PMID- 28742363
OWN - NLM
STAT- PubMed-not-MEDLINE
DCOM- 20180723
LR  - 20180723
IS  - 1520-5827 (Electronic)
IS  - 0743-7463 (Linking)
VI  - 33
IP  - 31
DP  - 2017 Aug 8
TI  - Improved Performance of Glucose Bioanodes Using Composites of (7,6) Single-Walled 
      Carbon Nanotubes and a Ferrocene-LPEI Redox Polymer.
PG  - 7591-7599
LID - 10.1021/acs.langmuir.7b00718 [doi]
AB  - The effect of incorporating different types of carbon nanotubes into composite 
      films of a redox polymer (FcMe(2)-C(3)-LPEI) and glucose oxidase (GOX) was 
      investigated. The composite films were constructed by first forming a 
      high-surface area network film of either single-walled carbon nanotubes (SWNTs) 
      or multiwalled carbon nanotubes (MWNTs) on a glassy carbon electrode (GCE) by 
      solution casting of a suspension of Triton-X-100 dispersed SWNTs. Next a glucose 
      responsive redox hydrogel was formed on top of the nanotube-modified electrode by 
      cross-linking FcMe(2)-C(3)-LPEI with glucose oxidase via ethylene glycol 
      diglycidyl ether (EGDGE). Electrochemical and enzymatic measurements showed that 
      composite films made with (7,6) SWNTs produced a higher response (3.3 mA/cm(2)) 
      to glucose than films made with (6,5) SWNTs (1.8 mA/cm(2)) or MWNTs (1.2 
      mA/cm(2)) or films made without SWNTs (0.7 mA/cm(2)). We also show that the 
      response of the composite films could be systematically varied by fabricating 
      SWNT films with different weight ratios of (7,6) and (6,5) SWNTs. Optimization of 
      the (7,6) SWNTs loading and the redox polymer-enzyme film produced a glucose 
      response of 11.2 mA/cm(2). Combining the optimized glucose films with a platinum 
      oxygen breathing cathode into a biofuel cell produced a maximum power density 
      output of 343 muW/cm(2).
FAU - Chen, Jie
AU  - Chen J
AD  - Department of Bioengineering, University of Texas at Dallas , 800 W. Campbell 
      Rd., Richardson, Texas 75083, United States.
FAU - Munje, Rujuta
AU  - Munje R
AD  - Department of Bioengineering, University of Texas at Dallas , 800 W. Campbell 
      Rd., Richardson, Texas 75083, United States.
FAU - Godman, Nicholas P
AU  - Godman NP
FAU - Prasad, Shalini
AU  - Prasad S
AD  - Department of Bioengineering, University of Texas at Dallas , 800 W. Campbell 
      Rd., Richardson, Texas 75083, United States.
FAU - Glatzhofer, Daniel T
AU  - Glatzhofer DT
FAU - Schmidtke, David W
AU  - Schmidtke DW
AUID- ORCID: 0000-0001-6404-318X
LA  - eng
PT  - Journal Article
PT  - Research Support, Non-U.S. Gov't
PT  - Research Support, U.S. Gov't, Non-P.H.S.
DEP - 20170725
PL  - United States
TA  - Langmuir
JT  - Langmuir : the ACS journal of surfaces and colloids
JID - 9882736
EDAT- 2017/07/26 06:00
MHDA- 2017/07/26 06:01
CRDT- 2017/07/26 06:00
PHST- 2017/07/26 06:00 [pubmed]
PHST- 2017/07/26 06:01 [medline]
PHST- 2017/07/26 06:00 [entrez]
AID - 10.1021/acs.langmuir.7b00718 [doi]
PST - ppublish
SO  - Langmuir. 2017 Aug 8;33(31):7591-7599. doi: 10.1021/acs.langmuir.7b00718. Epub 
      2017 Jul 25.