PMID- 28738604 OWN - NLM STAT- MEDLINE DCOM- 20180907 LR - 20180907 IS - 1873-3573 (Electronic) IS - 0039-9140 (Linking) VI - 174 DP - 2017 Nov 1 TI - Electrochemical investigation and determination of procaterol hydrochloride on poly(glutamic acid)/carboxyl functionalized multiwalled carbon nanotubes/polyvinyl alcohol modified glassy carbon electrode. PG - 436-443 LID - S0039-9140(17)30681-1 [pii] LID - 10.1016/j.talanta.2017.06.047 [doi] AB - Poly(glutamic acid) (P-GLU)/carboxyl functionalized multiwalled carbon nanotubes (MWCNTs-COOH)/polyvinyl alcohol (PVA) modified glassy carbon electrode (GCE) has been successfully prepared and the electrochemical behavior of procaterol hydrochloride (ProH) was studied. The results show that the as-prepared modified electrode exhibits a good electrocatalytic property towards the oxidation of ProH in 0.2M phosphate buffer solution (PBS) (pH 6.0) due to the enhanced oxidation peak current at ~+0.59V. Under optimal reaction conditions, the oxidation peak current of ProH is proportional to its concentration in the linear dynamic ranges of 0.060 - 8.0muM (R = 0.9974), with a detection limit of 8.0 x 10(-9)M. Finally, this method was efficiently used for the determination of ProH in tablets and human urine with recoveries of 88.5~98.7% and 89.2 ~ 108.0%, respectively. CI - Copyright (c) 2017 Elsevier B.V. All rights reserved. FAU - Kong, Dexian AU - Kong D AD - College of Life Sciences, Fujian Agriculture and Forestry University, Fuzhou, Fujian 350002, China; Key Laboratory for Analytical Science of Food Safety and Biology of MOE, Fujian Provincial Key Laboratory of Analysis and Detection Technology for Food Safety, and College of Chemistry, Fuzhou University, Fujian 350116, China. FAU - Jiang, Lili AU - Jiang L AD - Key Laboratory for Analytical Science of Food Safety and Biology of MOE, Fujian Provincial Key Laboratory of Analysis and Detection Technology for Food Safety, and College of Chemistry, Fuzhou University, Fujian 350116, China. FAU - Liu, Yijun AU - Liu Y AD - College of Life Sciences, Fujian Agriculture and Forestry University, Fuzhou, Fujian 350002, China. FAU - Wang, Zeming AU - Wang Z AD - College of Life Sciences, Fujian Agriculture and Forestry University, Fuzhou, Fujian 350002, China. FAU - Han, Libin AU - Han L AD - College of Life Sciences, Fujian Agriculture and Forestry University, Fuzhou, Fujian 350002, China. FAU - Lv, Rixin AU - Lv R AD - College of Life Sciences, Fujian Agriculture and Forestry University, Fuzhou, Fujian 350002, China. FAU - Lin, Jiandi AU - Lin J AD - College of Life Sciences, Fujian Agriculture and Forestry University, Fuzhou, Fujian 350002, China. FAU - Lu, Chun-Hua AU - Lu CH AD - Key Laboratory for Analytical Science of Food Safety and Biology of MOE, Fujian Provincial Key Laboratory of Analysis and Detection Technology for Food Safety, and College of Chemistry, Fuzhou University, Fujian 350116, China. Electronic address: chunhualu@fzu.edu.cn. FAU - Chi, Yuwu AU - Chi Y AD - Key Laboratory for Analytical Science of Food Safety and Biology of MOE, Fujian Provincial Key Laboratory of Analysis and Detection Technology for Food Safety, and College of Chemistry, Fuzhou University, Fujian 350116, China. FAU - Chen, Guonan AU - Chen G AD - Key Laboratory for Analytical Science of Food Safety and Biology of MOE, Fujian Provincial Key Laboratory of Analysis and Detection Technology for Food Safety, and College of Chemistry, Fuzhou University, Fujian 350116, China. LA - eng PT - Journal Article DEP - 20170621 PL - Netherlands TA - Talanta JT - Talanta JID - 2984816R RN - 0 (Nanotubes, Carbon) RN - 25513-46-6 (Polyglutamic Acid) RN - 3KX376GY7L (Glutamic Acid) RN - 9002-89-5 (Polyvinyl Alcohol) RN - X7I3EMM5K0 (Procaterol) SB - IM MH - Electrochemistry/*instrumentation MH - Electrodes MH - Glass/*chemistry MH - Glutamic Acid/*chemistry MH - Humans MH - Models, Molecular MH - Molecular Conformation MH - Nanotubes, Carbon/*chemistry MH - Polyglutamic Acid/*chemistry MH - Polymerization MH - Polyvinyl Alcohol/*chemistry MH - Procaterol/*analysis/urine OTO - NOTNLM OT - Electrochemical OT - Multiwalled carbon nanotube OT - Poly glutamic acid OT - Procaterol hydrochloride EDAT- 2017/07/26 06:00 MHDA- 2018/09/08 06:00 CRDT- 2017/07/26 06:00 PHST- 2017/04/06 00:00 [received] PHST- 2017/06/17 00:00 [revised] PHST- 2017/06/18 00:00 [accepted] PHST- 2017/07/26 06:00 [entrez] PHST- 2017/07/26 06:00 [pubmed] PHST- 2018/09/08 06:00 [medline] AID - S0039-9140(17)30681-1 [pii] AID - 10.1016/j.talanta.2017.06.047 [doi] PST - ppublish SO - Talanta. 2017 Nov 1;174:436-443. doi: 10.1016/j.talanta.2017.06.047. Epub 2017 Jun 21.