1, Dpto 208. 48950, Erandio, Bizkaia Spain. FAU - Nelissen, Inge AU - Nelissen I AD - VITO NV, Boeratang 200, 2400 Mol, Belgium. FAU - Njuguna, James AU - Njuguna J AD - Centre for Advanced Engineering Materials, School of Engineering, Robert Gordon University, Aberdeen, AB10 7GJ, United Kingdom. Electronic address: j.njuguna@rgu.ac.uk. LA - eng PT - Journal Article DEP - 20170627 PL - Netherlands TA - J Hazard Mater JT - Journal of hazardous materials JID - 9422688 OTO - NOTNLM OT - Carbon nanofibers OT - Carbon nanotubes OT - Drilling emissions OT - Nanoparticle release EDAT- 2017/07/18 06:00 MHDA- 2017/07/18 06:01 CRDT- 2017/07/17 06:00 PHST- 2016/11/22 00:00 [received] PHST- 2017/06/22 00:00 [revised] PHST- 2017/06/23 00:00 [accepted] PHST- 2017/07/18 06:00 [pubmed] PHST- 2017/07/18 06:01 [medline] PHST- 2017/07/17 06:00 [entrez] AID - S0304-3894(17)30478-8 [pii] AID - 10.1016/j.jhazmat.2017.06.057 [doi] PST - ppublish SO - J Hazard Mater. 2017 Oct 15;340:57-66. doi: 10.1016/j.jhazmat.2017.06.057. Epub 2017 Jun 27.